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    A sulfur-containing fluorinated unsaturated compound and its manufacturing process
    1.
    发明公开
    A sulfur-containing fluorinated unsaturated compound and its manufacturing process 失效
    Schwefel enthaltende fluorierteungesättigteVerbindungen und ihr Herstellungsprozess。

    公开(公告)号：EP0154894A1

    公开(公告)日：1985-09-18

    申请号：EP85102199.8

    申请日：1985-02-27

    申请人： DAIKIN INDUSTRIES, LIMITED

    发明人： Ishikawa, Nobuo, Prof. Dr.-Ing. ,  Kitazume, Tomoya, Dr.-Ing.

    IPC分类号： C07C149/16 ,  C07C149/18 ,  C07C149/31 ,  C07C149/34 ,  C07C149/36

    CPC分类号： C07C323/14 ,  C07C33/423 ,  C07C33/483 ,  C07C319/20 ,  C07C323/22 ,  C07C327/22 ,  C07C323/27 ,  C07C323/54

    摘要： There is provided a sulfur-containing fluorinated α,β-unsaturated carbonyl compound expressed by a general formula,
    wherein R 1 and R 2 are independently an aliphatic or aromatic group with or without a substituent or substituents.
    Further, a process of manufacturing the above compound wherein a halide of fluorinated carbonyl compound expressed by a general formula,
    , wherein R 1 is an aliphatic or aromatic group with or whith- out a substituent or substituents and X is a halogen atom, is reacted with a mercaptan expressed by a general formula,
    wherein R 2 is an aliphatic or aromatic group with or without a substituent or substituents, to produce a sulfur-containing I fluorinated carbonyl compound expressed by a general formula,
    wherein R 1 and R 2 are the same as those of the starting materials, and this sulfur-containing carbonyl compound is converted, by the elimination of hydrogen fluoride, to a sulfur-containing fluorinated unsaturated carbonyl compound expressed by a general formula,
    wherein R 1 and R 2 are the same as those of the starting materials.

    摘要翻译： 提供由通式R min-c-CF = CF-SR 2表示的含硫氟化的α，β-不饱和羰基化合物，其中R 1和R 2独立地是脂族或芳族 具有或不具有取代基的基团。 此外，制备上述化合物的方法，其中由通式R 1〜/ CHF-CF 2 X表示的氟化羰基化合物的卤化物，其中R 1是具有或没有取代基或取代基的脂族或芳族基团 并且X是卤素原子与由通式R 2 -SH表示的硫醇反应，其中R 2是具有或不具有取代基的脂族或芳族基团，以产生含硫氟化物 由通式表示的羰基化合物，其中R 1和R 2与起始原料相同，其中R 1，R 2，R 2，R 2和R 2与起始原料相同，并且该含硫羰基化合物 通过消除氟化氢而转化成由通式R 1〜X 2 CF = CF-SR 2表示的含硫氟化不饱和羰基化合物，其中R 1和R 2均为氢， 与原料相同。