摘要:
This invention provides a hydrogen storing alloy and a production method thereof. The hydrogen storing alloyhas a chemical composition of a general formulaR (1-x) Mg x Ni y , wherein R is one or more elements selected from rare earth elements comprising Y, x satisfies 0.05≤x≤0.3, and y satisfies 2.8≤y≤3.8. The ratio of the maximal peak intensity present in a range of 2θ=31°-33° to the maximal peak intensity present in a range of 2θ=41°-44° is 0.1 or less (including 0), as measured by X-ray diffraction in which a Cu-Kα ray is set as an X-ray source.
摘要:
The present invention aims to provide an alkaline secondary battery having a large discharge capacity, and little performance degradation during overdischarge. The object of the present invention can be achieved by a positive active material for an alkaline secondary battery having a core layer containing nickel hydroxide and a conductive auxiliary layer which coats the surface of the core layer, wherein the conductive auxiliary layer contains a cobalt oxyhydroxide phase and a cerium dioxide phase, and the active material contains lithium. The inclusion of the cerium dioxide phase in the conductive auxiliary layer enables the inhibition of reduction of cobalt oxyhydroxide even in conditions such as overdischarge. The inclusion of lithium in the active material and the inclusion of the cerium dioxide phase in the conductive auxiliary layer enable the increase of the battery discharge capacity.
摘要:
A cylindrical battery including: a battery case having a cylindrical shape; an electrode group disposed in the battery case, including a positive electrode, a negative electrode, and a separator, and having a pair of flat outer side surfaces opposed to each other; and a spacer disposed between an inner peripheral surface of the battery case and each of the flat outer side surfaces of the electrode group. The spacer has a case contact portion that extends continuously from a first axial end to a second axial end and is in contact with the inner peripheral surface of the battery case, and the case contact portion is formed with a communicating portion that communicates spaces partitioned by the case contact portion.
摘要:
According to the present invention, a battery includes: a cylindrical battery case; and an electrode body disposed in the battery case, and including a positive plate, a negative plate, and a separator disposed between the positive plate and the negative plate. A spacer formed of a dense body and an electrolyte storage space storing an electrolyte are provided between the electrode body and the battery case on one end or both ends of the battery case in an axial direction of the electrode body. Thus, a battery of high energy density and a long life, in which the unsteadiness of the electrode body in the battery case can be suppressed, can be provided at low cost.
摘要:
According to the present invention, a battery includes: a cylindrical battery case; and an electrode body disposed in the battery case, and including a positive plate, a negative plate, and a separator disposed between the positive plate and the negative plate. A spacer formed of a dense body and an electrolyte storage space storing an electrolyte are provided between the electrode body and the battery case on one end or both ends of the battery case in an axial direction of the electrode body. Thus, a battery of high energy density and a long life, in which the unsteadiness of the electrode body in the battery case can be suppressed, can be provided at low cost.
摘要:
The present invention aims to provide an alkaline secondary battery having a large discharge capacity, and little performance degradation during overdischarge. The object of the present invention can be achieved by a positive active material for an alkaline secondary battery having a core layer containing nickel hydroxide and a conductive auxiliary layer which coats the surface of the core layer, wherein the conductive auxiliary layer contains a cobalt oxyhydroxide phase and a cerium dioxide phase, and the active material contains lithium. The inclusion of the cerium dioxide phase in the conductive auxiliary layer enables the inhibition of reduction of cobalt oxyhydroxide even in conditions such as overdischarge. The inclusion of lithium in the active material and the inclusion of the cerium dioxide phase in the conductive auxiliary layer enable the increase of the battery discharge capacity.
摘要:
An aspect of the present invention is a sulfide solid electrolyte comprising at least one element M selected from the group consisting of Al, Si, B, Mg, Zr, Ti, Hf, Ca, Sr, Sc, Ce, Ta, Nb, W, Mo, and V, and N, and having a crystalline structure, wherein the crystalline structure includes a crystalline structure that has a crystal phase of Li 7 P 3 S 11 , Li 4 P 2 S 6 , or β-Li 3 PS 4 , or a first crystalline structure that has diffraction peaks at 2θ = 17.9° ± 0.5°, 19.1° ± 0.5°, 29.1° ± 0.5°, and 29.8° ± 0.5° in X-ray diffraction measurement with a CuKα line.
摘要:
An aspect of the present invention is a sulfide solid electrolyte comprising N, Ge, and an element M, and having a crystalline structure, wherein M represents at least one element selected from the group consisting of Al, Si, B, Mg, Zr, Ti, Hf, Ca, Sr, Sc, Ce, Ta, Nb, W, Mo, and V.
摘要:
A method for producing a sulfide solid electrolyte according to an embodiment of the present invention is a method for producing a sulfide solid electrolyte, including: preparing a composition containing P, S, N, an element A, and an element M; reacting the composition to obtain an intermediate; and heating the intermediate to obtain a sulfide solid electrolyte, where the composition includes a raw material compound containing N, the element A, and the element M. A represents at least one element selected from the group consisting of Li, Na, and K. M represents at least one element selected from the group consisting of Al, Ta, Si, Sc, Mg, Nb, B, Hf, C, P, Zr, and Ti. A method for selecting a raw material compound for use in producing a sulfide solid electrolyte according to another embodiment of the present invention is a method for selecting a raw material compound for use in producing a sulfide solid electrolyte, including: selecting a candidate material containing N, an element A', and an element M' as a candidate for the raw material compound; and calculating defect generation energy E Ndefect of N inside the candidate material with the use of the first principle calculation, where the candidate material is selected as the raw material compound when the E Ndefect is 4.00 eV or more. A sulfide solid electrolyte according to another embodiment of the present invention is a sulfide solid electrolyte that contains P, S, N, an element A, an element X, and an element M as constituent elements and that has a crystalline structure. X represents at least one element selected from the group consisting of Cl, Br, and I; A sulfide solid electrolyte according to another embodiment of the present invention is a sulfide solid electrolyte that contains P, S, N, an element A, and an element M and has crystallinity.