公开(公告)号：EP1221449A1

公开(公告)日：2002-07-10

申请号：EP00204745.4

申请日：2000-12-22

申请人： DSM N.V. ,  HILTI Aktiengesellschaft

发明人： Udding, Jan Henderikus ,  Wolters, Agnes Elisabeth ,  Wilhelm, Heinz ,  Pfeil, Armin ,  Bürgel, Thomas ,  Sager, Lutz

IPC分类号： C08F4/32

CPC分类号： C07C407/006 ,  C07C407/00 ,  C08F4/32 ,  C07C409/22 ,  C07C409/38 ,  C07C409/34 ,  C07C409/10

摘要： The invention relates to peroxide compositions comprising a reactive diluent for the peroxide, wherein the diluent is a component containing one or more vinyl ether group(s) and having a monomeric structure according to formula 1, (A-CH=CH-O) n -R, or being covalently built-in into a suitable resinous compound. In the formula

A represents hydrogen or an alkyl group with 1-3 C atoms, and individual A groups may be different
R either represents an aliphatic group, optionally branched, with 1-20 C atoms, etc.
or represents a polyethylene or polypropylene glycol with 2 to 10 glycol units, etc. and
n is 1, 2, 3 or 4.

The components with one or more vinyl ether group(s) covalently built-in into a suitable resinous compound are obtained by reaction of:

a) a first compound (the HVE-compound) containing at least one hydroxyl group and at least one vinyl ether group, and
b) a second compound (the D/HIC-compound), being an isocyanate, reacting with formation of one or more urethane group(s), and
c) a third compound (the G/P/HP-compound) chosen from the groups of (1) C 2-6 glycols, (2) C 5-20 polyols having 2-5 hydroxyl groups and (3) hydroxyl terminated polyester compounds, not being alkyd resins, having 1-5 free hydroxyl groups and from 2-50 monomeric ester units (the G/P/HP-compound), or mixtures thereof.

The invention also relates to the preparation of such compositions and to the use of such reactive diluents for peroxides in radically curing of unsaturated polyester resins for structural applications.

摘要翻译： 本发明涉及包含用于过氧化物的反应性稀释剂的过氧化物组合物，其中稀释剂是含有一个或多个乙烯基醚基团并且具有根据式1的单体结构的组分（A-CH = CH-O）nR ，或共价内置成合适的树脂化合物。 式A表示氢或具有1-3个C原子的烷基，各A基可以不同，R表示任选支链的1-20个C原子的脂族基团等，或代表聚乙烯或聚丙二醇 具有2至10个二醇单元等，n为1,2,3或4.通过以下反应获得共价掺入合适的树脂化合物的具有一个或多个乙烯基醚基团的组分：a）a 含有至少一个羟基和至少一个乙烯基醚基的第一化合物（HVE-化合物）和b）作为异氰酸酯的第二化合物（D / HIC-化合物）与形成一种或多种氨基甲酸酯基团 和（c）选自（1）C2-6二元醇，（2）具有2-5个羟基的C5-20多元醇的组的第三化合物（G / P / HP-化合物）和（3） 羟基封端的聚酯化合物，不是醇酸树脂，具有1-5个游离羟基和2-50个单体酯单元（G / P / HP-化合物），或其混合物 F。 本发明还涉及这种组合物的制备以及这种用于过氧化物的这种反应性稀释剂用于结构应用的不饱和聚酯树脂的自由基固化的用途。

公开(公告)号：EP1217017A1

公开(公告)日：2002-06-26

申请号：EP00204736.3

申请日：2000-12-22

申请人： DSM N.V. ,  HILTI Aktiengesellschaft

发明人： Udding, Jan Henderikus ,  Wolters, Agnes Elisabeth ,  Wilhelm, Heinz ,  Pfeil, Armin ,  Bürgel, Thomas ,  Sager, Lutz

IPC分类号： C08F283/00

CPC分类号： C08G18/672 ,  C04B40/065 ,  C08F283/01 ,  C08G18/6715 ,  C08L67/06 ,  C04B26/18 ,  C04B26/02 ,  C08L75/04

摘要： The invention relates to radically curable resin mortars, containing unsaturated polyester and a reactive diluent, for use as A-component in two-component (+ B-component containing peroxide and possibly an extender) for chemical fastening systems, wherein the diluent in the A-component is either a monomeric component according to formula 1

