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    A PROCESS FOR THE CONVERSION OF ALIPHATIC CYCLIC AMINES TO ALIPHATIC DIAMINES
    2.
    发明公开
    A PROCESS FOR THE CONVERSION OF ALIPHATIC CYCLIC AMINES TO ALIPHATIC DIAMINES 有权
    程序用于转换的脂环胺，脂肪族二胺

    公开(公告)号：EP2459513A2

    公开(公告)日：2012-06-06

    申请号：EP10739809.1

    申请日：2010-07-30

    申请人： Dow Global Technologies LLC

    发明人： FEIST, Shawn ,  HICKMAN, Daniel ,  MOLITOR, Erich ,  MOLZAHN, David ,  SANTHANY, Stacie ,  SCHUITMAN, Abraham

    IPC分类号： C07C209/22

    CPC分类号： C07C209/62 ,  C07C211/12 ,  C07C211/18 ,  C07C2601/14

    摘要： The instant invention is a process for the conversion of aliphatic cyclic amines to aliphatic diamines. The process for conversion of aliphatic cyclic amines to aliphatic diamines comprises the steps of: (1) selecting one or more cyclic amines; (2) contacting said one or more cyclic amines with ammonia and hydrogen, optionally water, and optionally one or more solvents in the presence of one or more heterogeneous metal based catalyst systems at a temperature in the range of from 120° C to about 250° C and a pressure in the range of from 700 to 3500 psig for a period in the range of at least one hour or more in one or more reactor systems; (3) forming a product mixture comprising one or more aliphatic diamine, optionally a portion of said one or more cyclic amines, optionally a portion of said ammonia, optionally a portion of said hydrogen, optionally water, and optionally a portion of said one or more solvents; (4) removing said product mixture from the reactor system; (5) removing at least a portion of said portion of ammonia, said portion of hydrogen, or mixture thereof from said product mixture via distillation; (6) removing at least a portion of said portion of water via distillation; (7) removing at least a portion of said portion of one or more optional solvents via distillation; (8) removing at least a portion of said portion of one or more cyclic amines; (9) thereby separating said one or more aliphatic diamines from said product mixture; and (10) thereby converting said one or more cyclic amines to one or more aliphatic diamines.

    PROCESS FOR REDUCTIVE AMINATION OF ALIPHATIC CYANOALDEHYDES TO ALIPHATIC DIAMINES
    5.
    发明公开
    PROCESS FOR REDUCTIVE AMINATION OF ALIPHATIC CYANOALDEHYDES TO ALIPHATIC DIAMINES 有权
    VERFAHRENFÜRDIE REDUKTIVE AMINIERUNG VON ALIPHTISCHEN CYANOALDEHYDEN ZU ALIPHATIS​​CHEN DIAMINEN

    公开(公告)号：EP2459515A2

    公开(公告)日：2012-06-06

    申请号：EP10739812.5

    申请日：2010-07-30

    申请人： Dow Global Technologies LLC

    发明人： MOLITOR, Erich ,  HICKMAN, Daniel ,  FEIST, Shawn ,  MOLZAHN, David ,  SANTHANY, Stacie ,  SCHUITMAN, Abraham

    IPC分类号： C07C209/48 ,  C07C209/26 ,  C07C211/18

    CPC分类号： C07C209/48 ,  C07C2601/14 ,  C07C211/18

    摘要： The instant invention provides a process for reductive amination of aliphatic cyanoaldehydes to aliphatic diamines, and aliphatic diamines produced via such method. The process for reductive amination of aliphatic cyanoaldehydes to aliphatic diamines comprises the steps of: (1) providing a mixture of one or more cycloaliphatic cyanoaldehydes, optionally water, and optionally one or more solvents, wherein said one or more cycloaliphatic cyanoaldehydes are selected from the group consisting of 1,3-cyanocyclohexane carboxaldehyde, 1,4-cyanocyclohexane carboxaldehyde, mixtures thereof, and combinations thereof; (2) contacting said mixture with a metal carbonate based solid bed or a weak base anion exchange resin bed at a temperature in the range of 15 to 40° C for a period of at least 1 minute or more, for example 5 minutes or more; (3) thereby treating said mixture, wherein said treated mixture has a pH in the range of 6 to 9; (4) feeding said treated mixture, hydrogen, and ammonia into a continuous reductive amination reactor system; (6) contacting said treated mixture, hydrogen, and ammonia with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature in the range of from 80° C to about 160° C and a pressure in the range of from 700 to 3500 psig; (7) thereby producing one or more cycloaliphatic diamines, wherein said one or more cycloaliphatic diamines are diamines selected from the group consisting of l,3-bis(aminomethyl)cyclohexane, l,4-bis(aminomethyl)cyclohexane, combinations thereof, and mixtures thereof.

