摘要:
The present invention provides a polymerizable composition comprising (A) a compoundincluding a polymerizable unsaturated group and (B) a macromolecular compound including, at a side chain thereof, a structure represented by the following general formula (I). The present invention also provides a negative type planographic printing plate precursor responsive to an infrared laser, the precursor being superior in recording sensitivity and printing durability and using the polymerizable compound as a recording layer. General formula (I)
Z - M +
wherein Z - represents COCOO - , COO - , SO 3 - or SO 2 -N - -R where R represents a monovalent organic group and M + represents an onium cation.
摘要:
A lithographic printing process comprises the steps of: imagewise exposing to infrared light a presensitized lithographic plate which comprises a hydrophilic support and an image-forming layer containing an infrared absorbing agent, a polymerization initiator and a binder polymer to polymerize the polymerizable compound within the exposed area; removing the image-forming layer within the unexposed area while mounting the lithographic plate on a cylinder of a printing press; and then printing with the lithographic plate while mounting the lithographic plate on the cylinder of the printing press. The polymerization initiator is a salt of an anion with a sulfonium ion. According to the present invention, a specific anion or a specific sulfonium ion is used in the polymerization initiator.
摘要:
A negative planographic printing plate precursor for heat-mode exposure systems, which has, on a support, a photosensitive layer containing: (A) a light-to-heat conversion agent; (B) a polymerizable unsaturated group-having compound; and (C) an onium salt having a counter anion with a valency of at least 2. The precursor is capable of being exposed with an IR laser for image formation thereon. The onium salt may be, for example, a diazonium salt, iodonium salt or sulfonium salt. The counter anion has at least two anionic sites which may be the same or different, and the anionic structure is preferably divalent to hexavalent.
摘要:
The present invention relates to a heat mode-compatible planographic printing plate comprising a photosensitive layer which is capable of recording with an infrared laser and formed by applying a photosensitive layer coating solution onto a hydrophilic support and then drying the photosensitive layer coating solution, the photosensitive layer coating solution being obtained by dissolving or dispersing I) an IR absorber, II) a polymerization initiator, and III) a compound having a polymerizable unsaturated group in a solvent, wherein the residual solvent in the photosensitive layer is 5 % by weight or less relative to the weight of the photosensitive layer.
摘要:
The invention provides a hydrophilic film obtained by curing, by at least one energy source selected from heat and light, a composition comprising a compound that has, in a molecule thereof, two or more ring structures selected from the group consisting of five-membered structures and six-membered structures, wherein the ring structures have a hydrophilic group. The invention further provides a planographic printing material having at least a substrate and the hydrophilic film formed on the substrate. The invention further provides a method for forming a planographic printing plate including at least forming an ink receiving portion on a planographic printing material by applying a hydrophobic material by an ink jet recording process.
摘要:
A lithographic printing plate precursor having a support, and an image recording layer containing a microcapsule and (A) an active light absorber, removable by a printing ink and/or fountain solution on the support, characterized in that the microcapsule is a specific urethane type microcapsule, and a lithographic printing method using the same.
摘要:
A polymerizable composition contains (A) a dye which is soluble in an organic solvent and in an alkaline aqueous solution and has an absorption in 700 to 1200 nm, (B) a radical polymerization initiator, (C) a compound having an ethylenically unsaturated bond, and (D) a binder polymer.
摘要:
A negative planographic printing plate precursor for heat-mode exposure systems, which has, on a support, a photosensitive layer containing: (A) a light-to-heat conversion agent; (B) a polymerizable unsaturated group-having compound; and (C) an onium salt having a counter anion with a valency of at least 2. The precursor is capable of being exposed with an IR laser for image formation thereon. The onium salt may be, for example, a diazonium salt, iodonium salt or sulfonium salt. The counter anion has at least two anionic sites which may be the same or different, and the anionic structure is preferably divalent to hexavalent.
摘要:
A planographic printing method including: providing a planographic printing plate precursor including a substrate and an image recording layer which is disposed on the substrate and contains (A) an infrared absorber, (B) a polymerization initiator and (C) a polymerizable compound; imagewise exposing the planographic printing plate precursor with an infrared laser; and supplying oil-based ink and an aqueous component to the exposed planographic printing plate precursor without any development treatment, so as to print an image. A region of the planographic printing plate precursor that has not been exposed with an infrared laser is removed during the printing. The polymerizable compound of (C) is represented by the following formula (1): wherein Ar 1 , R 1 , Z and n are as defined in the claims and the specification.