Abstract:
A carbon-based catalyst for flue gas desulfurization is brought into contact with a flue gas containing at least SO 2 gas, oxygen and water vapor so that the SO 2 gas can react with the oxygen and the water vapor to form sulfuric acid which is to be recovered. On a surface of the carbon-based catalyst, iodine, bromine or a compound thereof is added, ion exchanged or supported and a water-repellent treatment is applied. The carbon-based catalyst can also be used as a mercury adsorbent for flue gas treatment for adsorbing and removing metallic mercury from a flue gas containing metallic mercury, SO 2 gas, oxygen and water vapor.
Abstract:
Disclosed herein are a treatment method and a treatment system which are capable of inexpensively, efficiently, and safely treating wastewater discharged from a gasification plant in large amounts and containing two or more persistent substances. The method for treating wastewater discharged by wet-cleaning of gas obtained by partial oxidation of fossil fuel includes: a free cyanide removal step 2 in which free cyanides contained in the wastewater are removed by acidifying and aerating the wastewater; a biological treatment step 3 in which the wastewater that has been treated in the free cyanide removal step 2 is biologically treated; and a decomposition treatment step 4 in which COD components contained in the wastewater that has been treated in the biological treatment step 3 are decomposed. The decomposition treatment step 4 is preferably performed by an advanced oxidation treatment means, and may include the step of crystallizing calcium sulfate by adding a calcium-based alkaline agent to the wastewater.
Abstract:
Disclosed herein are a treatment method and a treatment system which are capable of inexpensively, efficiently, and safely treating wastewater discharged from a gasification plant in large amounts and containing two or more persistent substances. The method for treating wastewater discharged by wet-cleaning of gas obtained by partial oxidation of fossil fuel includes: a free cyanide removal step 2 in which free cyanides contained in the wastewater are removed by acidifying and aerating the wastewater; a biological treatment step 3 in which the wastewater that has been treated in the free cyanide removal step 2 is biologically treated; and a decomposition treatment step 4 in which COD components contained in the wastewater that has been treated in the biological treatment step 3 are decomposed. The decomposition treatment step 4 is preferably performed by an advanced oxidation treatment means, and may include the step of crystallizing calcium sulfate by adding a calcium-based alkaline agent to the wastewater.
Abstract:
A carbon-based catalyst for flue gas desulfurization is brought into contact with a flue gas containing at least SO 2 gas, oxygen and water vapor so that the SO 2 gas can react with the oxygen and the water vapor to form sulfuric acid which is to be recovered. On a surface of the carbon-based catalyst, iodine, bromine or a compound thereof is added, ion exchanged or supported and a water-repellent treatment is applied. The carbon-based catalyst can also be used as a mercury adsorbent for flue gas treatment for adsorbing and removing metallic mercury from a flue gas containing metallic mercury, SO 2 gas, oxygen and water vapor.
Abstract:
An exhaust gas treating method removes sulfur dioxide from exhaust gas containing at least sulfur dioxide and mercury by bringing the exhaust gas into contact with absorption liquid. Persulfate is added into the absorption liquid or alternatively, iodine gas is added to the exhaust gas before the exhaust gas is brought into contact with the absorption liquid. A high removal rate for both sulfur dioxide and mercury is stably maintained if the load of power generation and the composition of exhaust gas fluctuate.