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    More advanced preparation method of organic-transition metal hydride complexes containing aryl group or alkyl group as hydrogen storage materials
    1.
    发明公开
    More advanced preparation method of organic-transition metal hydride complexes containing aryl group or alkyl group as hydrogen storage materials 有权
    用于制备的改进方法，arylgruppen-或烷基有机Übergangsmetallhydridkomplexen作为储氢材料含

    公开(公告)号：EP2154105A1

    公开(公告)日：2010-02-17

    申请号：EP09010344.1

    申请日：2009-08-11

    申请人： HANWHA CHEMICAL CORPORATION

    发明人： Kim, Jong Sik ,  Kim, Dong Ok ,  Yoon, Hee Bock ,  Park, Jeasung ,  Jeon, Hyo Jin ,  Ahn, Gui Ryong ,  Kim, Dong Wook ,  Ihm, Jisoon ,  Cha, Moon-Hyun

    IPC分类号： C01B3/00 ,  C07F7/28

    CPC分类号： C07F7/28 ,  C01B3/0015 ,  C01B3/0026 ,  C01B6/02 ,  C07F1/00 ,  C07F1/005 ,  C07F7/006 ,  C07F17/00 ,  Y02E60/327 ,  Y02E60/328

    摘要： The present invention relates to a more advanced preparation method of organic-transition metal hydride as a hydrogen storage material, precisely a more advanced preparation method of organic-transition metal hydride containing aryl or alkyl group that facilitates safe and reverse storage of massive amount of hydrogen.
    The present invention relates to a preparation method of an organic-transition metal hydride comprising the steps of preparing a complex reducing agent composition by reacting alkali metal, alkali earth metal or a mixture thereof and (C10 ∼ C20) aromatic compound in aprotic polar solvent; and preparing organic-transition metal hydride by reacting the prepared complex reducing agent composition and organic-transition metal halide.
    The method of the present invention has advantages of minimizing the numbers and the amounts of byproducts by using a complex reducing agent and producing organic-transition metal hydride safely without denaturation under more moderate reaction conditions.

    摘要翻译： 本发明涉及一种有机 - 过渡金属氢化物作为储氢材料，精确地有机 - 过渡金属氢化物的一个更先进的制备方法包含芳基或烷基的更先进的制备方法做便于安全和反向氢的巨量的存储 ， 本发明涉及一种有机 - 过渡金属氢化物包括制备复杂通过使碱金属，碱土金属或它们的混合物和（C10¼C20）芳香化合物在非质子极性溶剂还原剂组合物的步骤的制备方法; 并且通过使所制备的络合物还原剂组合物与有机 - 过渡金属卤化物制备的有机 - 过渡金属氢化物。 本发明的方法具有由更温和的反应条件下使用复杂的还原剂和生产有机 - 过渡金属氢化物安全地而不变性最小化的数量和副产物的量的优点。

    Preparation method of organic-transition metal hydride complexes and their use as hydrogen storage materials
    4.
    发明公开
    Preparation method of organic-transition metal hydride complexes and their use as hydrogen storage materials 有权
    对于有机过渡金属的杂交复合物的制造方法和它们作为储氢材料使用

    公开(公告)号：EP2098530A1

    公开(公告)日：2009-09-09

    申请号：EP09003201.2

    申请日：2009-03-05

    申请人： HANWHA CHEMICAL CORPORATION

    发明人： Kim, Jong Sik ,  Park, Jeasung ,  Jeon, Hyo Jin ,  Yoon, Hee Bock ,  Kim, Dong Wook ,  Ahn, Gui Ryong ,  Kim, Dong Ok ,  Ihm, Jisoon ,  Cha, Moon-Hyun

    IPC分类号： C07F7/28 ,  C01B3/00

    CPC分类号： C07F5/069 ,  C01B3/001 ,  C01B3/0015 ,  C01B3/0026 ,  Y02E60/327 ,  Y02E60/328

    摘要： The present invention relates to an advanced preparation method of organic-transition metal hydride used as hydrogen storage materials, the method including: preparing organic-transition metal-aluminum hydride complexes by reacting the organic-transition metal halide with metal aluminum hydride compounds; and preparing the organic-transition metal hydride by reacting the organic-transition metal aluminum hydride complexes with Lewis bases.
    Since the preparation method of the organic-transition metal hydride according to the present invention does not use catalysts, it has advantages that it does not cause problems due to poisoning and can prepare the organic-transition metal hydride at high yield under less stringent conditions. The hydrogen storage materials containing the organic-transition metal hydride prepared from the preparation method can safely and reversibly store a large amount of hydrogen.

    摘要翻译： 本发明涉及到在用作储氢材料，该方法包括有机 - 过渡金属氢化物的制备先进方法：通过使与金属氢化铝化合物有机 - 过渡金属卤化物制备的有机 - 过渡金属 - 铝氢化物; 并且通过使与路易斯碱的有机 - 过渡金属铝氢化物络合物的制备有机 - 过渡金属氢化物。 由于有机 - 过渡金属氢化物的制备方法雅丁到本发明不使用的催化剂，它具有的优点也不会引起由于中毒的问题，并且可以较不严格的条件下制备高收率的有机 - 过渡金属氢化物。 含有来自制备方法制备的有机 - 过渡金属氢化物的储氢材料可以安全地和可逆地储存大量氢。