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    Method of producing high strength elongated products containing carbon nanotubes
    2.
    发明公开
    Method of producing high strength elongated products containing carbon nanotubes 审中-公开
    Verfahren zur Herstellung hochfesterverlängerterProdukte mitKohlenstoffnanoröhrchen

    公开(公告)号：EP1873281A1

    公开(公告)日：2008-01-02

    申请号：EP07075659.8

    申请日：2003-02-07

    申请人： DSM IP Assets B.V.

    发明人： Marissen, Roelof ,  van Es, Martin Antonius

    IPC分类号： D01F1/10 ,  D01F6/04 ,  C08K7/06

    CPC分类号： B82Y30/00 ,  C08K3/041 ,  D01F1/10 ,  D01F6/04 ,  D01F6/605 ,  Y10T428/249945 ,  C08L23/06

    摘要： The present invention relates to a method of producing a high strength and high modulus elongated product comprising the steps of (a) making a composition comprising a semi-crystalline polymer and carbon nanotubes, (b) extruding said composition into an elongated product, and (c) stretching the product below the melting point of the polymer, wherein in step (a) the composition is a colloidal dispersion of nanotubes in a solution of the polymer. The advantages of the invention include production of elongated products, like fibres with higher tensile properties, especially strength, with a lower concentration of nanotubes than with a known method.
    The invention also concerns a high strength elongated product containing nanotubes obtainable by the method according to the invention, especially a polyolefin fibre containing nanotubes having a tensile strength of higher than 3.0 GPa. The invention also relates to a process for making composite articles wherein high strength elongated products, preferably fibres, according to the invention are used and to anti-ballistic composites comprising said products.

    摘要翻译： 本发明涉及一种生产高强度和高模量细长产品的方法，包括以下步骤：（a）制备包含半结晶聚合物和碳纳米管的组合物，（b）将所述组合物挤出成细长产品，和（ c）将所述产物拉伸低于聚合物的熔点，其中在步骤（a）中，所述组合物是纳米管在聚合物溶液中的胶态分散体。 本发明的优点包括生产细长产品，如具有较高拉伸性能的纤维，特别是强度，具有比已知方法更低的纳米管浓度。 本发明还涉及通过根据本发明的方法获得的含有纳米管的高强度细长产品，特别是含有拉伸强度高于3.0GPa的纳米管的聚烯烃纤维。 本发明还涉及制造复合制品的方法，其中使用根据本发明的高强度细长产品，优选纤维，以及包含所述产品的抗弹道复合材料。

    Polyethylene multi-filament yarn
    4.
    发明公开
    Polyethylene multi-filament yarn 审中-公开
    的聚乙烯，Multifilamentgarn

    公开(公告)号：EP1746187A1

    公开(公告)日：2007-01-24

    申请号：EP05076648.4

    申请日：2005-07-18

    申请人： DSM IP Assets B.V.

    发明人： Simmelink, Joseph Arnold Paul Maria ,  van der Werff, Harm ,  Marissen, Roelof

    IPC分类号： D01F6/04 ,  D01F1/10

    CPC分类号： D01F6/04 ,  D01F1/10 ,  Y10T442/671

    摘要： The invention relates to a process for making a polyethylene multi-filament yarn comprising the steps of
    a) spinning multiple filaments from a solution comprising between 0.5 and 30 mass% of ultra high molecular weight polyethylene in a solvent;
    b) cooling the filament obtained to form gel filaments;
    c) removing at least partly the solvent from the gel filaments;
    d) drawing the filaments in at least one drawing step with a draw ration of more than 15 before, during or after removing solvent to a strength of at least 1 GPa, characterized in that the solution further comprises between 0.1 and 7 mass% of a sorbitol derivative.
    The invention further relates to a high performance polyethylene multi-filament yarn having a strength of at least 1 GPa, characterized in that the yarn comprises between 0.1 and 5 mass% of a sorbitol derivative.

    摘要翻译： 本发明涉及一种制备聚乙烯复丝纱线的方法，包括以下步骤：a）在溶剂中从含有0.5至30质量％的超高分子量聚乙烯的溶液中纺出多根长丝; b）冷却获得的细丝以形成凝胶丝; c）至少部分地从凝胶丝中除去溶剂; d）在去除溶剂之前，期间或之后，在至少一个拉伸步骤中拉丝长度大于15的拉丝步骤，其强度至少为1GPa，其特征在于，所述溶液还包含0.1至7质量％的 山梨醇衍生物。 本发明还涉及强度至少为1GPa的高性能聚乙烯复丝，其特征在于，所述纱线含有0.1〜5质量％的山梨糖醇衍生物。

    Process for the production of an isotropic polymeric network
    6.
    发明公开
    Process for the production of an isotropic polymeric network 审中-公开
    Verfahren zur Herstellung eines isotropen polymeren Netzwerks

    公开(公告)号：EP1486527A1

    公开(公告)日：2004-12-15

    申请号：EP03076841.0

    申请日：2003-06-13

    申请人： DSM IP Assets B.V.

