公开(公告)号：EP1620869A2

公开(公告)日：2006-02-01

申请号：EP04730173.4

申请日：2004-04-29

申请人： ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL)

发明人： WANG, Peng ,  ZAKEERUDDIN, Shaik, Mohammad ,  GRAETZEL, Michael

IPC分类号： H01G9/20

CPC分类号： H01L51/4226 ,  B82Y10/00 ,  B82Y30/00 ,  H01G9/2009 ,  H01G9/2031 ,  H01L51/0035 ,  H01L51/0086 ,  Y02E10/542 ,  Y02E10/549

摘要： A dye sensitized solar cell, wherein a compacting compound whose molecular structure comprises a terminal group, a hydrophobic part and an anchoring group is co-adsorbed together with the dye on the semi-conductive metal oxide layer of the photoanode, forming a dense mixed self-assembled monolayer.

公开(公告)号：EP2678345A1

公开(公告)日：2014-01-01

申请号：EP12710342.2

申请日：2012-02-24

申请人： Ecole Polytechnique Federale de Lausanne (EPFL)

发明人： NAZEERUDDIN, Mohammad ,  GRAETZEL, Michael ,  BARANOFF, Etienne ,  KESSLER, Florian ,  YUM, Jun-Ho ,  YELLA, Aswani ,  TSAO, Hoi Nok ,  ZAKEERUDDIN, Shaik, Mohammad

IPC分类号： C07F15/06 ,  H01M14/00

CPC分类号： H01G9/0029 ,  C07D401/04 ,  C07D401/14 ,  C09B57/00 ,  C09B57/10 ,  H01G9/2018 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0083 ,  H01M4/60 ,  H01M10/0525 ,  H01M10/0568 ,  Y02E10/542 ,  Y02E10/549 ,  Y02E60/122 ,  Y02E60/13

摘要： The present invention provides an improved redox couple for electrochemical and optoelectronic devices. The redox couple is based on a complex of a first row transition metal, said complex containing at least one mono-, bi-, or tridentate ligand comprising a substituted or unsubstituted ring or ring system comprising a five-membered N-containing heteroring and/or a six-membered ring comprising at least two heteroatoms, at least one of which being a nitrogen atom, said five- or six-membered heteroring, respectively, comprising at least one double bond. The invention also relates to electrolytes and to the devices containing the complex, and to the use of the complex as a redox couple. The invention further provides electrochemical and/or optoelectronic devices comprising a first and a second electrode and, between said first and second electrode, a charge transport layer, said a charge transport layer comprising tetracyanoborate ([B(CN)4]−) and a cationic metal complex functioning as redox-couple.

摘要翻译： 本发明提供用于电化学和光电子器件的改进的氧化还原电偶。 所述氧化还原对基于第一行过渡金属的络合物，所述复合物含有至少一种包含取代或未取代的环或环系统的单，双或三齿配体，所述环或环系包含五元N含量的杂环和/ 或包含至少两个杂原子的六元环，其中至少一个是氮原子，所述五元或六元杂环分别包含至少一个双键。 本发明还涉及电解质和含有复合物的装置，以及该复合物作为氧化还原对的用途。 本发明还提供了包括第一和第二电极以及在所述第一和第二电极之间的电荷传输层的电化学和/或光电子器件，所述电荷传输层包含四氰基硼酸盐（[B（CN）4] - ）和 用作氧化还原对的阳离子金属络合物。

公开(公告)号：EP1620869B1

公开(公告)日：2009-07-29

申请号：EP04730173.4

申请日：2004-04-29

申请人： ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL)

发明人： WANG, Peng ,  ZAKEERUDDIN, Shaik, Mohammad ,  GRAETZEL, Michael

IPC分类号： H01G9/20

CPC分类号： H01L51/4226 ,  B82Y10/00 ,  B82Y30/00 ,  H01G9/2009 ,  H01G9/2031 ,  H01L51/0035 ,  H01L51/0086 ,  Y02E10/542 ,  Y02E10/549

摘要： A dye sensitized solar cell, wherein a compacting compound whose molecular structure comprises a terminal group, a hydrophobic part and an anchoring group is co-adsorbed together with the dye on the semi-conductive metal oxide layer of the photoanode, forming a dense mixed self-assembled monolayer.

摘要翻译： 一种染料敏化太阳能电池，其中分子结构包含端基，疏水部分和锚定基团的压实化合物与染料共同吸附在光电阳极的半导体金属氧化物层上，形成致密混合的自我 组装单层。