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    Process for the catalytic hydrotreatment of petroleum feeds for the selective removal of sulfur and nitrogen
    1.
    发明公开
    Process for the catalytic hydrotreatment of petroleum feeds for the selective removal of sulfur and nitrogen 失效
    石油的催化加氢处理工艺中插入选择性除去硫和氮。

    公开(公告)号：EP0527635A2

    公开(公告)日：1993-02-17

    申请号：EP92307324.1

    申请日：1992-08-11

    申请人： EXXON RESEARCH AND ENGINEERING COMPANY

    发明人： Daage, Michel ,  Chianelli, Russell Robert

    IPC分类号： C10G45/02 ,  C10G45/72 ,  B01J35/02 ,  C10G45/04

    CPC分类号： C10G45/72 ,  C10G45/02

    摘要： The hydrotreating of petroleum feedstock is improved by using a layered transition metal catalyst, a mixture of such catalysts or a stacked bed of transition metal catalysts that has a selected ratio of edge to rim sites sufficient to provide a product having a predetermined sulfur and nitrogen content.
    In another aspect of the present invention, there is provided a method for selecting a transition metal catalyst system for use in hydrotreating nitrogen and sulfur containing feedstocks to provide a hydrotreated product having a predetermined nitrogen and sulfur content and at a predetermined reaction residence time, which method comprises: selecting the amount of sulfur and nitrogen to be removed from a given feedstock by hydrotreating to obtain a product having a predetermined nitrogen and sulfur content; determining the variation in the reaction kinetics for sulfur and nitrogen removal of the given feedstock by hydrotreating with a transition metal catalyst of varying edge to rim ratios; selecting, for a predetermined reaction residence time, that ratio from the varying edge to rim ratios of the transition metal catalyst that provides the requisite sulfur and nitrogen removal to provide the product of predetermined sulfur and nitrogen content.

    摘要翻译： 石油原料的加氢处理是通过使用层状过渡金属催化剂，谋求催化剂的混合物或过渡金属催化剂的叠式床改进确实具有边缘的至足以提供具有一预定的硫和氮含量的产品轮缘位点的选择的比率 ， 在本发明的另一个方面，提供了一种方法，用于选择的过渡金属的催化剂体系用于加氢处理的氮利用和含硫原料，以提供具有预定的氮和硫含量的加氢处理产物，并在预定的反应停留时间，这 方法包括：选择的硫和氮的量，以从给定的进料加氢处理以获得具有预定的氮和硫含量的产物中除去; 确定性采矿通过具有变化的边缘到轮缘比的过渡金属催化剂加氢处理在反应动力学对于给定的原料的硫和氮的去除的变化; 选择，在预定的反应停留时间，确实比从边缘变化与过渡金属催化剂的轮缘比率确实提供必要的硫和氮的去除，以提供预定的硫和氮含量的产品。

    Slurry hydroprocessing staged process
    5.
    发明公开
    Slurry hydroprocessing staged process 失效
    浆料加氢处理分阶段进行

    公开(公告)号：EP0420651A1

    公开(公告)日：1991-04-03

    申请号：EP90310609.4

    申请日：1990-09-27

    申请人： EXXON RESEARCH AND ENGINEERING COMPANY

    发明人： Winter, William Edward, Jr. ,  Sawyer, Willard Hall ,  Chianelli, Russell Robert

    IPC分类号： C10G65/08

    CPC分类号： C10G65/08

    摘要： A novel slurry hydrotreating process is described in which a hydrotreating catalyst of small particle size is contacted with petroleum or synfuel feedstocks, particularly gas oils, for hydrogenation of the aromatics contained in such feedstocks. The slurry hydrotreating process employs a high temperature stage followed by one or more low temperature stages.

    摘要翻译： 描述了一种新型淤浆加氢处理方法，其中使小粒度的加氢处理催化剂与石油或合成燃料原料，特别是瓦斯油接触，用于加氢这些原料中所含的芳族化合物。 浆料加氢处理工艺采用高温阶段，接着是一个或多个低温阶段。

    Hydrogenation processes using carbon-containing molybdenum and tungsten sulphide catalysts
    9.
    发明公开
    Hydrogenation processes using carbon-containing molybdenum and tungsten sulphide catalysts 失效
    氢化在使用含碳钼和硫化钨催化剂。

    公开(公告)号：EP0203232A1

    公开(公告)日：1986-12-03

    申请号：EP85303800.8

    申请日：1985-05-30

    申请人： EXXON RESEARCH AND ENGINEERING COMPANY

    发明人： Pecoraro, Theresa Anna ,  Chianelli, Russell Robert

    IPC分类号： B01J27/20 ,  B01J27/04 ,  C10G49/04 ,  C10G47/06

    CPC分类号： B01J27/20 ,  C10G45/04

    摘要： @ Sulfur and nitrogen-containing hydrocarbon feeds are upgraded by contacting said feed, at elevated temperature and in the presence of hydrogen, with a catalyst comprising a carbon-containing sulfide of a catalytic metal selected from tungsten, molybdenum and a mixture thereof. In a preferred embodiment, these catalysts are promoted with certain transition metal sulfides such as cobalt sulfide. The catalyst may be preformed or formed in-situ in the feed or from catalyst precursor salts.

    摘要翻译： 硫和含氮烃进料通过接触所述进料，在升高的温度和在氢存在下，用一种催化剂，包含从钨，钼和它们的混合物中的催化金属的含碳硫化物升级。 在一个优选实施例，本文的催化剂是促进与某些过渡金属硫化物：如硫化钴。 催化剂可以预先形成，或在进料或从催化剂前体盐原位形成。

    Carbon-containing molybdenum and tungsten sulfide catalysts
    10.
    发明公开
    Carbon-containing molybdenum and tungsten sulfide catalysts 失效
    Kohlenstoff enthaltende Molybden-和Wolframsulfid-Katalysatoren。

    公开(公告)号：EP0191960A1

    公开(公告)日：1986-08-27

    申请号：EP85301001.5

    申请日：1985-02-14

    申请人： EXXON RESEARCH AND ENGINEERING COMPANY

    发明人： Chianelli, Russell Robert ,  Pecoraro, Theresa Anna

    IPC分类号： B01J27/04 ,  B01J27/22

    CPC分类号： B01J27/20 ,  B01J27/24 ,  C10G45/04

    摘要： Catalysts comprising a carbon-containing sulfide of molybdenum or tungsten are prepared by contacting, in the presence of sulfur, hydrogen and a hydrocarbon, ammonia and ammonium substituted molybdate, thiomolybdate, tungstate and thiotungstate salts at a temperature of from about 200-600°C. These catalysts are useful for hydrotreating reactions. In a preferred embodiment, these catalysts will be promoted with certain transition metal sulfides, such as cobalt sulfide, which results in catalysts having greater activity then conventional catalysts such as cobaltmolybdate on alumina.

    摘要翻译： 包含钼或钨的含碳硫化物的催化剂通过在约200-600℃的温度下，在硫，氢和烃，氨和铵取代的钼酸盐，硫钼酸盐，钨酸盐和硫代钨酸盐的存在下， 这些催化剂可用于加氢处理反应。 在优选的实施方案中，这些催化剂将被某些过渡金属硫化物如硫化钴促进，这导致催化剂比常规催化剂如氧化铝上的钼酸钼具有更大的活性。