摘要:
A crosslinkable coating composition comprising: ingredient A that has at least two protons that can be activated to form a Michael carbanion donor; ingredient B that functions as a Michael acceptor having at least two ethylenically unsaturated functionalities each activated by an electron-withdrawing group; an additive; and a dormant carbamate initiator of Formula (1)
wherein R 1 and R 2 can be independently selected from hydrogen, a linear or branched substituted or unsubstituted alkyl group having 1 to 22 carbon atoms; 1 to 8 carbon atoms; and A n+ is a cationic species or polymer and n is an integer equal or greater than 1 with the proviso that A n+ is not an acidic hydrogen; and optionally further comprising ammonium carbamate (H 2 NR 1 R 2 + -OC=ONR 1 R 2 ). The crosslinkable coating composition can be used for a variety of coating applications including nail coating compositions.
摘要:
An organoclay composition where a phyllosilicate clay is exchanged with quaternary ammonium ions having a formula of [NR1R2R3R4]+ wherein at least one of R1, R2 and R3 is a mixture of branched alkyl groups. Organoclay compositions exhibit different properties compared to prior art organoclay compositions exchanged with quaternary ammonium ions having a formula of [NRaRbRcRd]+ where at least one of Ra, Rb, Rc and Rd is a not a mixture of branched alkyl groups but a single branched alkyl group, such as 12-methyl stearyl, having a branching point located at a single position along the linear backbone of the branched alkyl group.
摘要翻译:一种有机粘土组合物,其中层状硅酸盐粘土与具有式[NR 1 R 2 R 3 R 4] +的季铵离子交换,其中R 1,R 2和R 3中的至少一个是支化烷基的混合物。 与用式[NR a R b R c R d] +的季铵离子交换的现有技术有机粘土组合物相比,有机粘土组合物表现出不同的性质,其中R a,R b,R c和R d中的至少一个不是支化烷基的混合物, 基团,例如12-甲基硬脂基,其具有位于沿着支化烷基的线性骨架的单个位置处的支化点。
摘要:
A method for determining degree of organoclay delamination and degree of layer alignment in a polymer organoclay nanocomposite comprising one or more infrared light spectral measurements selected from the group consisting of (A) Si-O absorption bandwidth, (B) Si-O absorption band intensity, (C) Si-O absorption band area, and (D) Si-O absorption anisotropy.