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公开(公告)号：EP1819782A1
公开(公告)日：2007-08-22
申请号：EP05812129.4
申请日：2005-10-18
发明人： GRAWE, Thomas , FIEBERG, Andreas , RUERUP, Joachim , GAM, Allisa
CPC分类号： C08G18/44 , C08G18/0823 , C08G18/581 , C08G18/8064 , C08G63/42 , C08G63/64 , C08G63/6854 , C08G63/6954 , C09D5/4492 , C09D175/04
摘要： An improved aqueous cathodic electrocoating composition that contains an anti-crater agent which is a water-reducible polyester resin having an acid value less than 40 mg KOH/g. The water-reducible polyester is the reaction product of (1) a hydroxy cyclic carbonate; (2) a polycarboxylic acid anhydride; (3) optional monofunctional epoxy resin; (4) a polyfunctional epoxy resin; and, (5) a polyamine compound containing tertiary amine and either primary or secondary functionality. The reaction product is neutralized in the presence of acid and water to convert the tertiary amine groups to water-dilutable groups. Hydrolyzable silane groups can also be incorporated into the reaction product to further enhance its crater resistance property. The electrocoat composition produces coatings having a smoother appearance with fewer craters without adversely affecting intercoat adhesion of the cured film to subsequent coating layers applied thereover.
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公开(公告)号：EP0713511B1
公开(公告)日：1997-05-14
申请号：EP94924506.2
申请日：1994-08-04
发明人： CHUNG, Ding, Y. , GAM, Allisa
CPC分类号： C09D5/4457
摘要： An improved aqueous electrocoating composition that contains an anticrater agent which is a reaction product of poly epoxy hydroxy ether resin, polyoxyalkylene diamine and an amino, glycidyl or isocyanate functional alkyl alkoxy silane having a number average molecular weight of about 1,000-6,000; electrodeposited finishes are formed that have a significant reduction in craters and are smooth and even finishes.
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3.发明授权
公开(公告)号：EP1425354B1
公开(公告)日：2005-03-16
申请号：EP02766273.3
申请日：2002-09-12
发明人： GAM, Allisa
CPC分类号： C08G18/581 , C08G18/584 , C08G18/8029 , C08G18/8064 , C09D5/4453 , C09D175/04 , Y10T428/31511
摘要： An improved aqueous cathodic electrocoating composition having a binder of an epoxy-amine adduct and a blocked polyisocyanate crosslinking agent; wherein the improvement is the use of a hydoxyl-carbonate blocked polyisocyanate crosslinking agent. Electrodeposited finishes are formed that have reduced weight loss when heated to cure.
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4.发明授权CATHODIC ELECTROCOATING COMPOSITIONS HAVING IMPROVED APPEARANCE, IMPROVED EDGE COVERAGE AND REDUCED CRATERS 有权外观良好阴极电泳成分，改进边覆盖，降低陈涛，郭院成
公开(公告)号：EP1226217B1
公开(公告)日：2005-01-12
申请号：EP00965237.1
申请日：2000-09-21
发明人： GAM, Allisa
IPC分类号： C09D5/44 , C08G65/336 , C07F7/10
CPC分类号： C09D5/4457 , C07F7/0836 , C08G65/22 , C08G65/336 , C08L71/02 , C08L63/00
摘要： A cathodic electrocoating composition comprises an aqueous carrier, a film forming binder, comprising an epoxy-amine adduct and a blocked polyisocyanate crosslinking agent, dispersed in the carrier, and a novel additive comprising the reaction product of (1) a polyoxy alkylene di or monoamine; (2) a glycidoxy alkyl alkoxy silane; and (3) a glycidyl compound selected from the group consisting of a glycidyl ester of a carboxylic acid and an alkyl glycidyl ether, which reaction product is hydrolyzed in the presence of acid and water to convert alkoxysilane moieties to silanol moieties. The electrocoat composition produces coatings having a smoother appearance with better edge coverage and fewer craters.
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5.发明授权CATHODIC ELECTROCOATING COMPOSITION CONTAINING MORPHOLINE DIONE BLOCKED POLYISOCYANATE CROSSLINKING AGENT 有权与多异氰酸酯MORPHOLINDIONBLOCKIERTEM阴极ED涂料组合物
公开(公告)号：EP1517938B1
公开(公告)日：2007-10-31
申请号：EP03748933.3
申请日：2003-07-02
CPC分类号： C08G18/2875 , C08G18/581 , C08G18/807 , C09D5/4453
摘要： An improved aqueous cathodic electrocoating composition having a binder of an epoxy-amine adduct and a polyisocyanate crosslinking agent; wherein the improvement is the use of a polyisocyanate crosslinking agent having at least one crosslinkable morpholine dione group per molecule. Electrodeposited finishes are formed that have reduced volatile emissions and film weight loss when heated to cure.
