摘要:
This invention is directed to a polymeric composition comprising (a) a continuous phase of a cross-linked organosilicon polymer comprised of alternating (i) polycyclic hydrocarbon residues derived from the polycyclic polyenes having at least two non-aromatic, non-conjugated carbon-carbon double bonds in their rings and (ii) and residues derived from the group consisting of cyclic polysiloxanes and tetrahedral siloxysilanes, linked through carbon to silicon bonds, and (b) a discontinuous phase of a low molecular weight hydrocarbon elastomer having at least two hydrosilation reactable carbon-carbon double bonds. In addition, this invention is directed to a prepolymer composition comprising (a) a hydrosilation cross-linkable organosilicon prepolymer which is the partial reaction product of (i) polycyclic polyenes having at least two non-aromatic, non-conjugated hydrosilation reactive carbon-carbon double bonds in their rings and (ii) cyclic polysiloxanes or tetrahedral siloxsilanes having at least two hydrosilation reaction ≡SiH groups wherein at least one of (i) or (ii) has at least three reactive groups, and (b) hydrocarbon elastomer having at least two hydrosilation reactable carbon-carbon double bonds.
摘要:
This invention is directed to a polymeric composition comprising (a) a continuous phase of a cross-linked organosilicon polymer comprised of alternating (i) polycyclic hydrocarbon residues derived from the polycyclic polyenes having at least two non-aromatic, non-conjugated carbon-carbon double bonds in their rings and (ii) and residues derived from the group consisting of cyclic polysiloxanes and tetrahedral siloxysilanes, linked through carbon to silicon bonds, and (b) a discontinuous phase of a low molecular weight hydrocarbon elastomer having at least two hydrosilation reactable carbon-carbon double bonds. In addition, this invention is directed to a prepolymer composition comprising (a) a hydrosilation cross-linkable organosilicon prepolymer which is the partial reaction product of (i) polycyclic polyenes having at least two non-aromatic, non-conjugated hydrosilation reactive carbon-carbon double bonds in their rings and (ii) cyclic polysiloxanes or tetrahedral siloxsilanes having at least two hydrosilation reaction ≡SiH groups wherein at least one of (i) or (ii) has at least three reactive groups, and (b) hydrocarbon elastomer having at least two hydrosilation reactable carbon-carbon double bonds.