摘要:
A copolycarbonate-polyester, comprising units of formula (I) wherein at least 60 percent of the total number of R1 groups are divalent aromatic organic radicals and the balance thereof are divalent aliphatic or alicyclic radicals; units of formula (II) wherein T is a C7-20 divalent alkyl aromatic radical or a C6-20 divalent aromatic radical, and D is a divalent C6-20 aromatic radical; and units of the formula (III) wherein R2 and R3 are each independently a halogen or a C1-6 alkyl group, R4 is a methyl or phenyl group, each c is independently O to 4, and T is as described above.
摘要:
A copolycarbonate is discloses, comprising units of the formula (1) wherein 70 to 99.5 mole percent of the total number of R1 groups are derived from a dihydroxy compound of formula (2) wherein R2 and R3 are each independently a halogen or a Cj-6 alkyl group, R4 is a methyl or a phenyl group, and c is independently O to 4; and 0.5 to 30 mole percent of the total number of R1 groups are derived from a dihydroxy compound of formula (3) wherein at least 60% of the R3 groups are aromatic, and the dihydroxy compound of formula (3) is not the same as the dihydroxy compound of formula (2), and wherein the copolycarbonate has a glass transition temperature of 2500C or higher.
摘要:
A polycarbonate such as aliphatic/aromatic polycarbonate comprises repeating structural carbonate units of the formula (H-I): in which Rh is a radical having the formula (H-2): wherein each of R11, R12, R13, R14, R15. R16, R17, R18, R19, R20, R2I, R22, R23, R24, R25, R26, R27, and R28 is independently a hydrogen, a C1-C6 alkyl group, or a halogen substituted C1-C6 alkyl group. The polycarbonate, and a thermoplastic composition thereof, have improved thermal stability, cost-effectiveness, and exhibit improved manufacturability such as, for example, minimum cyclic carbonate formation and minimum amine acceptor requirement.
摘要:
A dihydroxy aromatic compound having a Formula (I) wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and each R3 and R4, at each occurrence, can be the same or different and are independently at each occurrence an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons, 'n' is an integer having a value 0 to 4 and 'm' is an integer having a value 0 to 4. Also described herein are polymers made using the dihydroxy compounds of Formula (I), methods of making these polymers and compositions comprising these polymers.