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6.发明公开CATHODIC ELECTROCOATING COMPOSITION CONTAINING A MORPHOLINE DIONE CROSSLINKING AGENT 有权阴极电泳组合物中一种吗啉CONTAINS
公开(公告)号：EP1525271A1
公开(公告)日：2005-04-27
申请号：EP03763136.3
申请日：2003-06-30
CPC分类号： C09D5/4453 , C09D5/4496 , Y10T428/31511
摘要： An improved aqueous cathodic electrocoating composition having a binder of an epoxy-amine adduct and a crosslinking agent; wherein the improvement is the use of a crosslinking agent having at least one, preferably a plurality of morpholine dione groups per molecule. Electrodeposited finishes are formed that have reduced volatile emissions and film weight loss when heated to cure.
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7.发明公开
公开(公告)号：EP1425354A1
公开(公告)日：2004-06-09
申请号：EP02766273.3
申请日：2002-09-12
发明人： GAM, Allisa
CPC分类号： C08G18/581 , C08G18/584 , C08G18/8029 , C08G18/8064 , C09D5/4453 , C09D175/04 , Y10T428/31511
摘要： An improved aqueous cathodic electrocoating composition having a binder of an epoxy-amine adduct and a blocked polyisocyanate crosslinking agent; wherein the improvement is the use of a hydoxyl-carbonate blocked polyisocyanate crosslinking agent. Electrodeposited finishes are formed that have reduced weight loss when heated to cure.
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公开(公告)号：EP2580287A2
公开(公告)日：2013-04-17
申请号：EP11792983.6
申请日：2011-06-07
发明人： GAM, Allisa
IPC分类号： C08L75/06
CPC分类号： C09D5/4465 , C08G18/246 , C08G18/4291 , C08G18/581 , C08G18/6407 , C08G18/7664 , C08G18/8029 , C08L75/06 , C09D5/4419 , C09D7/65 , C09D175/06
摘要： The present disclosure relates to an improved electrocoating coating composition wherein the improvement is the addition of a non-water reducible anticrater agent. The non-water reducible anticrater agent is a polyesterurethane that is the reaction product of an aliphatic carboxylic acid anhydride, a monofunctional epoxy compound, a monofunctional alcohol and a diisocyanate and/or a polyisocyanate. The improved electrocoating composition provides cured coatings that have fewer craters and have a smooth surface when compared to coatings utilizing other anticrater additives.
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公开(公告)号：EP1819782B1
公开(公告)日：2008-03-05
申请号：EP05812129.4
申请日：2005-10-18
发明人： GRAWE, Thomas , FIEBERG, Andreas , RUERUP, Joachim , GAM, Allisa
CPC分类号： C08G18/44 , C08G18/0823 , C08G18/581 , C08G18/8064 , C08G63/42 , C08G63/64 , C08G63/6854 , C08G63/6954 , C09D5/4492 , C09D175/04
摘要： An improved aqueous cathodic electrocoating composition that contains an anti-crater agent which is a water-reducible polyester resin having an acid value less than 40 mg KOH/g. The water-reducible polyester is the reaction product of (1) a hydroxy cyclic carbonate; (2) a polycarboxylic acid anhydride; (3) optional monofunctional epoxy resin; (4) a polyfunctional epoxy resin; and, (5) a polyamine compound containing tertiary amine and either primary or secondary functionality. The reaction product is neutralized in the presence of acid and water to convert the tertiary amine groups to water-dilutable groups. Hydrolyzable silane groups can also be incorporated into the reaction product to further enhance its crater resistance property. The electrocoat composition produces coatings having a smoother appearance with fewer craters without adversely affecting intercoat adhesion of the cured film to subsequent coating layers applied thereover.
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10.发明公开CATHODIC ELECTROCOATING COMPOSITION CONTAINING MORPHOLINE DIONE BLOCKED POLYISOCYANATE CROSSLINKING AGENT 有权与多异氰酸酯MORPHOLINDIONBLOCKIERTEM阴极ED涂料组合物
公开(公告)号：EP1517938A1
公开(公告)日：2005-03-30
申请号：EP03748933.3
申请日：2003-07-02
CPC分类号： C08G18/2875 , C08G18/581 , C08G18/807 , C09D5/4453
摘要： An improved aqueous cathodic electrocoating composition having a binder of an epoxy-amine adduct and a polyisocyanate crosslinking agent; wherein the improvement is the use of a polyisocyanate crosslinking agent having at least one crosslinkable morpholine dione group per molecule. Electrodeposited finishes are formed that have reduced volatile emissions and film weight loss when heated to cure.
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