公开(公告)号：EP2022835B1

公开(公告)日：2018-04-11

申请号：EP07742962.9

申请日：2007-05-08

申请人： Denka Company Limited

发明人： EMOTO, Hideyuki ,  IBUKIYAMA, Masahiro ,  KAWASAKI, Takashi

IPC分类号： C09K11/64 ,  C04B35/597 ,  C04B35/626

CPC分类号： C09K11/7731 ,  C04B35/597 ,  C04B35/6262 ,  C04B2235/3208 ,  C04B2235/3217 ,  C04B2235/3224 ,  C04B2235/3865 ,  C04B2235/3873 ,  C04B2235/442 ,  C04B2235/445 ,  C04B2235/5409 ,  C04B2235/5436 ,  C04B2235/761 ,  C04B2235/766 ,  C04B2235/767 ,  C09K11/08 ,  C09K11/0883 ,  C09K11/646 ,  C09K11/7721 ,  C09K11/7734 ,  H01L33/502 ,  Y10T428/2982

摘要： Phosphor that can provide white LED that uses a blue LED or an ultraviolet LED as a light source and that has superior luminous efficiency. This phosphor includes, as a main component, ±-type sialon represented by a general expression: (M1)x(M2)y(Si,Al) 12 (O,N) 16 (where M1 is one or more types of elements selected from a group consisting of Li, Mg, Ca, Y, and lanthanide element (except for La and Ce) and M2 is one or more types of elements selected from a group consisting of Ce, Pr, Eu, Tb, Yb, and Er, and 0.3‰¤X+Y‰¤1.5 and 0

公开(公告)号：EP3093327A3

公开(公告)日：2017-05-03

申请号：EP16150385.9

申请日：2007-05-08

申请人： Denka Company Limited

发明人： EMOTO, Hideyuki ,  IBUKIYAMA, Masahiro ,  KAWASAKI, Takashi

IPC分类号： C09K11/64 ,  C09K11/77 ,  C04B35/626 ,  C04B35/597 ,  H01L33/50

CPC分类号： C09K11/7731 ,  C04B35/597 ,  C04B35/6262 ,  C04B2235/3208 ,  C04B2235/3217 ,  C04B2235/3224 ,  C04B2235/3865 ,  C04B2235/3873 ,  C04B2235/442 ,  C04B2235/445 ,  C04B2235/5409 ,  C04B2235/5436 ,  C04B2235/761 ,  C04B2235/766 ,  C04B2235/767 ,  C09K11/08 ,  C09K11/0883 ,  C09K11/646 ,  C09K11/7721 ,  C09K11/7734 ,  H01L33/502 ,  Y10T428/2982

摘要： Phosphor that can provide white LED that uses a blue LED or an ultraviolet LED as a light source and that has superior luminous efficiency. This phosphor is composed of host material of β-type sialon represented by a general expression of Si 6-z Al z O z N 8-z (wherein 0.01≤z≤4.2) and includes 0.01 to 10atm% of a metal element M3, wherein M3 is one or more types of elements selected from among Mn, Ce, and Eu. Constituent particles of the phosphor have an average circularity degree of 0.75 or more, a particle size distribution D 50 of 5 to 30µm, and D 10 of 2.0µm or more. The particles of the phosphor includes light emission-related elements that have a low concentration in the interior of the particle and that have a high concentration at the outer periphery of the particle, and the light emission-related element at the outer periphery of the phosphor particle has a concentration 1.2 times or more higher than that of the light emission-related element at the interior of the particle.

摘要翻译： 可以提供使用蓝色LED或紫外线LED作为光源的白色LED的荧光粉，具有出色的发光效率。 该荧光体由Si6-zAlzOzN8-z（其中，0.01≤z≤4.2）的通式表示的β型赛隆的主体材料构成，并且包含0.01〜10原子％的金属元素M3，其中M3为1种以上 的选自Mn，Ce和Eu中的元素。 荧光体的构成粒子的平均圆形度为0.75以上，粒度分布D50为5〜30μm，D10为2.0μm以上。 荧光体的粒子包含在粒子内部具有低浓度且在粒子的外周具有高浓度的发光相关元素，并且在荧光体的外围处的发光相关元素 颗粒具有比颗粒内部的发光相关元件高1.2倍或更多的浓度。

公开(公告)号：EP3093327A2

公开(公告)日：2016-11-16

申请号：EP16150385.9

申请日：2007-05-08

申请人： Denka Company Limited

发明人： EMOTO, Hideyuki ,  IBUKIYAMA, Masahiro ,  KAWASAKI, Takashi

IPC分类号： C09K11/64 ,  C09K11/77 ,  C04B35/626 ,  C04B35/597 ,  H01L33/50

CPC分类号： C09K11/7731 ,  C04B35/597 ,  C04B35/6262 ,  C04B2235/3208 ,  C04B2235/3217 ,  C04B2235/3224 ,  C04B2235/3865 ,  C04B2235/3873 ,  C04B2235/442 ,  C04B2235/445 ,  C04B2235/5409 ,  C04B2235/5436 ,  C04B2235/761 ,  C04B2235/766 ,  C04B2235/767 ,  C09K11/08 ,  C09K11/0883 ,  C09K11/646 ,  C09K11/7721 ,  C09K11/7734 ,  H01L33/502 ,  Y10T428/2982

摘要： Phosphor that can provide white LED that uses a blue LED or an ultraviolet LED as a light source and that has superior luminous efficiency. This phosphor is composed of host material of β-type sialon represented by a general expression of Si 6-z Al z O z N 8-z (wherein 0.01≤z≤4.2) and includes 0.01 to 10atm% of a metal element M3, wherein M3 is one or more types of elements selected from among Mn, Ce, and Eu. Constituent particles of the phosphor have an average circularity degree of 0.75 or more, a particle size distribution D 50 of 5 to 30µm, and D 10 of 2.0µm or more. The particles of the phosphor includes light emission-related elements that have a low concentration in the interior of the particle and that have a high concentration at the outer periphery of the particle, and the light emission-related element at the outer periphery of the phosphor particle has a concentration 1.2 times or more higher than that of the light emission-related element at the interior of the particle.

摘要翻译： 可以提供使用蓝色LED或紫外线LED作为光源并具有优异发光效率的白色LED的荧光体。 该荧光体由Si 6-z Al z O z N 8-z（其中0.01‰¤‰‰4.2）的一般表达式所代表的²型赛隆的主体材料组成，并且包括0.01至10atm％的金属元素 M3，其中M3是选自Mn，Ce和Eu中的一种或多种元素。 荧光体的成分粒子的平均圆形度为0.75以上，粒径分布D 50为5〜30μm，D 10为2.0μm以上。 荧光体的粒子包括在粒子内部具有低浓度并且在粒子的外周具有高浓度的发光相关元素，在荧光体的外周的发光相关元素 颗粒的浓度比颗粒内部的发光相关元素的浓度高1.2倍以上。