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    IN-LINE BLENDING OF PLASTICIZERS WITH A BASE POLYMER
    3.
    发明公开
    IN-LINE BLENDING OF PLASTICIZERS WITH A BASE POLYMER 有权
    IN-LINE混合的基础聚合物增塑剂

    公开(公告)号：EP2201042A1

    公开(公告)日：2010-06-30

    申请号：EP08831077.6

    申请日：2008-09-09

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： KISS, Gabor ,  GALUSKA, Alan, A.

    IPC: C08F2/01

    CPC classification number: C08F10/00 ,  C08F210/16 ,  C08F2/001 ,  C08F2/01 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/20

    Abstract: A process for in-line blending of plasticizers and polymers in a single reactor train including one or more serially configured reactors, a high-pressure separator downstream fluidly connected to the train, and one or more storage tanks, wherein the train produces one or more base polymer components and the one or more storage tanks store one or more off-line produced plasticizers; contacting in the reactor train olefin monomers, catalyst systems and optional comonomers, scavengers, diluents or solvents, at a temperature above the solid-fluid phase transition temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa, forming a reactor effluent including a homogeneous mixture; passing the reactor effluent through theseparator to separate a monomer-rich phase from a polymer-rich phase; and feeding the plasticizers to the process after the reactor train.

    IN-LINE BLENDING OF PLASTICIZERS WITH A BASE POLYMER
    4.
    发明授权
    IN-LINE BLENDING OF PLASTICIZERS WITH A BASE POLYMER 有权
    IN-LINE混合的基础聚合物增塑剂

    公开(公告)号：EP2201042B1

    公开(公告)日：2012-06-27

    申请号：EP08831077.6

    申请日：2008-09-09

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： KISS, Gabor ,  GALUSKA, Alan, A.

    IPC: C08F10/00 ,  C08F2/01

    CPC classification number: C08F10/00 ,  C08F210/16 ,  C08F2/001 ,  C08F2/01 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/20

    Abstract: A process for in-line blending of plasticizers and polymers in a single reactor train including one or more serially configured reactors, a high-pressure separator downstream fluidly connected to the train, and one or more storage tanks, wherein the train produces one or more base polymer components and the one or more storage tanks store one or more off-line produced plasticizers; contacting in the reactor train olefin monomers, catalyst systems and optional comonomers, scavengers, diluents or solvents, at a temperature above the solid-fluid phase transition temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa, forming a reactor effluent including a homogeneous mixture; passing the reactor effluent through theseparator to separate a monomer-rich phase from a polymer-rich phase; and feeding the plasticizers to the process after the reactor train.

    IN-LINE PROCESS TO PRODUCE PELLET-STABLE POLYOLEFINS
    5.
    发明公开
    IN-LINE PROCESS TO PRODUCE PELLET-STABLE POLYOLEFINS 有权
    IN-LINE用于生产球团矿稳定的聚烯烃

    公开(公告)号：EP2231779A1

    公开(公告)日：2010-09-29

    申请号：EP08863908.3

    申请日：2008-12-18

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： KISS, Gabor ,  GALUSKA, Alan, A.

    IPC: C08L51/04

    CPC classification number: C08L23/04 ,  B01J19/0006 ,  B01J2219/00038 ,  C08F110/06 ,  C08F210/06 ,  C08L23/10 ,  Y02P20/544 ,  C08L2666/06 ,  C08F2500/12 ,  C08F2500/20 ,  C08F2500/03 ,  C08F210/16

    Abstract: An in-line fluid phase process for blending low crystallinity polymer components (LCPCs) and high crystallinity polymer components (HCPCs) to form pellet-stable polyolefin pellets is provided. The in-line process for producing the blend includes providing two or more parallel reactor trains and one or more separators for product blending and product-feed separation; wherein the two or more reactor trains producting the LCPC and HCPC blend components operate under fluid phase bulk homogeneous conditions, and at least one of the reactor trains operates under supercritical conditions. The HCPC blend component is a high crystallinity polypropylene-based polymer. The LCPC blend component is a low crystallinity ethylene-based or propylene-based polymer. The resultant blend pellets exhibit a reduced tendency or an eliminated tendency to agglomerate during shipping, handling and storage.

    MONOMER RECYCLE PROCESS FOR FLUID PHASE IN-LINE BLENDING OF POLYMERS
    6.
    发明公开
    MONOMER RECYCLE PROCESS FOR FLUID PHASE IN-LINE BLENDING OF POLYMERS 有权
    用于流体相在线共混的单体再循环方法

    公开(公告)号：EP2125902A1

    公开(公告)日：2009-12-02

    申请号：EP08742020.4

    申请日：2008-03-05

    Applicant: ExxonMobil Research and Engineering Company

    Inventor： KISS, Gabor ,  GALUSKA, Alan, A. ,  LATTNER, James, R.

    IPC: C08F2/00

    CPC classification number: C08F6/003 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F2/001 ,  C08F2500/15 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/20 ,  C08F210/16

    Abstract: A monomer recycle process for fluid phase in-line blending of polymers is provided. The monomer recycle process includes providing a first group (G1) of one or more reactor trains and a second group (G2) of one or more reactor trains and one or more separators fluidly connected to G1 and G2; polymerizing in each of G1 and G2 olefin monomers to form homogenous fluid phase polymer-monomer mixtures wherein each of the G1 and G2 have at least one common monomer; passing the reactor effluents from G1 through the G1 separators to separate a monomer-rich phase from a polymer-enriched phase, passing the polymer-enriched phase and the reactor effluents from G2 into the G2 separator to separate another monomer-rich phase from a polymer-rich blend, and recycling to each of G1 and G2 the separated monomer-rich phase from the G1 and G2 separators, respectively.

    Abstract translation: 提供了用于流体相在线共混聚合物的单体再循环过程。 单体再循环过程包括提供流体连接至G1和G2的一个或多个反应器序列的第一组（G1）和一个或多个反应器序列的第二组（G2）以及流体连接至G1和G2的一个或多个分离器; 在G1和G2烯烃单体中的每一种中聚合以形成均相流体相聚合物 - 单体混合物，其中G1和G2各自具有至少一种常见单体; 使来自G1的反应器流出物通过G1分离器以将富含单体的相与富含聚合物的相分离，使富含聚合物的相和来自G2的反应器流出物进入G2分离器以将另一种富含单体的相与聚合物 并且分别从G1和G2分离器向G1和G2中的每一个再循环分离的富含单体的相。

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