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公开(公告)号:EP3294695B1
公开(公告)日:2020-09-30
申请号:EP16793238.3
申请日:2016-05-06
IPC分类号: C07C7/144 , B01D69/12 , B01D69/10 , B01J47/12 , B01D71/06 , B01D53/22 , C08J5/22 , C08F216/14 , C09D129/10
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2.
公开(公告)号:EP4370238A1
公开(公告)日:2024-05-22
申请号:EP22751516.0
申请日:2022-07-07
发明人: MAJUMDAR, Sudipto , LOUSENBERG, Robert D. , LOPRETE, Kenneth E. , SHANGGUAN, Ning , GONCHAROVSKY, Irene , WARGO, Jacob A.
CPC分类号: B01D53/228 , B01D69/12 , B01D71/32 , B01D69/02 , B01D2325/1420130101 , B01D2325/2020130101 , B01D71/44 , B01D71/82 , B01D71/70 , B01D2256/2220130101 , B01D2257/10220130101 , Y02C20/40
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公开(公告)号:EP4337374A1
公开(公告)日:2024-03-20
申请号:EP22726959.4
申请日:2022-05-12
IPC分类号: B01D71/32 , C08F8/12 , C08F226/02
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公开(公告)号:EP4126308A1
公开(公告)日:2023-02-08
申请号:EP21724066.2
申请日:2021-03-26
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公开(公告)号:EP3307422A1
公开(公告)日:2018-04-18
申请号:EP16808370.7
申请日:2016-06-10
IPC分类号: B01D61/38 , C07C7/144 , C07C21/18 , C08F214/26 , C08K5/02
CPC分类号: B01D71/32 , B01D53/228 , B01D67/0006 , B01D71/52 , B01D71/76 , B01D2323/06 , B01D2323/08 , B01D2325/20 , C07C17/38 , C08F214/186 , C07C21/18 , C07C21/185
摘要: Membranes having a permselective active layer of a copolymerized perfluorinated monomer and an non-fluorinated alkylvinylester monomer demonstrate superior selective permeability performance for separating gas mixtures compared to membranes of exclusively perfluorinated polymers. Preferred active layer compositions are copolymers of perfluoro-2,2-dimethyl-1,3 dioxole (PDD) copolymerized with an alkylvinyl ester such as vinyl acetate, and vinyl pivalate, and with alkylvinyl esters that are substantially hydrolyzed to provide copolymerized vinyl alcohol functionality. The membranes can have a thin, high diffusion rate, “gutter layer” of a fluorinated polymer highly permeable to nitrogen positioned between the active layer and a porous support layer. A novel copolymer effective in selectively permeable membranes is a copolymer of PDD and an alkylvinyl ester compound having the formula H2C═CHOC(0)R1 in which R1 is a linear or branched alkyl group of from 2 to 5 carbon atoms.
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