A METHOD TO IMPROVE HALOGENATION REACTIONS
    6.
    发明公开
    A METHOD TO IMPROVE HALOGENATION REACTIONS 审中-公开
    一种改善卤化反应的方法

    公开(公告)号:EP3204345A1

    公开(公告)日:2017-08-16

    申请号:EP15849151.4

    申请日:2015-10-05

    摘要: In the halogenation reaction of olefin/halo-olefin (i.e., organic), an excess amount of halogen gas (fluorine, chlorine, vaporized bromine and iodine, or their combination) is normally used in order to achieve as complete as possible conversion of the organic. In a conventional process, the excess halogen gas in the off-gas stream is scrubbed by caustic solution which increases the consumption of halogen and generates waste for disposal. The present invention provides a novel process to recover and reuse the excess halogen gas and thus reduce the operating cost of the process.

    摘要翻译: 在烯烃/卤代烯烃(即有机)的卤化反应中,通常使用过量的卤素气体(氟,氯,汽化的溴和碘或它们的组合)以尽可能完全地转化 有机。 在常规方法中,废气流中过量的卤素气体被苛性碱溶液洗涤,这会增加卤素的消耗并产生废物以供处理。 本发明提供了一种回收和再利用过量卤素气体的新方法,从而降低了该方法的运行成本。

    METHOD TO IMPROVE 1,1,3-TRICHLOROPROPENE AND/OR 3,3,3-TRICHLOROPROPENE SELECTIVITY DURING THE DEHYDROCHLORINATION OF 1,1,1,3-TETRACHLOROPROPANE
    8.
    发明公开
    METHOD TO IMPROVE 1,1,3-TRICHLOROPROPENE AND/OR 3,3,3-TRICHLOROPROPENE SELECTIVITY DURING THE DEHYDROCHLORINATION OF 1,1,1,3-TETRACHLOROPROPANE 审中-公开
    工艺为1,1,3-三氯丙烯和/或3,3,3-三氯丙烯1,1,1,3-过程中四氯化丙烷脱氯化氢中选择性改进

    公开(公告)号:EP2970063A1

    公开(公告)日:2016-01-20

    申请号:EP14774357.9

    申请日:2014-03-04

    IPC分类号: C07C17/42 C07C21/04

    摘要: This invention relates to a method to improve 1,1, 3 -trichloropropene (HCC- 1240za) and/or 3,3,3-trichloropropene (HCC-1240zf) selectivity in the dehydrochlormation of 1,1,1,3-tetrachloropropane (HCC-250fb). In normal practice, FeCl3 is used as the catalyst for the dehydrochlormation of HCC-250fb to produce 1,1,3- trichloropropene and/or 3,3,3-trichloropropene. The present invention demonstrates that when using FeCl3 as the catalyst for 1,1,1,3-tetrachloropropane dehydrochlormation, the reaction product contains significant amounts of high boiling compounds, such as pentachlorocyclohexene and/or hexachlorocyclohexane species. The addition of one or more UV-stabilizer and/or anti-oxidant compounds, or mixtures thereof, into the dehydrochlormation reaction system, inhibits the formation of these high boiling compounds and improves selectivity to the desired product.