摘要:
The invention relates to a method for producing metal hydroxides or alkaline metal carbonates by anode dissolution of the corresponding metals and precipitation of the hydroxides or alkaline carbonates in an aqueous medium. The anode dissolution of the metal components is carried out in the anode compartment of a three-compartment electrolytic cell. An aqueous auxiliary salt solution is fed to an intermediate compartment that is disposed between the anode compartment and the cathode compartment and that is separated therefrom by a porous membrane. An at least not alkaline metal salt solution is continuously taken from the anode compartment while an alkaline auxiliary salt solution is continuously taken from the cathode compartment. The at least not alkaline metal salt solution and the alkaline auxiliary salt solution are combined outside the electrolytic cell for the purpose of precipitating metal hydroxides or alkaline metal carbonates.
摘要:
The invention relates to a nickel hydroxide that is coated with an oxidation-stable cobaltous hydroxide coating for use in rechargeable batteries. The oxidation stability is brought about by doping the surface of the cobaltous hydroxide layer with anions of weak inorganic oxo-acids.
摘要:
The present invention concerns cobalt metal agglomerates consisting of peanut-shaped primary particles, a method of producing them and their use. The primary particles have a mean particle size of between 0.1 and 0.7 νm. The proposed method is characterised in that in a first step an aqueous cobalt (II) salt solution of the formula CoX2, in which X = Cl, NO and/or 1/2 SO, is converted with aqueous solutions or suspensions of alkali and/or ammonium carbonates and/or hydrocarbonates at temperatures of between 40 and 100 °C, thus forming basic cobalt carbonate. This step is followed by separation and neutral salt-free washing. The basic cobalt carbonate thus obtained is converted by the addition of alkaline lyes to Co(OH)2, oxidized with oxidizing agents to form the heterogenite CoO(OH) which is then reduced with reducing agents to form the cobalt metal agglomerates. These can be used for producing cobalt sintered articles and positive electrodes in alkaline secondary batteries.
摘要:
A process for preparing basic cobaltous carbonates having the general formula: Co[(OH)2]a[CO3]1-a is disclosed, as well as cobaltous carbonates and cobaltous oxalate carbonates obtained by this process and their use.
摘要:
The present invention concerns cobalt metal agglomerates consisting of peanut-shaped primary particles, a method of producing them and their use. The primary particles have a mean particle size of between 0.1 and 0.7 νm. The proposed method is characterised in that in a first step an aqueous cobalt (II) salt solution of the formula CoX2, in which X = Cl, NO and/or 1/2 SO, is converted with aqueous solutions or suspensions of alkali and/or ammonium carbonates and/or hydrocarbonates at temperatures of between 40 and 100 °C, thus forming basic cobalt carbonate. This step is followed by separation and neutral salt-free washing. The basic cobalt carbonate thus obtained is converted by the addition of alkaline lyes to Co(OH)2, oxidized with oxidizing agents to form the heterogenite CoO(OH) which is then reduced with reducing agents to form the cobalt metal agglomerates. These can be used for producing cobalt sintered articles and positive electrodes in alkaline secondary batteries.
摘要:
The invention relates to a method for producing spherical nickel hydroxide by anodically dissolving a nickel electrode and by precipitating nickel hydroxide in a completely and thoroughly mixed electrolysis cell. An electrolysis brine with a content of 20 to 50 g/l chloride ions and 1 to 7 g/l ammonia with a pH-value of 9.5 to 11.5 and a temperature of 45 to 60° C is used.
摘要:
The invention relates to a method for producing spherical nickel hydroxide by anodically dissolving a nickel electrode and by precipitating nickel hydroxide in a completely and thoroughly mixed electrolysis cell. An electrolysis brine with a content of 20 to 50 g/l chloride ions and 1 to 7 g/l ammonia with a pH-value of 9.5 to 11.5 and a temperature of 45 to 60° C is used.
摘要:
The invention relates to a method for producing spherical tungstic acid powder by acidifying an aqueous solution of alkaline tungstate with mineral acid at a high temperature, preferably in a continuously stirred tank reactor or a cascade of at least two continuously stirred tank reactors, and to tungstic acid thus obtained and characterised by a high bulk density and spherical morphology.
摘要:
The invention relates to a nickel mixed hydroxide comprising Ni as a primary element and having a layer structure comprising at least one element Ma which is selected from the group Fe, Cr, Co, Ti, Zr and Cu, and which exists in two different oxidation levels that, with regard to the number of outer electrons, differ by one electron. The inventive nickel mixed hydroxide also comprises; at least one element Mb which is present in the trivalent oxidation level and which is selected from the group B, Al, Ga, In and SE (rare-earth metals); optionally comprises at least one element Mc which is present in the bivalent oxidation level and which is selected from the group Mg, Ca, Sr, Ba and Zn; comprises, in addition to the hydroxide, at least one additional anion selected from the group halogenides, carbonate, sulfate, oxalate, acetate, borate and phosphate in a quantity which is sufficient to ensure the electroneutrality of the mixed hydroxide; and comprising hydration water in a quantity which stabilizes the respective structure of the mixed hydroxide. The inventive nickel-mixed hydroxide is produced by coprecipitating the hydroxides in an alkaline medium. The inventive nickel mixed hydroxides are characterized by a very high electrochemical utilization of the nickel ions, high capacitances with regard to mass, and a very good cycle stability and, as a result, are advantageously suited as cathode material in alkaline batteries.