摘要:
An azo dye represented by formula (I): formula (I) A-N = N-B wherein, A represents a group having a substituent required for inducing an intramolecular nucleophilic substitution reaction with a nitrogen atom of a reduced azo group as a nucleophilic species when the azo group is reductively decomposed, the group forming a compound containing the nitrogen atom in a ring structure, and B represents an aromatic or hetero ring which is bound to the azo group through a carbon atom.
摘要:
A dye-forming coupler of formula (I), a silver halide photographic light-sensitive material containing the coupler, and an azomethine dye that can be derived from the dye-forming coupler: wherein Q is a group -C(-R 11 )=C(-R 12 )-SO 2 -; R 11 and R 12 bond with each other to form, together with the -C=C- moiety, a 5- to 7-membered ring, or they each represent a hydrogen atom or a substituent; R1, R3 and R4 each represent a substituent; m is an integer of 0 to 4; and X represents a hydrogen atom or a group that splits off upon a coupling reaction with an oxidized product of a developing agent; with the proviso that the following compound (I-A) is excluded from the dye-forming coupler of formula (I).
摘要:
A yellow dye-forming coupler represented by formula (I): wherein Q represents a group of nonmetallic atoms that form a 5- to 7-membered ring in combination with the -N=C-N(R 1 )-; R 1 and R 2 each represent a substituent; R 4 represents an alkyl group; m represents an integer of 0 to 4; and X represents a hydrogen atom, or a group capable of being split-off upon a coupling reaction with an oxidized product of a developing agent; and when R 4 represents a primary alkyl group, R 1 represents -(CH 2 ) 3 O-R 101 in which R 101 is an alkyl group having 4 to 8 carbon atoms. A silver halide color photographic light-sensitive material having at least one yellow dye-forming coupler represented by formula (I) in at least one layer provided on a support.
摘要:
A silver halide photographic light-sensitive material including a support and at least one light-sensitive layer formed on the support, wherein at least one of the light-sensitive layers contains at least one of the couplers represented by the following formula (I): wherein Z represents an atomic group that comprises a carbon atom and/or a nitrogen atom which, together with N-C=C, form a 5- or 6-member aromatic ring; R represents a substituent, and when there are a plurality of R, the R can be same or different, and may be coupled to each other so as to form a fused ring; m represents an integer of from 1 to 4; and X represents a carbonyl group, a methylene group, or a >C=N-Rn group wherein Rn represents a substituent. The silver halide photographic light-sensitive material, which has excellent color reproducibility and sharpness and has good color image light-fastness, can be obtained by including therein a coupler which can provide a dye which has excellent hues and storage stability of an image, and whose molar extinction coefficient is high. Also, a method of preparing an azo dye by a coupling reaction of a compound represented by formula (I) and an oxidized p-phenylenediamine derivative is disclosed.
摘要:
3-(4-tert-butylphenyl)-1H-1,2,4-triazol-5-yl acetic acid and its use for the production of photographic couplers and pharmaceutical and/or agricultural compounds is disclosed.
摘要:
A method for preparing a 1H-1,2,4-triazol-5-yl acetic acid compound of formula (4), whereby a compound of formula (1), wherein R1 represents an alkyl group or aryl group, is reacted, with a compound of formula (2), wherein R2 represents an alkyl group, R3 represents an alkyl group or aryl group, A represents an acid substance, and n is 0, 0.5 or 1, in the presence of water, a water-soluble organic solvent, and NaOH or CH 3 COOM, in which latter M represents an alkali metal, to produce a compound represented by the below-given formula (3), wherein R1 and R2 have the same meanings as those in formulas (1) and (2), and then adding M 2 CO 3 , wherein M has the same meaning as defined above, the solution is heated to obtain the compound of formula (4).
The compound of formula (4) wherein R1 is 4-tert-butylphenyl is new and can be used for the production of photographic couplers, pharmaceutical or agricultural compounds.
摘要:
There is disclosed a silver halide color photographic light-sensitive material which comprises a compound of the formula (I) contained in at least one hydrophilic colloid layer on a support: wherein R 1 and R 2 each represent an aliphatic group, an aromatic group, or a heterocyclic group; R 3 represents a substituent; m and n are each an integral number of 0 to 5, provided that m + n ≦ 5 ; and R 1 and R 2 may bond together to form a ring. The light-sensitive material is excellent in the solubility and dispersion stability of photographic reagents, good in color reproduction, and excellent in the fastness of dye images.