    摘要翻译： 脂肪族氰醛还原胺化成脂肪族二胺的方法，包括（1）提供1,3-氰基环己烷甲醛和/或1,4-氰基环己烷甲醛的混合物; （2）将所述混合物与金属碳酸盐基固体床或弱碱性阴离子交换树脂床在15至40℃的温度下接触至少1分钟; （3），从而处理所述混合物，其中所述处理的混合物的pH在6至9的范围内; （4）将所述处理的混合物，氢气和氨进料到连续还原胺化反应器系统中; （6）在一种或多种非均相金属基催化剂体系的存在下，在80℃至160℃的温度和700至3500psig的压力下使所述经处理的混合物，氢气和氨彼此接触; （7），从而产生一种或多种脂环族二胺。

    CYCLOALIPHATIC DIAMINES AND METHOD OF MAKING THE SAME
    6.
    发明公开
    CYCLOALIPHATIC DIAMINES AND METHOD OF MAKING THE SAME 有权
    CYCLOALIPHATIS​​CHE DIAMINE UND HERSTELLUNGSVERFAHRENDAFÜR

    公开(公告)号：EP2459514A2

    公开(公告)日：2012-06-06

    申请号：EP10739807.5

    申请日：2010-07-30

    申请人： Dow Global Technologies LLC

    发明人： SCHUITMAN, Abraham ,  FEIST, Shawn ,  FISH, Barry ,  HICKMAN, Daniel ,  MOLITOR, Erich ,  TULCHINSKY, Michael

    IPC分类号： C07C209/26

    CPC分类号： C07C209/48 ,  C07C209/26 ,  C07C2601/14 ,  C07C211/18

    摘要： The instant invention provides cycloaliphatic diamines and a method of making the same. The cycloaliphatic diamines according to the instant invention comprise the reaction product of one or more cycloaliphatic cyanoaldehydes selected from the group consisting of 1,3-cyanocyclohexane carboxaldehyde, 1,4-cyanocyclohexane carboxaldehyde, mixtures thereof, and combinations thereof, hydrogen, and ammonia fed into a continuous reductive amination reactor system; wherein the one or more cycloaliphatic cyanoaldehydes, hydrogen, and ammonia are contacted with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature in the range of from 80° C to about 160° C and a pressure in the range of from 700 to 3500 psig; and wherein one or more cycloaliphatic diamines are formed; and wherein said one or more cycloaliphatic diamines are selected from the group consisting of 1,3- bis(aminomethyl)cyclohexane, 1,4-bis(aminomethyl)cyclohexane, combinations thereof, and mixtures thereof.

    摘要翻译： 本发明提供脂环族二胺及其制备方法。 根据本发明的脂环族二胺包括一种或多种选自1,3-氰基环己烷甲醛，1,4-氰基环己烷甲醛，其混合物及其组合的脂环族氰醛的反应产物，氢和氨进料 成为连续还原胺化反应器系统; 其中所述一种或多种环脂族氰醛，氢和氨在一种或多种非均相金属基催化剂体系的存在下在80℃至约160℃的温度下彼此接触，并且压力 在700至3500psig范围内; 并且其中形成一种或多种脂环族二胺; 并且其中所述一种或多种脂环族二胺选自1,3-双（氨基甲基）环己烷，1,4-双（氨基甲基）环己烷，其组合，及其混合物。

