POLYOLEFIN RESIN COMPOSITION AND PRODUCTION METHOD OF SAME

    公开(公告)号:EP3778668A1

    公开(公告)日:2021-02-17

    申请号:EP19781049.2

    申请日:2019-04-02

    摘要: Disclosed are a polyolefin resin composition and a production method using same. Provided is a polyolefin resin which satisfies the following conditions: (1) melt index (MI2.16, 190 °C, under a load of 2.16 kg) is 0.1 to 1.5 g/10 min; (2) density is 0.91 to 0.93 g/cc; (3) polydispersity Index (Mw(weight-average molecular weight)/Mn(number-average molecular weight)) is 3 to 7; (4) Mz(Z-average molecular weight)/Mw(weight-average molecular weight) is 2.3 to 4.5; and (5) COI (Comonomer Orthogonal Index) value calculated by Equation 1 in the specification is 5 to 12. In Equation 1, "SCB number at Mz" represents average number of branches derived from comonomers per 1000 carbon atoms at Z-average molecular weight (Mz), and "SCB number at Mn" represents average number of branches derived from comonomers per 1000 carbon atoms at number-average molecular weight (Mn) when a molecular weight- comonomer distribution graph was prepared in which log value (log Mw) of molecular weight (Mw) is marked in x-axis of the graph and the amount of polymer (dw_dlog Mw) corresponding to the log value (log Mw) and average number of short chain branches (SCB) derived from comonomer (number of branches per 1,000 carbon atoms, unit: number/1,000C) corresponding to the log value (log Mw) are marked in y-axis of the graph.

    ETHYLENE AND ALPHA-OLEFIN POLYMERIZATION APPARATUS AND PREPARATION METHOD
    2.
    发明公开
    ETHYLENE AND ALPHA-OLEFIN POLYMERIZATION APPARATUS AND PREPARATION METHOD 审中-公开
    乙烯 - 烯烃聚合反应

    公开(公告)号:EP3093070A1

    公开(公告)日:2016-11-16

    申请号:EP15733221.4

    申请日:2015-01-02

    IPC分类号: B01J19/24 C08F10/06

    摘要: Disclosed are an apparatus and a method for polymerization that can economically copolymerize ethylene and alpha-olefin by reusing reacting raw materials and solvents. The apparatus for polymerization of ethylene and alpha-olefin comprises: a polymerization reactor in which ethylene and alpha-olefin are supplied as reaction raw materials along with a solvent, and the reaction raw materials are copolymerized in a solution state, to thereby produce a polymerization product comprising an ethylene and alpha-olefin copolymer dissolved in the solvent; a unit for separating unreacted ethylene, alpha-olefin, low molecular weight oligomer and a polymer, including a flash tower for distilling and separating the unreacted ethylene and alpha-olefin contained in the polymerization product, and a stripper unit for distilling and separating the solvent and the low molecular weight oligomer having a lower molecular weight than the molecular weight of the ethylene and alpha-olefin copolymer contained in the polymerization product; and a solvent recovery unit for separating the low molecular weight oligomer from the separated low molecular weight oligomer and solvent and recovering the solvent.

    摘要翻译: 公开了可以通过重复使用原料和溶剂的反应来经济地共聚乙烯和α-烯烃的聚合装置和方法。 乙烯和α-烯烃的聚合装置包括:其中乙烯和α-烯烃与溶剂一起作为反应原料供应的聚合反应器,反应原料以溶液状态共聚,从而产生聚合 产物包含溶解在溶剂中的乙烯和α-烯烃共聚物; 用于分离未反应的乙烯,α-烯烃,低分子量低聚物和聚合物的单元,包括用于蒸馏和分离聚合产物中所含的未反应的乙烯和α-烯烃的闪蒸塔和用于蒸馏和分离溶剂的汽提器单元 低分子量低聚物的分子量低于聚合产物中所含的乙烯和α-烯烃共聚物的分子量; 以及用于从分离的低分子量低聚物和溶剂中分离低分子量低聚物并回收溶剂的溶剂回收单元。