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公开(公告)号：EP2428524A4
公开(公告)日：2018-01-03
申请号：EP11732341
申请日：2011-04-19
申请人： DAELIM IND CO LTD
发明人： KANG SUNG-WOO , KIM NAM-KYU , JUN YOUNG-JAE , KIM MAN-JUNG , KIM KIL-SU
IPC分类号： C08F2/34 , B01J8/18 , B01J19/24 , C08F10/00 , C08F210/16
CPC分类号： B01J8/44 , B01J8/1827 , B01J8/1854 , B01J8/1863 , B01J2208/00274 , B01J2208/0092 , B01J2208/00929 , C08F210/16 , C08F2/34 , C08F210/14 , C08F2500/07 , C08F2500/18 , C08F2500/08
摘要： A method for preparing polyolefin from alpha-olefin with high productivity using an internal circulating fluidized bed polymerization reactor is disclosed. The method for gas-phase polymerization of alpha-olefin comprising the steps of: supplying circulation gas including one or more alpha-olefins and inert gas into a polymerization reactor; polymerizing the alpha-olefin to polyolefin in two separated polymerisation areas in the polymerization reactor; and discharging produced polyolefin from the polymerization reactor. The polymerization reactor is divided into the two polymerization areas by a draft tube, and an inside of the draft tube forms a riser where growing polyolefin polymers move up in fast fluidization, and an outside of the draft tube forms an annulus where the polyolefin polymers passing the riser move down by gravity, and the polyolefin polymers passing the annulus are introduced to a lower part of the riser again, so that the polyolefin polymers are polymerized during circulating between the riser and the annulus.
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公开(公告)号：EP2832753A4
公开(公告)日：2015-11-25
申请号：EP13767447
申请日：2013-03-29
申请人： DAELIM IND CO LTD
发明人： SOHN BYUNG-KEEL , YU SEUNG-TACK , YOO SANG-WON , JUN YOUNG-JAE , HONG SAH-MUN
CPC分类号： C08F210/16 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08L23/04 , C08L23/06 , C08L23/0807 , C08L23/0815 , C08L2205/025 , C08L2207/068 , C08L2308/00 , C08L2314/06 , Y10T428/139 , Y10T442/60 , C08F4/65904 , C08F110/02 , C08F2500/04 , C08F2500/05 , C08F2500/07 , C08F2500/12 , C08F2500/11 , C08F2500/19 , C08F2500/20 , C08F210/14 , C08F4/65912
摘要： Multimodal polyolefin resin having excellent characteristics such as moldability, mechanical strength, external appearance and a polyolefin resin molded product are disclosed. The polyolefin resin satisfies all requirements of following (1) to (5), (1) density (d): 0.934 to 0.963 g/cm3, (2) melt flow index(MIE, 190°C, 2.16 kg load condition): 0.01 to 1.0 g/10 minutes, (3) ratio of weight-average molecular weight (Mw) and number-average molecular weight (Mn) measured by Gel Permeation Chromatography (GPC) (Mw/Mn, Molecular weight distribution (MWD)): 12 to 60, (4) at least two peaks appear when the molecular weight of the polyolefin resin is measured with GPC, and (5) amount of polyolefin having Mw of 10,000 or less exceeds 15 weight% and amount of polyolefin having Mw of 1,000,000 or more exceeds 1.5 weight%, when the molecular weight of the polyolefin resin is measured with GPC.
摘要翻译： 公开了具有成型性，机械强度，外观和聚烯烃树脂成型品等特性优异的多峰聚烯烃树脂。 聚烯烃树脂满足以下（1）〜（5），（1）密度（d）：0.934〜0.963g / cm 3，（2）熔体流动指数（MIE，190℃，2.16kg负载条件）的所有要求： 0.01〜1.0g / 10分钟，（3）通过凝胶渗透色谱法（GPC）（Mw / Mn，分子量分布（MWD））测定的重均分子量（Mw）和数均分子量 ：12〜60，（4）当用GPC测定聚烯烃树脂的分子量时，出现至少两个峰，（5）Mw为10,000以下的聚烯烃的量超过15重量％，Mw的Mw为 当用GPC测量聚烯烃树脂的分子量时，其100万以上超过1.5重量％。
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3.发明公开
公开(公告)号：EP2305719A4
公开(公告)日：2015-10-28
申请号：EP09800508
申请日：2009-06-23
申请人： DAELIM IND CO LTD
发明人： HONG SAH-MUN , KANG SUNG-WOO , JUN YOUNG-JAE , SOHN BYUNG-KEEL
IPC分类号： C08F4/642 , C08F4/655 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F2410/01 , C08F2/06 , C08F110/02 , C08F2500/01 , C08F2500/12 , C08F210/14 , C08F4/6592 , C08F4/6491
摘要： This invention relates to an olefin polymerization catalyst and an olefin polymerization method using the same, which produces an olefin polymer of a low melt index and a relatively high molecular weight. The olefin polymerization catalyst includes an organic compound of Formula 1; an organometallic compound of Formula 2; an organic transition metal compound of Formula 3; and an aluminoxane.
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