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公开(公告)号：EP4406932A1
公开(公告)日：2024-07-31
申请号：EP22872094.2
申请日：2022-09-23
申请人： China Petroleum & Chemical Corporation , Sinopec Research Institute of Petroleum Processing Co., Ltd.
发明人： FU, Zhaolin , TAO, Zhiping , XING, Enhui , LUO, Yibin , SHU, Xingtian , ZHAO, Jie , YAN, Rui , JIA, Dandan , ZHU, Zhongpeng , ZHENG, Weiping
摘要： Disclosed is a continuous process for preparing exo-THDCPD by isomerization of endo-THDCPD, which comprises passing endo-THDCPD and hydrogen gas successively through a first reaction zone filled with a hydrogenation protectant and a second reaction zone filled with an isomerization catalyst to perform a hydroisomerization reaction so as to obtain exo-THDCPD, wherein the hydrogenation protectant is a supported metal hydrogenation catalyst, and the isomerization catalyst is a metal-modified molecular sieve catalyst. The process can effectively convert endo-THDCPD to exo-THDCPD, with a conversion of greater than 86% and a target product selectivity of greater than 94%. This process is clean and green, and it can achieve a continuous operation of more than 2000 hours and has an industrial application prospect.
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公开(公告)号：EP4275789A1
公开(公告)日：2023-11-15
申请号：EP22736632.5
申请日：2022-01-11
申请人： China Petroleum & Chemical Corporation , Sinopec Research Institute of Petroleum Processing Co., Ltd.
发明人： LUO, Yibin , WANG, Chengqiang , OUYANG, Ying , XING, Enhui , SHU, Xingtian
摘要： A catalytic cracking agent, having an active component consisting of a phosphorus-modified molecular sieve and a non-phosphorus-modified molecular sieve or only consisting of a phosphorus-modified molecular sieve, characterized in that with an electron probe microanalysis (EPMA), the D value of phosphorus in the catalytic cracking agent is ≥65%, preferably ≥68%, provided that the active component consists of the phosphorus-modified molecular sieve and the non-phosphorus-modified molecular sieve, or the D value of phosphorus in the catalytic cracking agent is≥82%, preferably≥84%, provided that the active component only consists of the phosphorus-modified molecular sieve.
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公开(公告)号：EP4275788A1
公开(公告)日：2023-11-15
申请号：EP22736636.6
申请日：2022-01-11
申请人： China Petroleum & Chemical Corporation , Sinopec Research Institute of Petroleum Processing Co., Ltd.
发明人： LUO, Yibin , WANG, Chengqiang , LIANG, Weijun , SHU, Xingtian , LI, Jun , XING, Enhui
摘要： The present invention provides a process for preparing a catalytic cracking catalyst, which is characterized in that the process comprises: mixing raw materials including a rare earth-containing NaY molecular sieve obtained by contacting a NaY molecular sieve with a rare-earth salt solution or a mixed solution of rare-earth salt solution and ammonium salt solution, filtering, and water-washing, an inorganic oxide binder and a natural mineral, slurrying and shaping into shaped bodies; hydrothermally calcining shaped bodies in an atmosphere condition where a pressure is externally applied and an aqueous solution containing an acidic substance or an alkaline substance is extennally added; and then ammonium-exchanging to remove the alkali metal. The present invention optimizes and shortens the preparation process of the catalyst, which can reduce the preparation cost, and the prepared catalyst has excellent heavy oil conversion ability, higher gasoline and diesel yield, lower coke selectivity, and relatively reduces the used amount of the molecular sieve in the catalyst.
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公开(公告)号：EP4137456A1
公开(公告)日：2023-02-22
申请号：EP21788139.0
申请日：2021-04-13
发明人： LUO, Yibin , WANG, Chengqiang , OUYANG, Ying , XING, Enhui , SHU, Xingtian
摘要： The present invention relates to a phosphorus-containing or phosphorus-modified ZSM-5 molecular sieve, which is characterized in that in its 27A1 MAS-NMR, the ratio of peak area for the resonance signal having a chemical shift of 39±3ppm to peak area for the resonance signal having a chemical shift of 54ppm±3ppm is ≥1; or in its surface XPS elemental analysis, the value of n1/n2 is≤0.1; wherein, n1 represents the mole number of phosphorus, n2 represents the total mole number of silicon and aluminum; the present invention also relates to a cracking auxiliary or cracking catalyst containing said phosphorus-containing/phosphorus-modified ZSM-5 molecular sieve, and a process for preparing the same and use thereof.
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公开(公告)号：EP3872056A1
公开(公告)日：2021-09-01
申请号：EP19875387.3
申请日：2019-10-25
发明人： LUO, Yibin , OUYANG, Ying , XING, Enhui , SHU, Xingtian , CHENG, Xiaojie , ZHU, Genquan
摘要： Disclosed is a catalytic cracking process and a catalyst system, the process comprising a step of contacting a cracking feedstock with a catalytic cracking catalyst in the presence of a radical initiator for reaction under catalytic cracking conditions; wherein the radical initiator comprises a dendritic polymer and/or a hyperbranched polymer, the dendritic polymer and the hyperbranched polymer each independently has a degree of branching of about 0.3-1, and the dendritic polymer and the hyperbranched polymer each independently has a weight average molecular weight of greater than about 1000. The catalytic cracking process is beneficial to enhancing and accelerating the free radical cracking of petroleum hydrocarbon and promoting the regulation of cracking activity and product distribution; by using the process disclosed herein, the conversion of catalytic cracking can be improved, the yields of ethylene and propylene can be increased, and the yield of coke can be reduced.
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公开(公告)号：EP4137457A1
公开(公告)日：2023-02-22
申请号：EP21788715.7
申请日：2021-04-13
发明人： LUO, Yibin , WANG, Chengqiang , OUYANG, Ying , XING, Enhui , SHU, Xingtian
摘要： A phosphorus-modified MFI-structured molecular sieve, which is characterized in that the molecular sieve has a K value, satisfying: 70% ≤ K ≤ 90%; for example, 75% ≤ K ≤ 90%; further for example, 78% ≤ K ≤ 85%; wherein, the K value is as defined in the specification; the present invention also relates to a cracking auxiliary or cracking catalyst comprising the phosphorus-modified MFI molecular sieve, and a process of preparing the same and use thereof.
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