摘要:
An improved continuous cyclic process for removing oxides of sulfur from a waste gas (A) with a regenerable particulate adsorbent in which hot absorbent particles pick up SOx in a fast fluid transport riser (B), followed by separation of clean gas (D) from sulfur-containing particles which are then recycled to a desorber (G) in which they are contacted at elevated temperature with a mixture of reducing gas (H) and water vapor (I) for release of sulfur as hydrogen sulfide. The adsorbent particles are then recycled in the process. Means are provided for removing particulates in the waste gas.
摘要:
An improved process for reducing SOx in the flue gas from FCC regenerators operated in complete combustion mode is disclosed. The FCC riser is modified to include an SOx desorption zone (D) upstream from the zone in the riser in which regenerated cracking catalyst (A) contacts hydrocarbon feedstock (E). The circulating catalyst inventory (A) includes a regenerable SOx adsorbent. In the SOx desorption zone (D), the hot circulating catalyst inventory (A) is mixed with a reducing gas (B) and water vapor (C) and the gas/solid mixture is maintained in that zone for sufficient time to desorb.
摘要:
A process and apparatus for upgrading a petroleum charge of crude oil or residual fractions thereof to provide a product with substantially reduced heavy metals content and Conradson Carbon number. The charge is dispersed into a descending curtain of heated, substantially inert contact material. This contact material preferably has a conversion rate not substantially greater than 10% in the CAT D test. The vapors generated on contact of the charge with the curtain are collected immediately from the side of the curtain opposite from where the charge is dispersed. The collected vapors are cooled to avoid thermal cracking. The product is suitable for catalytic cracking or use as heavy fuel or heavy fuel precursor.
摘要:
An improved continuous cyclic process for removing oxides of sulfur from a waste gas (A) with a regenerable particulate adsorbent in which hot absorbent particles pick up SOx in a fast fluid transport riser (B), followed by separation of clean gas (D) from sulfur-containing particles which are then recycled to a desorber (G) in which they are contacted at elevated temperature with a mixture of reducing gas (H) and water vapor (I) for release of sulfur as hydrogen sulfide. The adsorbent particles are then recycled in the process. Means are provided for removing particulates in the waste gas.
摘要:
A process wherein lower boiling products (H) are obtained from a hydrocarbon feed (J and/or HH) by contacting the feed with fluidized solid contact material at elevated temperature in a riser (K), spent contact material is separated and stripped of volatile hydrocarbons in a stripping zone (D), stripped contact material is regenerated with oxygen-containing gas (A) in a regeneration zone (B), and hot freshly regenerated fluidized solid contact material is returned to the riser (K), the process further including two or more of the following: (i) suspending hot regenerated contact material in a carbonizable lift gas at the lower portion of the riser and injecting hydrocarbon feed higher in the riser; (ii) charging hydrocarbon feed into the base of the riser, steam cooling a portion of the hot freshly regenerated contact material, and contacting the hydrocarbon feed with hot regenerated contact material upstream of where said hydrocarbon feed is contacted with the steam cooled contact material; (iii) cooling a portion of hot freshly regenerated contact material before returning it to the riser; and (iv) adding a portion of freshly heated regenerated contact material to said stripping zone.
摘要:
A process wherein lower boiling products (H) are obtained from a hydrocarbon feed (J and/or HH) by contacting the feed with fluidized solid contact material at elevated temperature in a riser (K), spent contact material is separated and stripped of volatile hydrocarbons in a stripping zone (D), stripped contact material is regenerated with oxygen-containing gas (A) in a regeneration zone (B), and hot freshly regenerated fluidized solid contact material is returned to the riser (K), the process further including two or more of the following: (i) suspending hot regenerated contact material in a carbonizable lift gas at the lower portion of the riser and injecting hydrocarbon feed higher in the riser; (ii) charging hydrocarbon feed into the base of the riser, steam cooling a portion of the hot freshly regenerated contact material, and contacting the hydrocarbon feed with hot regenerated contact material upstream of where said hydrocarbon feed is contacted with the steam cooled contact material; (iii) cooling a portion of hot freshly regenerated contact material before returning it to the riser; and (iv) adding a portion of freshly heated regenerated contact material to said stripping zone.
摘要:
A process wherein lower boiling products (H) are obtained from a hydrocarbon feed (J and/or HH) by contacting the feed with fluidized solid contact material at elevated temperature in a riser (K), spent contact material is separated and stripped of volatile hydrocarbons in a stripping zone (D), stripped contact material is regenerated with oxygen-containing gas (A) in a regeneration zone (B), and hot freshly regenerated fluidized solid contact material is returned to the riser (K), the process further including two or more of the following:
(i) suspending hot regenerated contact material in a carbonizable lift gas at the lower portion of the riser and injecting hydrocarbon feed higher in the riser; (ii) charging hydrocarbon feed into the base of the riser, steam cooling a portion of the hot freshly regenerated contact material, and contacting the hydrocarbon feed with hot regenerated contact material upstream of where said hydrocarbon feed is contacted with the steam cooled contact material; (iii) cooling a portion of hot freshly regenerated contact material before returning it to the riser; and (iv) adding a portion of freshly heated regenerated contact material to said stripping zone.
摘要:
A hydrocarbon conversion system wherein a hydrocarbon feed is converted to lower boiling products in a reactor (K) by contact at elevated temperature with fluidized solid material, spent material containing coke from said reactor is separated from reaction products and stripped of volatile hydrocarbons in a stripping zone (D), stripped solid material is regenerated with oxygen-containing gas in a regeneration zone (B), and hot freshly regenerated fluidized material is returned to the reactor (K), characterised by carrying out both the conversion and the regeneration in a dilute phase and passing all of the solid material from the reactor (K) and the regeneration zone (B) through respective preseparators (E) wherein rapid disengagement of solids and gases occur and from which the solid material is returned to respective beds in respective vessels (C,D) other than said reactor (K) and regenerator (B).