        (A-CH=CH-O) n -R     (formula 1)

or a resinous compound, in which a monomeric component having vinyl ether group(s) has been built-in covalently, and the content of the component containing one or more vinyl ether group(s) being from 0.5 to 50 wt.%, calculated (as indicated) as weight percentage relative to the resin composition. A, R and n are specified as hydrogen or C 1-3 alkyl; C 1-20 (hetero)-aliphatic with hydroxyl or amino groups, or poly(C 2 or 3 )glycol with 2-10 glycol units; and 1 to 4, respectively.
The resinous compounds with buit-in vinyl ether group(s) (0.5 to 50 wt.%, calculated as indicated).are obtained by reaction of a mixture of appropriate amounts of:

a) a first compound (HVE) containing hydroxyl group(s) and at least one vinyl ether group, and
b) a second compound (D/HIC), being an isocyanate; and
c) a third compound (G/P/HP) from (1) C 2-6 glycols, (2) C 5-20 polyols having 2-5 hydroxyl groups and (3) hydroxyl terminated polyester compounds, not being alkyd resins, having 1-5 free hydroxyl groups and 2-50 monomeric units, or mixtures thereof.

The invention also relates to two-component chemical fastening systems comprising such curable mortar and a B-component, as well as to methods of preparing such mortars and use thereof for chemical fastening.

摘要翻译： 本发明涉及含有不饱和聚酯和反应性稀释剂的自由基固化树脂砂浆，用作用于化学紧固系统的双组分（含B +成分的过氧化物和可能的增量剂）中的A成分，其中A中的稀释剂 - 组分是根据式1（A-CH = CH-O）nR的单体组分或其中共聚有内含乙烯基醚基团的单体组分的树脂化合物， 含有一个或多个乙烯基醚基团的组分为0.5至50重量％，以相对于树脂组合物的重量百分数计算（如所示）。 A，R和n指定为氢或C 1-3烷基; 具有羟基或氨基的C1-20（杂）脂族基或具有2-10个二醇单元的聚（C2或3）二醇; 和1至4。 通过使适量的混合物反应获得含有乙烯基醚基团的树脂化合物（按所示计算为0.5至50重量％）：a）含有羟基的第一化合物（HVE）（ s）和至少一种乙烯基醚基团，和b）第二化合物（D / HIC），其为异氰酸酯; 和c）来自（1）C2-6二醇的第三化合物（G / P / HP），（2）具有2-5个羟基的C5-20多元醇和（3）羟基封端的聚酯化合物，不是醇酸树脂， 1-5个游离羟基和2-50个单体单元，或其混合物。 本发明还涉及包含这种可固化砂浆和B组分的双组分化学紧固系统，以及制备这种砂浆的方法及其用于化学固定的方法。

公开(公告)号：EP1225189A1

公开(公告)日：2002-07-24

申请号：EP00204744.7

申请日：2000-12-22

申请人： DSM N.V. ,  HILTI Aktiengesellschaft

发明人： Udding, Jan Henderikus ,  Wolters, Agnes Elisabeth ,  Wilhelm, Heinz ,  Pfeil, Armin ,  Bürgel, Thomas ,  Sager, Lutz

IPC分类号： C08F283/01 ,  C08F283/00 ,  C09D5/34 ,  C08F290/06

CPC分类号： C08G18/672 ,  C08F283/00 ,  C08F283/01 ,  C08F290/06 ,  C08G18/6715

摘要： The invention relates to two-component chemical fastening systems, the A-component containing an unsaturated polyester and a reactive diluent, and the B-component containing a peroxide and an extender, wherein the extender is either a monomeric component according to formula 1

        (A-CH=CH-O) n -R     (formula 1)

or a resinous compound, in which a monomeric component having vinyl ether group(s) has been built-in covalently, and the content of the peroxide in the B-component is from 0.5 to 99 wt.%. In the formula A, R and n are specified as hydrogen or C 1-3 alkyl; C 1-20 (hetero)-aliphatic with hydroxyl or amino groups, or poly(C 2 or 3 )glycol with 2-10 glycol units; and 1 to 4, respectively.
The resinous compounds with built-in vinyl ether group(s) (0.5 to 50 wt.%, calculated as indicated) are obtained by reaction of a mixture of appropriate amounts of:

a) a first compound (HVE) containing at least one hydroxyl group and at least one vinyl ether group, and
b) a second compound (D/HIC), being an isocyanate; and
c) a third compound (G/P/HP) from (1) C 2-6 glycols, (2) C 5-20 polyols having 2-5 hydroxyl groups and (3) hydroxyl terminated polyester compounds, not being alkyd resins, having 1-5 free hydroxyl groups and 2-50 monomeric units, or mixtures thereof.

