公开(公告)号：EP2371799B1

公开(公告)日：2014-03-05

申请号：EP09832031.0

申请日：2009-09-14

申请人： Hyundai Heavy Industries Co., Ltd. ,  Korea Research Institute Of Chemical Technology

发明人： BAE, Jong Wook ,  OH, Jong Hyeok ,  JUN, Ki Won ,  LEE, Yun Jo ,  KO, Jun-Ho ,  SONG, Seok-Lyong ,  MIN, Keh-Sik

IPC分类号： C07C29/153 ,  C07C29/154

CPC分类号： C07C29/154 ,  Y02P20/582 ,  C07C31/04

公开(公告)号：EP2371799A1

公开(公告)日：2011-10-05

申请号：EP09832031.0

申请日：2009-09-14

申请人： Hyundai Heavy Industries Co., Ltd. ,  Korea Research Institute Of Chemical Technology

发明人： BAE, Jong Wook ,  OH, Jong Hyeok ,  JUN, Ki Won ,  LEE, Yun Jo ,  KO, Jun-Ho ,  SONG, Seok-Lyong ,  MIN, Keh-Sik

IPC分类号： C07C29/153

CPC分类号： C07C29/154 ,  Y02P20/582 ,  C07C31/04

摘要： The present invention relates to a methanol synthesis method using a synthesis gas generated by a mixed reforming of natural gas and carbon dioxide. More particularly, the method of the present invention seeks to utilize carbon dioxide in an economically advantageous manner, and firstly produces a synthesis gas by using a catalyst (Ni/Ce/MgAlO x , or Ni/Ce-Zr/MgAlO x ) and a reaction process condition under which carbon monoxide, carbon dioxide, and hydrogen maintain a specific ratio [H 2 /(2CO+3CO 2 ) = 0.85-1.15] from the mixed reforming wherein the steam reforming of natural gas and the carbon dioxide reforming of methane are carried out at the same time. Subsequently, the thus-produced synthesis gas is employed to synthesize methanol using a catalyst system (the catalyst consisting of a Cu-Zn-Al-based oxide containing CuO, ZnO, and Al 2 O 3 at a predetermined ratio, and cerium-zirconium oxide produced by a sol-gel method) which is appropriate for a methanol synthesis while producing less by-products. Further, the present invention relates to a methanol synthesis method using carbon dioxide in which the synthesis gas which is the unreacted material remaining after the completion of said reforming, is efficiently recirculated and reused to improve the carbon use efficiency (methane and CO 2 use efficiency) of the whole process as well as energy efficiency.

摘要翻译： 本发明涉及一种使用通过混合重整天然气和二氧化碳的产生的合成气的甲醇合成方法。 更具体地，本发明的方法试图利用二氧化碳在经济上有利的方式，并首先通过使用催化剂产生一个合成气（镍/ CE / MgAlO x或镍/铈锆/ MgAlO x）和 在其下的一氧化碳，二氧化碳和氢的反应工艺条件保持从混合特定的比率[H2 /（2CO + 3CO 2）= 0.85-1.15]重整worin的天然气蒸汽重整与甲烷二氧化碳重整 在的Sametime被执行。 随后，将由此生成的合成气中采用使用催化剂系统（基于铜 - 锌 - 铝氧化物以规定的比例含有氧化铜，氧化锌，和Al 2 O 3的催化剂由......组成，和铈 - 锆以合成甲醇 通过溶胶 - 凝胶法生产的氧化物）所有，而副产物产生更少是适合于甲醇合成。 此外，本发明涉及使用二氧化碳，其中合成气的所有据说这是重整完成后剩余的未反应的物质，有效地再循环并重复使用，以改善碳的利用效率（甲烷和二氧化碳的使用效率的甲醇合成方法 ）的整个过程以及能量效率的。

