摘要:
Disclosed are polymer blends comprising polycarbonate(s) and polyester(s) wherein the polycarbonate is a polycarbonate derived from bisphenol A and the polyester comprises residues of or is derived from one or more aromatic dicarboxylic acids, neopentyl glycol, and 1,4-cyclohexanedimethanol.
摘要:
Disclosed are polymer blends comprising polycarbonate(s) and polyester(s) wherein the polycarbonate is a polycarbonate derived from bisphenol A and the polyester comprises residues of or is derived from one or more aromatic dicarboxylic acids, neopentyl glycol, and 1,4-cyclohexanedimethanol.
摘要:
The present application relates to polyester compositions, processes to prepare molded articles from these polyester compositions, and containers fabricated from polyester clay composites for food and beverages. The processing methods employed in this invention enable containers to be formed which exhibit excellent clarity. Specifically, the present invention relates to a process comprising forming a parison from a composite composition comprising about 0.10 to about 25 weight % platelet particles dispersed in at least one polyester at a processing temperature which is at least 50° above the Tg of said polyester; and molding said parison into a clear, thin walled article.
摘要:
This invention relates to a process for producing a polyester comprising the steps of: (g) obtaining an aqueous homogenous solution of isosorbide; (h) feeding the aqueous homogenous solution of step (a) into a reactor; (i) feeding one or more glycols and one or more dicarboxylic acids either into the aqueous solution of step (a) or into the reactor of step (b) either prior to, during and/or subsequent to step (b); (j) esterifying the reactor contents at sufficient temperatures and pressures, and optionally in the presence of suitable catalysts, to effect esterificaton; (k) forming a prepolymer; and (l) polycondensing the prepolymer at sufficient temperatures and pressures in the presence of a suitable catalyst to effect polycondensation to form a polyester.
摘要:
This invention is directed to a process for preparing an exfoliated, high I.V. polymer-platelet particle nanocomposite comprising the steps of: (i) melt mixing platelet particles with a matrix polymer-compatible oligomeric resin to form an oligomeric resin-platelet particle composite; and (ii) mixing the oligomeric resin-platelet particle composite with a high molecular weight matrix polymer, thereby increasing the molecular weight of the oligomeric resin-platelet particle composite and producing an exfoliated, high I.V. polymer nanocomposite material. The invention also is directed to a nanocomposite material produced by the process, products produced from the nanocomposite material, and a nanocomposite prepared from an oligomeric resin-platelet particle precursor composite.
摘要:
This invention is directed to a polyamide-clay nanocomposite, products produced from the nanocomposite, and a process for preparing a polyamide-clay nanocomposite. The polyamide-clay nanocomposite comprises (a) an amorphous matrix polyamide comprising (i) a residue of a dicarboxylic acid component comprising at least two diacids and (ii) a residue of a diamine component, and (b) a layered clay material, wherein the layered clay material is dispersed in the matrix polyamide.
摘要:
The present invention comprises polyester blend compositions having improved flavor retaining properties and color, comprising: (A) 98.0 to 99.95 weight percent of a polyester which comprises (1) a dicarboxylic acid component comprising repeat units from at least 85 mole percent terephthalic acid or naphthalenedicarboxylic acid derived from terephthalic acid or naphthalenedicarboxylic acid respectively; and (2) a diol component comprising repeat units from at least 85 mole percent ethylene glycol, based on 100 mole percent dicarboxylic acid and 100 mole percent diol; and (B) 2.0 to 0.05 weight percent of a polyamide; wherein the combined weights of (A) and (B) total 100 percent.
摘要:
This invention relates to polyester polyesteramide blends comprising: (A) about 95-99.99 weight percent of a polyester which comprises a dicarboxylic acid component comprising repeat units from at least 85 mol % terephthalic acid, naphthalene-2,6-dicarboxylic acid or mixtures of terephthalic acid and naphthalene-2,6-dicarboxylic acid and a diol component comprising repeat units from at least 85 mol % ethylene glycol, said mole percents being based on 100 mol % dicarboxylic acid and at least 100 mol % diol; and (B) about 5-0.01 weight percent of a polyesteramide of the formula: A(N)x(D)y where A is a dicarboxylic acid selected from aromatic or cycloaliphatic dicarboxylic acids having 8 to 14 carbon atoms or aliphatic dicarboxylic acids having 3 to 24 carbon atoms, N is a diamine having 2 to 24 carbon atoms, D is a diol having 2 to 14 carbon atoms, X is an integer from 0.01 to 0.99 and Y is an integer from 0.99 to 0.01. The blends of the present invention display good barrier properties, low color and acetaldehyde concentration. The blends are useful for a variety of molded articles including containers, films and sheets.
摘要:
This invention relates to a polyester composition comprising a blend of: (A) 99.5 to 75 weight % of a copolyester having an inherent viscosity of 0.1 to 1.2 dL/g and having a melting point in excess of 250 °C, comprising: (a) one or more dicarboxylic acids, and (b) a glycol component comprising at least 80 mole % 1,4-cyclohexanedimethanol; and (B) 0.5 to 25 weight % of one or more polyalkylene ethers, wherein the weight percentages of all components in said blend total 100 weight %.
摘要:
Described are films capable of being coated with a conductive coating at temperatures equal to or greater than 240 °C, said film comprising a biaxially-oriented polyester film that is produced from a polyester having a melting point of 260 °C or greater.