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1.发明授权PROCESS FOR THE PREPARATION OF AN ELASTOMERIC POLYMER FROM ETHYLENE, ALPHA-OLEFIN AND OPTIONALLY DIENE 失效方法用于生产弹性体由乙烯，ALFA-烯烃和IF DIEN
公开(公告)号：EP0758346B1
公开(公告)日：1998-07-29
申请号：EP95914581.4
申请日：1995-04-18
申请人： DSM N.V.
IPC分类号： C08F210/16 , C08F4/602
CPC分类号： C08F210/18 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F210/16 , C08F210/06 , C08F2500/17 , C08F2500/09 , C08F2500/21 , C08F2500/05 , C08F2500/25
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公开(公告)号：EP0835271A1
公开(公告)日：1998-04-15
申请号：EP96921153.0
申请日：1996-06-26
申请人： DSM N.V.
CPC分类号： C08F210/18 , C08F4/65908 , C08F4/6592 , C08F210/16 , C08F210/06 , C08F2500/03 , C08F2500/09
摘要： The invention relates to an elastomeric copolymer comprising 25-85 wt.% of ethylene, 15-75 wt.% of α-olefine and optionally up to 20 wt.% of diene. It is characterized in that the copolymer has a Uniform Branching Coefficient, UBC, which satisfies the relation (a). The invention also relates to a process for the preparation of such an elastomeric copolymer. In this process a catalyst having a reactivity factor RF
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3.发明公开PROCESS FOR THE PREPARATION OF AN ETHYLENE AND $g(a)-OLEFIN COPOLYMER 失效METHOD FOR PRODUCTION的乙烯/α-烯烃共聚物的
公开(公告)号：EP0896599A1
公开(公告)日：1999-02-17
申请号：EP97919763.0
申请日：1997-05-01
申请人： DSM N.V.
发明人： RENKEMA, Jacob , MUSKENS, Bernardus, Johanna , VAN BEEK, Johannes, Antonius, Maria , VAN DOREMEALE, Gerardus, Henricus, Josephus
CPC分类号： C08F10/00 , C08F4/63908 , C08F4/6392
摘要： The present process preparing an ethylene/α-olefin copolymer is conducted in the presence of a novel transition metal complex and co-catalyst. The process is further characterizable in that the transition metal complex is a reduced transition metal complex, selectable from groups 4-6 of the Periodic System of the Elements, with a multidentate monoanionic ligand and with two monoanionic ligands, at a temperature of between 100 and 220 °C. In particular the reduced transition metal in the complex is titanium (Ti (III)).
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公开(公告)号：EP0674665A1
公开(公告)日：1995-10-04
申请号：EP94903133.0
申请日：1993-12-01
申请人： DSM N.V.
发明人： RENKEMA, Jacob , KONINGS, Jeroen, Hubertina, Gerardus , MUSKENS, Bernardus, Johanna , RADEMAKERS, Gerardus, Arnoldus , PERSAD, Radjindrakumar , VERWEIJ, Petronella, Danielle
摘要： The invention relates to a catalyst that is suitable for the preparation, via a Ziegler polymerisation, of an olefine polymer, comprising an organometallic compound and a transition metal-imidoaryl complex, characterised in that the complex contains at least one amido group bound to the transition metal, the aryl group in the complex being an o,o-disubstituted phenyl group.
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公开(公告)号：EP0792296A1
公开(公告)日：1997-09-03
申请号：EP95936797.0
申请日：1995-10-31
申请人： DSM N.V.
CPC分类号： C08F210/18 , C08F10/00 , C08F210/16 , C08F4/602 , C08F210/06 , C08F2500/04 , C08F2500/21 , C08F2500/25
摘要： The invention relates to a process for the preparation of a rubber-like copolymer of ethene, one or more α-olefins and optionally one or more polyunsaturated compounds, under the influence of a catalyst system comprising a transition metal compound, the transition metal being chosen from groups 3-6 of the Periodic System of the Elements, an organometal compound and optionally a promoter, characterized in that the organometal compound in the catalyst system to be used is an amido complex that answers the general formula (I): Ru-Me1-X1v-(NR1R2)w, where Me1 is a metal chosen form group 1, 2, 12 or 13 of the Periodic System of the Elements, each R separately represents a hydrocarbon group having 1-20 C-atoms, NR1R2 is an amido group, with R?1 and R2¿, bridged or not bridged, being the same or different and representing hydrogen or a hydrocarbon group having 1-20 C-atoms or a group of the general formula: MR33, where M is an element that has been chosen from group 14 of the Periodic System of the Elements, each R3 separately represents hydrogen, a hydrocarbon group having 1-20 C-atoms or a group containing a hetero atom, X1 is a halogen atom, u+v+w=p and 0∫w∫p, p representing the valency of Me1.
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公开(公告)号：EP0674665B1
公开(公告)日：1997-04-09
申请号：EP94903133.0
申请日：1993-12-01
申请人： DSM N.V.
发明人： RENKEMA, Jacob , KONINGS, Jeroen, Hubertina, Gerardus , MUSKENS, Bernardus, Johanna , RADEMAKERS, Gerardus, Arnoldus , PERSAD, Radjindrakumar , VERWEIJ, Petronella, Danielle
IPC分类号： C08F4/62 , C08F10/00 , C08F210/16
摘要： The invention relates to a catalyst that is suitable for the preparation, via a Ziegler polymerisation, of an olefine polymer, comprising an organometallic compound and a transition metal-imidoaryl complex, characterised in that the complex contains at least one amido group bound to the transition metal, the aryl group in the complex being an o,o-disubstituted phenyl group.
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公开(公告)号：EP0792296B1
公开(公告)日：1999-06-16
申请号：EP95936797.0
申请日：1995-10-31
申请人： DSM N.V.
CPC分类号： C08F210/18 , C08F10/00 , C08F210/16 , C08F4/602 , C08F210/06 , C08F2500/04 , C08F2500/21 , C08F2500/25
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8.发明公开PROCESS FOR THE PREPARATION OF AN ELASTOMERIC POLYMER FROM ETHYLENE, ALPHA-OLEFIN AND OPTIONALLY DIENE 失效方法用于生产弹性体由乙烯，ALFA-烯烃和IF DIEN
公开(公告)号：EP0758346A1
公开(公告)日：1997-02-19
申请号：EP95914581.0
申请日：1995-04-18
申请人： DSM N.V.
CPC分类号： C08F210/18 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F210/16 , C08F210/06 , C08F2500/17 , C08F2500/09 , C08F2500/21 , C08F2500/05 , C08F2500/25
摘要： The invention relates to a process for the preparation of a polymer from ethylene, an α-olefin and optionally a diene, according to which these monomers are polymerised under the influence of a metallocene catalyst, the polymerisation taking place in the presence of a catalyst comprising a specific 2-indenyl metallocene, resulting in a bimodal, elastomeric polymer with a molecular weight distribution of more than 3.5, under such reaction conditions that the amount of water in the polymerisation medium is smaller than 0.5 ppm. The invention also relates to polymers with a specific branching index.
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