    A PROCESS FOR SEPARATING ONE OR MORE ALIPHATIC DIAMINES FROM REDUCTIVE AMINATION REACTION SOLVENTS AND IMPURITIES
    10.
    发明公开
    A PROCESS FOR SEPARATING ONE OR MORE ALIPHATIC DIAMINES FROM REDUCTIVE AMINATION REACTION SOLVENTS AND IMPURITIES 有权
    方法用于生产和一种或多种脂族二胺SOLVENTS分离和外地代理还原胺化反应

    公开(公告)号：EP2459516A2

    公开(公告)日：2012-06-06

    申请号：EP10739811.7

    申请日：2010-07-30

    申请人： Dow Global Technologies LLC

    发明人： SANTHANY, Stacie ,  AU-YEUNG, Patrick ,  DARE, Gerald ,  FEIST, Shawn ,  FISH, Barry ,  HICKMAN, Daniel ,  JEAN, David ,  MOLITOR, Erich ,  SCHUITMAN, Abraham ,  TOYZAN, Todd

    IPC分类号： C07C209/84

    CPC分类号： C07C209/86 ,  C07C2601/14 ,  C07C211/28

    摘要： The instant invention provides a process for separating one or more aliphatic diamines from reductive amination reaction solvents and impurities, and aliphatic diamines obtained via such a process. The process for separating one or more aliphatic diamines from reductive amination reaction solvents and impurities according to the instant invention comprises the steps of: (1) feeding one or more cycloaliphatic cyanoaldehydes, hydrogen, ammonia, and optionally one or more solvents into a continuous reductive amination reactor system; (2) contacting said one or more cycloaliphatic cyanoaldehydes, hydrogen, and ammonia with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature in the range of from 80° C to about 160° C and a pressure in the range of from 700 to 3500 psig; (3) thereby forming a product mixture comprising one or more cycloaliphatic diamines, optionally one or more bicyclic by-products, optionally one or more cycloaliphatic aminonitriles, optionally one or more cycloaliphatic aminoalcohols, optionally one or more oligomeric by-products, ammonia, water, hydrogen, and optionally one or more solvents; (4) removing said product mixture from the reactor system; (5) removing at least a portion of said ammonia, said hydrogen, or mixture thereof from said product mixture via distillation; (6) removing at least a portion of said water and said one or more optional solvents via distillation; (7) removing at least a portion of one or more optional bicyclic by-products via distillation; (8) removing one or more optional cycloaliphatic aminonitriles, one or more optional cycloaliphatic aminoalcohols, one or more optional oligomeric by-products via distillation; and (9) thereby separating said one or more cycloaliphatic diamines from said product mixture.

    摘要翻译： 本发明提供用于分离一种或还原阿米娜灰反应溶剂和杂质，并且经由检索处理得到的脂肪族二胺更多脂族二胺的方法。 用于分离一种或还原阿米娜灰反应溶剂和杂质雅丁给本发明以上的脂肪族二胺的方法，包括以下步骤：（1）将一种或多种脂环族氰基，氢，氨和任选的一种或多种溶剂为连续还原 阿米娜和灰的反应器系统; （2）使所述一种或多种脂环族氰基，氢，和氨海誓山盟在一种或多种非均相基于金属的催化剂体系的在温度从80℃至约160℃，范围内的存在 压力在700至3500 psig的的范围内; （3）由此形成的产物混合物，其包括副产物的一种或多种脂环族二胺，任选的一种或多种双环副产物，任选的一种或多种脂环族的氨基腈，任选的一种或多种脂环族氨基醇，任选的一种或多种低聚，氨，水 ，氢，和任选的一种或多种溶剂; （4）从该反应器系统，其中所述产品混合物; （5）去除至少所述氨，所述氢，或它们的混合物从蒸馏经由所述产品混合物的一部分; （6）除去至少一部分水和所述一个或经由蒸馏多种任选的溶剂; （7）除去至少一个副产物通过蒸馏一种或多种任选的双环部分; （8）去除一个或多个任选的脂环族氨基腈，一种或多种任选的环脂族氨基醇，副产物通过蒸馏一种或多种任选的低聚; 和（9），从而从所述产品混合物中分离所述一种或多种脂环族二胺。