-
公开(公告)号:EP3907004A1
公开(公告)日:2021-11-10
申请号:EP19910741.8
申请日:2019-10-30
申请人: China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
发明人: WU, Hongfei , ZHENG, Mingfang , HU, Songshuang , LI, Tonglin , LIU, Jun , XU, Ke , WANG, Xiaoqing , PAN, Feng
IPC分类号: B01J31/24 , C07C2/34 , C07C2/36 , C07C11/107 , C07C11/02
摘要: Disclosed are a halogen-containing compound as shown in a formula I and use thereof as a ligand for an ethylene oligomerization catalyst composition; and further disclosed are an ethylene oligomerization catalyst composition containing the halogen-containing compound, and ethylene oligomerization, trimerization and tetramerization methods using the catalyst composition. As a ligand of a catalyst for ethylene oligomerization, a fluoropolymer can effectively improve the catalytic performance of a catalyst system, and particularly exhibits significantly improved activity and selectivity in an ethylene oligomerization reaction. The catalyst composition has better industrial application prospects and economic value.
-
2.
公开(公告)号:EP3907003A1
公开(公告)日:2021-11-10
申请号:EP19910858.0
申请日:2019-10-30
申请人: China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
发明人: WU, Hongfei , ZHENG, Mingfang , HU, Songshuang , LI, Tonglin , LIU, Jun , XU, Ke , WANG, Xiaoqing , PAN, Feng
摘要: A halogen-containing compound represented by a formula I and a use thereof as a ligand of an ethylene oligomerization catalyst composition, an ethylene oligomerization catalyst composition comprising the halogen-containing compound, and an ethylene oligomerization method, ethylene trimerization method and ethylene tetramerization method using the catalyst composition. Serving as the ligand of the ethylene oligomerization catalyst, the halogen-containing polymer may effectively improve the catalytic performance of a catalyst system, especially by displaying a significantly improved catalytic performance in an ethylene oligomerization reaction. The maximum catalyst activity may exceed 4 × 10 8 g•mol(Cr) -1 •h -1 , and the total selectivity of 1-hexene and 1-octene exceeds 92 wt%. In a C6 product, the content of 1-hexene may reach about 97%, and in a C8 product, the content of 1-octene may reach more than 98%. The present catalyst composition has good industrial application prospects and economic value.
-
公开(公告)号:EP3967783A1
公开(公告)日:2022-03-16
申请号:EP20802910.8
申请日:2020-05-06
摘要: The present invention relates to a catalyst used for dehydrogenation of an organic hydrogen-storage material to generate hydrogen, a support for the catalyst, and a preparation process thereof; the present invention also relates to a hydrogen-storage alloy and a preparation process thereof; and the present invention also relates to a process for providing high-purity hydrogen, a high-efficiently distributed process for producing high-purity and high-pressure hydrogen, a system for providing high-purity and high-pressure hydrogen, a mobile hydrogen supply system, and a distributed hydrogen supply apparatus.
-
-