公开(公告)号：EP3243891A1

公开(公告)日：2017-11-15

申请号：EP15877183.2

申请日：2015-11-27

申请人： Korea Research Institute of Chemical Technology

发明人： JUN, Ki Won ,  LEE, Yun Jo ,  KWAK, Geun Jae ,  PARK, Hae Gu ,  KIM, Yong Tae ,  KANG, Seok Chang

IPC分类号： C10G69/04 ,  C10G2/00

CPC分类号： C10G2/332 ,  C07C1/0435 ,  C07C1/12 ,  C10G2/00 ,  C10G2/50 ,  C10G11/05 ,  C10G45/68 ,  C10G69/04 ,  C10G2300/1022 ,  C10G2400/22 ,  C10G2400/30

摘要： The present invention relates to a method for directly synthesizing a monocyclic aromatic compound and a long-chain olefin compound from a carbon dioxide-rich synthetic gas and, more specifically, to a method for directly synthesizing a monocyclic aromatic compound and a long-chain olefin compound from a carbon dioxide-rich synthetic gas, the method comprising a step of preparing a C 1 -C 15 short-chain hydrocarbon by Fischer-Tropsch (FT) synthesis and a step of preparing a monocyclic aromatic compound and a long-chain olefin compound by dehydrogenating the prepared short-chain hydrocarbon, and having effects of maximizing the yield of the short-chain hydrocarbon by using, as a synthetic gas to be used in FT synthesis, a carbon dioxide-rich synthetic gas in which the molar ratio of hydrogen, carbon monoxide and carbon dioxide is delimited to a specific range, and maximizing the yield of the monocyclic aromatic compound or the long-chain olefin compound by specifying the composition of a catalyst to be used in the dehydrogenation and the temperature and pressure condition.

摘要翻译： 直接合成单环芳香族化合物和长链烯烃化合物的方法技术领域本发明涉及由富含二氧化碳的合成气体直接合成单环芳香族化合物和长链烯烃化合物的方法，更具体地说，涉及直接合成单环芳香族化合物和长链烯烃 所述方法包括通过费 - 托（FT）合成制备C1-C15短链烃的步骤和通过以下步骤制备单环芳族化合物和长链烯烃化合物的步骤： 使所制备的短链烃脱氢，并且具有通过使用FT合成中使用的合成气体而使短链烃的产率最大化的效果，所述合成气体中富含二氧化碳的合成气体的氢气， 一氧化碳和二氧化碳的含量限定在特定范围内，并且通过指定ac的组成来最大化单环芳族化合物或长链烯烃化合物的产率 atalyst用于脱氢和温度和压力条件。

公开(公告)号：EP2703082A2

公开(公告)日：2014-03-05

申请号：EP12777039.4

申请日：2012-04-25

申请人： Korea Research Institute of Chemical Technology (KRICT)

发明人： HA, Kyoung Su ,  CHEON, Joo Young ,  LEE, Yun Jo ,  BAEK, Seung-Chan ,  KWAK, Geun Jae ,  PARK, Seon Ju ,  JUN, Ki Won

IPC分类号： B01J35/08 ,  B01J23/70 ,  B01J23/75 ,  B01J23/89 ,  B01J37/08

CPC分类号： B01J23/8913 ,  B01J21/04 ,  B01J23/40 ,  B01J23/70 ,  B01J23/89 ,  B01J37/0221 ,  B01J37/0244 ,  B01J37/0248 ,  C10G2/33 ,  C10G2/331 ,  C10G2/34

摘要： The present invention relates to a catalyst for Fischer-Tropsch synthesis which has excellent heat transfer capability. This catalyst contains (1) central core particle or particles made of a heat transfer material (HTM) selected from the group consisting of a metal, a metal oxide, a ceramic, and a mixture thereof; and (2) outer particle layer which surrounds the central core particles and is attached to the surfaces of the central core particles by a binder material layer. The outer particle layer has a support and catalyst particles in a powder form containing metal particles disposed on the support. The catalyst having such a dual particle structure shows excellent heat transfer capability and, thus, exhibits high selectivity to a target hydrocarbon. Therefore, the catalyst of the present invention is useful in a fixed-bed reactor for Fischer-Tropsch synthesis for producing hydrocarbons from synthetic gas.

