摘要:
The invention relates to a method of preparing aromatic polycarbonate having a high molecular weight by boundary face condensation of carbonate oligomer in the presence of an aromatic monohydroxy compound as a chain stopper, base, water and organic solvent at a temperature of at most 70 C, in which the components, among which the chain stopper, are mixed in static mixers to form a fine dispersion, reacting these in a residence zone with plug flow and repeating these steps at least once.
摘要:
A method for recovering substantially pure p,p-bisarylols from a mixture comprising the same by subjecting the mixture to vacuum distillation and melt crystallization in the absence of an adduct crystallization and the generation of a reaction recycle stream.
摘要:
The invention relates to a method for the continuous preparation of carbonate oligomers by boundary face oligomerisation of aromatic dihydroxy compounds with phosgene while adding base, in which the reaction is carried out in a loop-like reactor system in the absence of chain stopper and while using less than 200 ppm of catalyst related to the organic solvent using at least one static mixer and plug folw, optionally in combination with a stirred tank reactor.
摘要:
A method for recovering substantially pure p,p-bisarylols from a mixture comprising the same by subjecting the mixture to vacuum distillation and melt crystallization in the absence of an adduct crystallization and the generation of a reaction recycle stream.
摘要:
The invention relates to a method of preparing a compound of formula 1
wherein R i , R 2 and R 3 correspond to H, a branched or non-branched, optionally substituted alkyl group, or an optionally substituted aryl group, suitable as a chain stopper in the preparation of an aromatic polycarbonate, by reaction of a compound of formula 2
wherein Ri, R 2 and R 3 have the meanings described hereinbefore, with phosgene, comprising the continuous supply of the compound of formula 2 and phosgene to a solution of phosgene in a solvent, the temperature being kept at a value between 0 and 15°C and the pH being kept at a value between 1 and 6.