    发明人： Marissen, Roelof ,  Lange, Ronald Frans Maria ,  Put, Jozef Albert ,  van Dijk, Joachim

    IPC分类号： C08G83/00

    CPC分类号： C08G61/122 ,  C08G61/02 ,  C08G61/12

    摘要： The present invention relates to a process for the production of an isotropic polymeric network comprising multifunctional molecules with a functionality, n, of at least 5 by contacting in a solvent an amount of the multifunctional molecules with an amount of a coupling agent, whereby through supramolecular chemistry a bond between the multifunctional molecule and the coupling agent is formed.
    The invention furthermore relates to an isotropic polymeric network with a density lower than 1300 kg/m 3 and a specific Young's modulus of at least 0.007 GPa.m 3 /kg, shaped articles hereof and the use of the isotropic polymeric network as construction material.

    摘要翻译： 本发明涉及生产各向同性聚合物网络的方法，其包括通过在溶剂中使一定量的多官能分子与一定量的偶联剂接触而具有官能度n至多为5的多官能分子，由此通过超分子 形成多功能分子与偶联剂之间的化学键。 本发明还涉及密度低于1300kg / m 3，特定杨氏模量至少为0.007GPa.m 3 / kg的各向同性聚合物网络，其成型制品和 各向同性聚合物网络作为建筑材料。

    Bone fixing device
    7.
    发明公开
    Bone fixing device 审中-公开
    Vorrichtung zur Knochenfixation

    公开(公告)号：EP1444959A1

    公开(公告)日：2004-08-11

    申请号：EP03075368.5

    申请日：2003-02-07

    申请人： DSM IP Assets B.V.

    发明人： Dirks, Christiaan Henri Peter ,  Marissen, Roelof

    IPC分类号： A61B17/82

    CPC分类号： A61B17/8869 ,  A61B17/82

    摘要： Closed loop of high performance polyethylene fibers for use as a bone-fixing tool, and method for fixing bone parts by a surgical cable comprising the steps of laying the surgical cable, having two end parts, around at least part of the bone parts to be fixed, exerting a force on the end parts bringing the cable under a tension required for the fixing of the bone parts and locking the tensioned cable against the influence of forces acting counter to the exerted force.

    摘要翻译： 用作骨固定工具的高性能聚乙烯纤维的闭环，以及通过手术电缆固定骨部件的方法，包括以下步骤：将具有两个端部的手术电缆放置在至少部分骨部分周围 固定，在端部上施加力，使得电缆处于固定骨部件所需的张力并且锁定张紧的电缆免受与施加的力相反的力的影响。

    Bone fixing device
    10.
    发明公开
    Bone fixing device 审中-公开
    骨固定装置

    公开(公告)号：EP1444960A1

    公开(公告)日：2004-08-11

    申请号：EP03075381.8

    申请日：2003-02-07

    申请人： DSM IP Assets B.V.

    发明人： Marissen, Roelof ,  Wetzels, Karel Jozef

    IPC分类号： A61B17/82 ,  A61B17/04

    CPC分类号： A61B17/823 ,  A61B17/0487 ,  A61B17/842 ,  A61B2017/0459

    摘要： Bone fixing device comprising a surgical cable having a first and a second end and at least two fixing plates having a central hole and a ring surrounding the hole, the ring having an inner edge adjacent to the hole and an outer edge along a circumference of the fixing plate, the two fixing plates being in a stacked position leaving a gap between them and the holes at least partly overlapping each other, at least one end of the cable following a continuous trajectory comprising a first upward part (a) running through the hole, an outward part (b) running over one ring in the direction of its outer edge, a downward part (c) outside the outer edge running in a direction opposite to the upward part, a second upward part (d) running through the hole in the first direction and a part (e) running through the gap between the fixing plates, the other end also being connected to the fixing plates.

    摘要翻译： 骨固定装置，包括具有第一端和第二端的手术线缆以及具有中心孔和围绕该孔的环的至少两个固定板，该环具有邻近该孔的内边缘和沿该外周边的外边缘 所述两个固定板处于堆叠位置，在它们之间留有间隙并且所述孔至少部分地彼此重叠，所述缆线的至少一个端部沿着连续轨迹包括穿过所述孔的第一向上部分（a） （b）在其外边缘的方向上延伸超过一个环，在与所述向上部分相反的方向延伸的所述外边缘之外的向下部分（c），穿过所述孔的第二向上部分（d） 在第一方向上和穿过固定板之间的间隙的部分（e），另一端也连接到固定板。