MELT POLYCARBONATE CATALYST SYSTEMS
    1.
    发明公开
    MELT POLYCARBONATE CATALYST SYSTEMS 有权
    催化剂体系熔化聚碳酸酯

    公开(公告)号:EP1358246A2

    公开(公告)日:2003-11-05

    申请号:EP01986539.3

    申请日:2001-12-18

    IPC分类号: C08G64/00

    CPC分类号: C08G64/307

    摘要: This invention provides a method for preparing polycarbonates, which utilizes polycondensation catalysta of the formula Ax+MF6-x, wherein A is an alkali metal or alkaline earth cation; M is a transition metal of group IVA or VA, or M is a p-block metal of group IIIB, IVB or VB; and x is 1, 2, or 3. We have found that this new class of catalysts provide excellent polmerization rates for hte prepartion of Bisphenol A polycarbonate form teh metl polmerization rates for the preparation of Bisphenol A polycarbonate form the melt polymerization of disphenyl carbonate and Bisphenol A. Moreover, the catalysts of the invention were found to be very selective in substantially reducingt the level of branching side reation, i.e., formation of Fries product, normally assocatiated with the melt polycarbonate process.

    MELT POLYCARBONATE CATALYST SYSTEMS
    4.
    发明授权
    MELT POLYCARBONATE CATALYST SYSTEMS 有权
    催化剂体系熔化聚碳酸酯

    公开(公告)号:EP1358246B1

    公开(公告)日:2006-07-12

    申请号:EP01986539.3

    申请日:2001-12-18

    IPC分类号: C08G64/00

    CPC分类号: C08G64/307

    摘要: This invention provides a method for preparing polycarbonates, which utilizes polycondensation catalysta of the formula Ax MF6 , wherein A is an alkali metal or alkaline earth cation; M is a transition metal of group IVA or VA, or M is a p-block metal of group IIIB, IVB or VB; and x is 1, 2, or 3. We have found that this new class of catalysts provide excellent polmerization rates for hte prepartion of Bisphenol A polycarbonate form teh metl polmerization rates for the preparation of Bisphenol A polycarbonate form the melt polymerization of disphenyl carbonate and Bisphenol A. Moreover, the catalysts of the invention were found to be very selective in substantially reducingt the level of branching side reation, i.e., formation of Fries product, normally assocatiated with the melt polycarbonate process.