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公开(公告)号：EP1008598A2
公开(公告)日：2000-06-14
申请号：EP99309658.5
申请日：1999-12-01
摘要： Siloxanes are polymerised by equilibration, condensation and/or ring-opening polymerisation using a phosphazene base catalyst. A linear phosphazene base catalyst of the general formula
wherein R denotes a C 1-10 hydrocarbon or wherein two R groups on one N atom form with the N atom a heterocyclic group, X denotes an anion and n is from 1 to 10 is prepared by reacting a linear phosphonitrile halide compound with a secondary amine or a salt of a secondary amine or a metal amide thereof to form an aminated phosphazene material, followed by an ion exchange reaction replacing the anion with a nucleophile.摘要翻译： 硅氧烷通过使用磷腈碱催化剂的平衡，缩合和/或开环聚合来聚合。 一种通式
的线性磷腈碱催化剂，其中R表示C1-10烃或其中一个N原子上的两个R基团与N原子为杂环基，X表示阴离子，n为1至10。 通过使线性磷腈卤化物与仲胺或仲胺或其金属酰胺的盐反应以形成胺化的磷腈材料，然后用亲核试剂代替阴离子的离子交换反应制备。 -
公开(公告)号：EP1008598A3
公开(公告)日：2001-08-29
申请号：EP99309658.5
申请日：1999-12-01
摘要： Siloxanes are polymerised by equilibration, condensation and/or ring-opening polymerisation using a phosphazene base catalyst. A linear phosphazene base catalyst of the general formula wherein R denotes a C 1-10 hydrocarbon or wherein two R groups on one N atom form with the N atom a heterocyclic group, X denotes an anion and n is from 1 to 10 is prepared by reacting a linear phosphonitrile halide compound with a secondary amine or a salt of a secondary amine or a metal amide thereof to form an aminated phosphazene material, followed by an ion exchange reaction replacing the anion with a nucleophile.
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公开(公告)号：EP1008598B1
公开(公告)日：2004-05-26
申请号：EP99309658.5
申请日：1999-12-01
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4.发明公开Method for making a catalyst composition 审中-公开Verfahren zur Herstellung einer katalytischen Zusammensetzung
公开(公告)号：EP1008551A2
公开(公告)日：2000-06-14
申请号：EP99309659.3
申请日：1999-12-01
IPC分类号： C01B21/098 , C08G77/08
CPC分类号： C08G77/08 , C01B21/098 , C01B21/0986
摘要： A method for making a phosphonitrile halide of the formula (X(PX 2 =N) a PX 3 )) + A - wherein X represents a halogen, A represents X or (PX 6 ) - , and a is an integer of from 1 to 9, comprises a first step of reacting PX 5 and a disilazane under cooling in an inert non-chlorinated solvent and a second step of heating the reaction mixture to at least 50°C for a time sufficient to produce the phosphonitrile halide. The method may also include a third step of adding a cyclosiloxane of the formula ((CH 3 ) 2 SiO) b , wherein b is an integer of from 3 to 6, to the reaction mixture resulting from the second step to form a phosphonitrile halide containing species of the formula Z-((CH 3 ) 2 SiO) b -Z wherein Z is X or a group OPX 2 (NPX 2 ) a NPX 2 -, the phosphonitrile halide containing species having at least one group of the formula OPX 2 (NPX 2 ) a NPX 2 -. Also disclosed is the use of the phosphonitrile halide made by the method of the present invention as a catalyst for the polymerisation of organopolysiloxanes.
摘要翻译： 一种制备式（X（PX2 = N）aPX3））+（A）的磷腈卤化物的方法，其中X表示卤素，A表示X或（PX6） - ，并且a为 1至9包括在惰性非氯化溶剂中在冷却下使PX5和二硅氮烷反应的第一步骤，以及将反应混合物加热至少50℃的时间足以产生磷腈卤化物的第二步骤。 该方法还可以包括第三步骤，将由式（（CH 3）2 SiO）b的环硅氧烷（其中b为3至6的整数）加入到由第二步产生的反应混合物中以形成含磷腈卤化物的物质 的式Z - （（CH 3）2 SiO）bZ其中Z是X或基团OPX2（NPX2）aNPX2-，含磷腈卤化物的物质具有至少一个式OPX2（NPX2）aNPX2-的基团。 还公开了通过本发明的方法制备的磷腈卤化物作为有机聚硅氧烷聚合的催化剂的用途。
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公开(公告)号：EP1008551A3
公开(公告)日：2000-08-16
申请号：EP99309659.3
申请日：1999-12-01
IPC分类号： C01B21/098 , C08G77/08
CPC分类号： C08G77/08 , C01B21/098 , C01B21/0986
摘要： A method for making a phosphonitrile halide of the formula (X(PX 2 =N) a PX 3 )) + A - wherein X represents a halogen, A represents X or (PX 6 ) - , and a is an integer of from 1 to 9, comprises a first step of reacting PX 5 and a disilazane under cooling in an inert non-chlorinated solvent and a second step of heating the reaction mixture to at least 50°C for a time sufficient to produce the phosphonitrile halide. The method may also include a third step of adding a cyclosiloxane of the formula ((CH 3 ) 2 SiO) b , wherein b is an integer of from 3 to 6, to the reaction mixture resulting from the second step to form a phosphonitrile halide containing species of the formula Z-((CH 3 ) 2 SiO) b -Z wherein Z is X or a group OPX 2 (NPX 2 ) a NPX 2 -, the phosphonitrile halide containing species having at least one group of the formula OPX 2 (NPX 2 ) a NPX 2 -. Also disclosed is the use of the phosphonitrile halide made by the method of the present invention as a catalyst for the polymerisation of organopolysiloxanes.
摘要翻译： 一种制备式（X（PX2 = N）aPX3））+ A-的磷腈卤化物的方法，其中X代表卤素，A代表X或（PX6） - ，a是1至9的整数，包括 在冷却下在惰性非氯化溶剂中使PX5和二硅氮烷反应的第一步骤和将反应混合物加热至至少50℃足以产生磷腈卤化物的时间的第二步骤。 所述方法还可以包括将式（（CH 3）2 SiO）b的环硅氧烷（其中b为3至6的整数）加入到由第二步得到的反应混合物中以形成含磷腈卤化物的物质 其中Z是X或OPX2（NPX2）aNPX2-的式Z - （（CH3）2SiO）bZ，所述含膦腈卤化物的物质具有至少一个式OPX2（NPX2）aNPX2-的基团。 还公开了通过本发明的方法制备的磷腈卤化物作为有机聚硅氧烷聚合的催化剂的用途。
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