摘要:
O-(Perfluoroalkyl)dibenzofuranium salt derivatives represented by general formula (1) (wherein Rf is perfluoroalkyl being 1 to 10 carbon atoms; and X- is a conjugate based of a Brønsted acid); intermediates for the preparation of the derivatives; a process for the preparation of the intermediates; perfluoroalkylating agents comprising the derivatives or the intermediates; and a process for perfluoroalkylation. The O-(perfluoroalkyl)dibenzofuranium salt derivatives are useful as perfluoroalkylating agents which permit high-yield perfluoroalkylation, and are applicable to a wide range of compounds and so inhibited in self-decomposition as to be relatively stable.
摘要:
O-(perfluoroalkyl)dibenzofuranium salt derivatives represented by the following general formula (1), (wherein Rf in said general formula (1) is a C1-10 perfluoroalkyl group and X - is a conjugate base of a Brönsted acid). Intermediates for preparation of the derivatives, a preparation method thereof, perfluoroalkylating agents comprising the said derivatives and the said preparation intermediates, and a perfluoroalkylating method. The present invention can provide O-(perfluoroalkyl)dibenzofuranium salt derivatives as perfluoroalkylating agents which show good yields in the perfluoroalkylation reaction, a wide range of application and comparatively stable properties with repressed self-decomposition, the intermediate for preparation thereof, a preparation method for the intermediates thereof, the perfluoroalkylating agents and a perfluoroalkylation method.