公开(公告)号：EP2597078A1

公开(公告)日：2013-05-29

申请号：EP13156447.8

申请日：2007-03-20

申请人： Chevron U.S.A. Inc.

发明人： Elomari, Saleh

IPC分类号： C07C2/60 ,  C07C2/62 ,  C10G29/20

CPC分类号： C07C2/62 ,  C07C2/60 ,  C07C2527/11 ,  C07C2531/02 ,  C10G29/205

摘要： Disclosed is an alkylation process. The process comprises contacting a hydrocarbon mixture comprising at least one olefin having from 2 to 6 carbon atoms and at least one isoparaffin having from 3 to 6 carbon atoms under alkylation conditions in the presence of an acidic ionic liquid catalyst. The catalyst comprising a mixture of at least one acidic ionic liquid and at least one alkyl halide. The acidic ionic liquid is a chloroaluminate ionic liquid prepared by mixing aluminum trichloride (AlCl 3 ) and a hydrocarbyl substituted pyridinium halide having the general formula A:

where R = H, methyl, ethyl, propyl, butyl, pentyl or hexyl group and X is a chloroaluminate; and wherein the isoparaffin and the olefin are alkylated.

摘要翻译： 公开了烷基化方法。 该方法包括在酸性离子液体催化剂存在下，在烷基化条件下使包含至少一种具有2至6个碳原子的烯烃和至少一个具有3至6个碳原子的异链烷烃的烃混合物接触。 催化剂包含至少一种酸性离子液体和至少一种烷基卤化物的混合物。 酸性离子液体是通过将三氯化铝（AlCl 3）和具有通式A的烃基取代的吡啶鎓卤化物混合制备的氯铝酸盐离子液体，其中R = H，甲基，乙基，丙基，丁基，戊基或己基，X是 氯铝酸盐; 并且其中异链烷烃和烯烃被烷基化。

公开(公告)号：EP2597078B1

公开(公告)日：2017-12-13

申请号：EP13156447.8

申请日：2007-03-20

申请人： Chevron U.S.A. Inc.

发明人： Elomari, Saleh

IPC分类号： C07C2/60 ,  C07C2/62 ,  C10G29/20

CPC分类号： C07C2/62 ,  C07C2/60 ,  C07C2527/11 ,  C07C2531/02 ,  C10G29/205

摘要： Disclosed is an alkylation process. The process comprises contacting a hydrocarbon mixture comprising at least one olefin having from 2 to 6 carbon atoms and at least one isoparaffin having from 3 to 6 carbon atoms under alkylation conditions in the presence of an acidic ionic liquid catalyst. The catalyst comprising a mixture of at least one acidic ionic liquid and at least one alkyl halide. The acidic ionic liquid is a chloroaluminate ionic liquid prepared by mixing aluminum trichloride (AlCl 3 ) and a hydrocarbyl substituted pyridinium halide having the general formula A: where R = H, methyl, ethyl, propyl, butyl, pentyl or hexyl group and X is a chloroaluminate; and wherein the isoparaffin and the olefin are alkylated.