摘要翻译： 本发明涉及具有优异传热能力的用于费 - 托合成的催化剂。 该催化剂含有（1）由选自金属，金属氧化物，陶瓷及其混合物的传热材料（HTM）制成的中心核颗粒或颗粒; 和（2）围绕中心核颗粒并通过粘合剂材料层附着到中心核颗粒表面的外颗粒层。 外颗粒层具有载体和催化剂颗粒，所述催化剂颗粒为包含置于载体上的金属颗粒的粉末形式。 具有这种双粒子结构的催化剂显示出优异的传热能力，因此对目标烃显示出高选择性。 因此，本发明的催化剂可用于从合成气生产烃的费 - 托合成的固定床反应器。

公开(公告)号：EP3075450B1

公开(公告)日：2020-09-02

申请号：EP14866315.6

申请日：2014-11-26

申请人： Korea Research Institute of Chemical Technology

发明人： HA, Kyoung Su ,  KWAK, Geun Jae ,  WOO, Min Hee ,  LEE, Yun Jo ,  JUN, Ki Won

IPC分类号： B01J33/00 ,  B01J37/18 ,  B01J23/89 ,  C10G2/00 ,  B01J37/02

公开(公告)号：EP3075450A1

公开(公告)日：2016-10-05

申请号：EP14866315.6

申请日：2014-11-26

申请人： Korea Research Institute of Chemical Technology

发明人： HA, Kyoung Su ,  KWAK, Geun Jae ,  WOO, Min Hee ,  LEE, Yun Jo ,  JUN, Ki Won

IPC分类号： B01J37/16 ,  B01J37/04 ,  C10G2/00

CPC分类号： B01J23/8913 ,  B01J21/12 ,  B01J23/88 ,  B01J23/8896 ,  B01J23/8906 ,  B01J31/02 ,  B01J31/26 ,  B01J33/00 ,  B01J37/0219 ,  B01J37/16 ,  B01J37/18 ,  B01J2231/625 ,  B01J2531/005 ,  C07C1/04 ,  C07C1/0425 ,  C07C1/0435 ,  C07C1/0445 ,  C07C1/045 ,  C10G2/333 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P30/40

摘要： The present invention relates to a method for producing the activated catalyst for Fischer-Tropsch synthesis comprising: a first step of reducing a catalyst for Fischer-Tropsch synthesis; a second step of preparing liquid hydrocarbon in which a part or all of molecular oxygen is eliminated; and a third step of introducing the reduced catalyst prepared in the first step into the liquid hydrocarbon prepared in the second step while blocking its contact with air. Since the reduced catalyst used for Fischer-Tropsch synthesis is introduced into liquid hydrocarbon from which molecular oxygen is removed or coated by liquid hydrocarbon, the catalyst for Fischer-Tropsch synthesis activated based on the present invention maintains a high activity even if exposed to the air for a long time, thereby easily facilitating the long-term storage and long-distance transfer of the reduced catalyst.

摘要翻译： 本发明涉及一种用于费 - 托合成的活化催化剂的制备方法，包括：还原用于费 - 托合成的催化剂的第一步骤; 制备其中部分或全部分子氧被消除的液态烃的第二步骤; 以及第三步骤，将在第一步骤中制备的还原催化剂引入在第二步骤中制备的液体烃中，同时阻止其与空气接触。 由于用于费 - 托合成的还原催化剂被引入分子氧被液体烃除去或涂覆的液态烃中，所以基于本发明活化的费 - 托合成催化剂即使暴露在空气中也保持高活性 长时间，从而容易地促进还原催化剂的长期储存和长距离转移。