COATING COMPOSITIONS AND PROCESS FOR THE PRODUCTION OF MULTILAYER COATINGS
    4.
    发明授权
    COATING COMPOSITIONS AND PROCESS FOR THE PRODUCTION OF MULTILAYER COATINGS 有权
    涂料组合物及其制造方法多层涂层

    公开(公告)号:EP1817386B1

    公开(公告)日:2010-01-13

    申请号:EP05803025.5

    申请日:2005-09-29

    IPC分类号: C09D175/04 C08G18/40

    摘要: An aqueous coating composition, comprising A) at least one water-dilutable hydroxy-functional binder and B) at least one polyisocyanate crosslinking agent with free isocyanate groups, wherein component A) comprises A1) 40-95 wt.% of at least one water-dilutable hydroxy-functional (meth)acrylic copolymer with a hydroxyl value of 60-250 mg of KOH/g and an acid value of 5-50 mg of KOH/g, which is obtained by free-radical copolymerization performed in a non-aqueous phase, wherein the ratio of primary hydroxyl groups to secondary hydroxyl groups in the (meth)acrylate copolymer A1) is 1: 0.1 to 1 :1.2 and at least 80% of the secondary hydroxyl groups result from reaction products of a monoepoxy ester and an unsaturated acid-functional monomer, and A2) 5-60 wt.% of at least one water-dilutable polyester oligomer, wherein the total of the weight percentages of component A1) and A2) add up to 100 wt.% and wherein the free-radical polymerization for the production of component A1) is performed at least in part in the presence of component A2) and/or wherein component A2) is added during polymerization or after completion of polymerization.