摘要:
The present invention relates to the composition and process for making (meth)acrylate amide acetals. The present invention further relates to novel poly(meth)acrylate compositions formed by polymerization of these (meth)acrylate amide acetals, and their inclusion in crosslinked coatings.
摘要:
The present invention is directed to two component coating compositions that cure under ambient conditions and more particularly to those having low VOC (volatile organic content) that are suitable for use in automotive refinish and Original Equipment Manufacturing (OEM) applications. The coating composition includes crosslinkable and crosslinking components, wherein the crosslinkable component includes a low polydispersity, low molecular weight copolymer having on an average 2 to 25 functional groups, such as hydroxyl, amine, acetoacetoxy and secondary amine. The copolymer is polymerized from a monomer mixture that includes one or more non-functional acrylate monomers and one or more functional methacrylate monomers provided with the functional groups. The crosslinking component includes polyisocyanate, ketimine, melamine, or a combination thereof. The invention is also directed to coating produced from the coating composition.
摘要:
A coating composition containing about 40-90% by weight of film forming binder and 10-60% by weight of an organic liquid carrier; wherein the binder contains about (a) 10-70% by weight, based on the weight of the binder, of a dispersed gelled acrylic polymer having (i) a core of gelled polymerized ethylenically unsaturated monomers which is not soluble in the organic liquid carrier and having chemically grafted thereto (ii) substantially linear stabilizer polymeric components that are soluble in the organic liquid carrier and comprise polymerized ethylenically unsaturated monomers and have a weight average molecular weight of about 500-20,000 determined by GPC (gel permeation chromatography) using polystyrene as the standard; wherein the core, the stabilizer polymeric component, or both contain at least 3% by weight of polymerized ethylenically unsaturated monomers having isocyanate groups attached thereto that are capable of reacting with component (b); (b) 30-90% by weight, based on the weight of the binder, of an oligomer or polymer or both having functional groups capable of reacting with the isocyanate groups of component (a); and (c) 0-60% by weight, based on the weight of the binder, of an organic polyisocyanate crosslinking agent.
摘要:
This invention relates to coating compositions and more particularly to highly productive coating compositions that quickly harden for sanding or buffing by incorporating therein a polyisocyanate adduct mixture into the coating composition as the crosslinking material. Such coatings are particularly useful for refinishing automobiles and trucks.
摘要:
The present invention is directed to a multi component coating composition that includes a crosslinkable, crosslinking and catalyst components. The catalyst component includes organo zinc cocatalysts, organo tin catalysts, and carboxylic acids. The catalyst component provides long pot life to a pot mix obtained by mixing the aforementioned with components while simultaneously providing a coating resulting from the pot mix with desired coating properties, such as desired early hardness of a coating resulting from a relatively low temperature baking cure cycle.
摘要:
coating composition comprising a binder of a. polyisocyanate crosslinking agent; b. an isocyanate-reactive component having at least one compound having the following formula: (I) wherein n on average is 1.7 to 2 and X stands for a cycloaliphatic norbornane derivative containing methylene amine groups of formula (II) either alone, as combinations of these, and/or as mixtures of isomers of these, in which the exact point of attachment and orientation of -CH 2 - group to the NH group and R 20 -R 22 to the norbornane scaffold can vary and mixtures of compounds and isomers are commonly utilized by this invention; two component compositions and articles coated with the novel composition also are part of the invention.
摘要:
A coating composition containing film forming binder and a volatile liquid carrier for the binder; wherein the binder contains (a) an acrylic polymer of polymerized monomers selected from the group consisting of an alkyl methacrylate, an alkyl acrylate, each having 1-12 carbon atoms in the alkyl group, isobornyl methacrylate, isobornyl acrylate, hydroxy alkyl methacrylate, hydroxy alkyl acrylate each having 1-4 carbon atoms in the alkyl group, styrene and any mixtures thereof; (b) an acrylosilane polymer of polymerized monomers selected from the group consisting of an alkyl methacrylate, and alkyl acrylate, each having 1-12 carbon atoms in the alkyl group, isobornyl methacrylate, isobornyl acrylate, hydroxy alkyl methacrylate, hydroxy alkyl acrylate each having 1-4 carbon atoms in the alkyl group, styrene and any mixtures thereof and an ethylenically unsaturated hydroxy functional acrylosilane monomer; and (c) an organic polyisocyanate. The clear coating has improved resistance to marring and to acid etching when exposed to natural weathering conditions.
摘要:
The invention is directed to a two-pack solvent-based ambient curable coating composition comprising a binder of a hydroxyl and cross-linking components. The hydroxyl component includes a linear or branched cycloaliphatic moiety-containing reactive oligomer or blend of oligomers with a weight average molecular weight not exceeding 3,000, a polydispersity not exceeding about 1.7 with at least 2 hydroxyl groups, at least 1, on average, being a primary hydroxyl group. The reactive oligomer is formed by the reaction of an oligomeric acid with monofunctional epoxy. The cross-linking component includes one or more of an oligomeric cross-linker containing at least 2 isocyanate groups. The coating composition of the invention is particularly suited in automotive refinish coatings.
摘要:
The present invention relates to the use of (meth)acrylate functionalized amide acetals as reactive components with crosslinking agents to give new coatings compositions. The present invention further relates to the use of (meth)acrylate functionalized amide acetals as reactive components with crosslinking agents and UV radiation to give new coatings compositions.