The invention also relates to methods for preparing (the B-component) of such two-component chemical fastening systems, as well as to use of the systems for chemical fastening.

摘要翻译： 本发明涉及双组分化学紧固系统，含有不饱和聚酯和反应性稀释剂的A组分和含有过氧化物和增量剂的B组分，其中增量剂是根据式1的单体组分（A -CH = CH-O）n R或其中具有乙烯基醚基团的单体成分共价共建的树脂化合物，B成分中的过氧化物的含量为0.5〜99重量％。 ％。 在式A中，R和n指定为氢或C 1-3烷基; 具有羟基或氨基的C1-20（杂）脂族基或具有2-10个二醇单元的聚（C2或3）二醇; 和1至4。 通过将适当量的混合物反应获得含有内置乙烯基醚基团（0.5至50重量％，按所示计算）的树脂化合物：a）含有至少一个羟基的第一化合物（HVE） 基团和至少一个乙烯基醚基团，和b）第二化合物（D / HIC），其为异氰酸酯; 和c）来自（1）C2-6二醇的第三化合物（G / P / HP），（2）具有2-5个羟基的C5-20多元醇和（3）羟基封端的聚酯化合物，不是醇酸树脂， 1-5个游离羟基和2-50个单体单元，或其混合物。 本发明还涉及制备这种双组分化学紧固系统（B组分）的方法以及使用该系统进行化学固定。

公开(公告)号：EP1221452A1

公开(公告)日：2002-07-10

申请号：EP00204746.2

申请日：2000-12-22

申请人： DSM N.V.

发明人： Udding, Jan Henderikus ,  Wolters, Agnes Elisabeth

IPC分类号： C08G18/67 ,  C08G18/68

CPC分类号： C08G18/6715 ,  C08G18/68

摘要： The invention relates to radically curable resin compositions comprising at least a resinous component with one or more vinyl ether group(s), and one or more reactive monomers, wherein said resinous component is obtained by reaction of a mixture of appropriate amounts of a) a compound containing at least one hydroxyl group and at least one vinyl ether group; b) a diisocyanate (or higher isocyanate) compound, reacting with formation of one or more urethane group(s); and c) a compound chosen from the groups of C 2-6 glycols, C 5-20 polyols having 2-5 hydroxyl groups and (un)saturated hydroxyl terminated polyester compounds, with 1-5 free hydroxyl groups and from 2-50 monomeric ester units, the content of vinyl ether groups in the resin composition being from 0.5 to 50 wt.%, calculated as the weight percentage of the HVE-compound relative to the total weight of the resin composition (excluding the weight of additives, fillers and the like),
the total acid number of the radically curable resin composition being less than 10 mg of KOH per g, and wherein the curing is effected with the aid of a radical-forming system that is unstable in the temperature range from -20°C to + 110°C.
The invention also relates to a process for the preparation of such resin compositions and uses thereof.

摘要翻译： 本发明涉及自由基固化树脂组合物，其包含至少一种具有一个或多个乙烯基醚基团的树脂组分和一种或多种反应性单体，其中所述树脂组分通过将适量的a） 含有至少一个羟基和至少一个乙烯基醚基团的化合物; b）与形成一种或多种氨基甲酸酯基团反应的二异氰酸酯（或更高级的异氰酸酯）化合物; 和c）选自C 2-6二元醇，具有2-5个羟基的C5-20多元醇和具有1-5个游离羟基的（未）饱和羟基封端的聚酯化合物和2-50个单体酯单元的化合物 ，树脂组合物中乙烯基醚基的含量为0.5〜50重量％，以HVE-化合物的重量百分数计，相对于树脂组合物的总重量（不包括添加剂的重量，填料等） ），自由基固化性树脂组合物的总酸值小于10mg每克KOH，其中固化是在自由基形成体系的帮助下进行的，所述自由基形成体系在-20℃至 + 110℃。本发明还涉及制备这种树脂组合物的方法及其应用。