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1.发明公开SALT OF DITHIOCARBAMIC ACID, PRODUCTION THEREOF, AND PRODUCTION OF ISOTHIOCYANATE FROM SAID SALT 失效二硫代氨基甲酸盐类，用于生产与制造的这些盐异硫氰酸酯方法。
公开(公告)号：EP0523244A1
公开(公告)日：1993-01-20
申请号：EP92904239.8
申请日：1992-01-29
发明人： YAMAGUCHI, Mikio, Ihara Chemical Ind. Co., Ltd. , OHI, Hideo, Ihara Chemical Ind. Co. Ltd. Kenkyusho
IPC分类号： C07C333/16 , C07C331/28 , C07D401/04 , C07D487/08
CPC分类号： C07D213/74 , C07C331/28 , C07C333/16 , C07D487/08
摘要： Salts of dithiocarbamic acid which can be converted into isothiocyanates, which are suitable intermediates for producing thiazabicyclononane derivatives and monothiourazole derivatives, in a remarkably high yield; a process for producing the salts in a high yield without the necessity for using thiophosgene which is problematic in toxicity; and a process for producing isothiocyanates from the salts. The salt is a compound represented by general formula (2) and produced by the reaction of an aniline represented by general formula (5) with carbon disulfide in the presence of 1,4-diazabicyclo[2.2.2]octane (3) or 4-pyrrolidinopyridine (4). The isothiocyanate (1) is produced by the reaction of the salt (2) with a halogen compound.
摘要翻译： 二硫代氨基甲酸的盐可以转化成异硫氰酸酯，它们是制造thiazabicyclononane衍生物和monothiourazole衍生物，在显着高的收率合适中间体; 用于制造高收率的盐而不需要使用硫光气的所有这是有问题的毒性的方法; 和用于产生从所述盐异硫氰酸酯的方法。 所述盐的化合物由通式（2）表示，并且由苯胺的由通式（5）表示与二硫化碳在1,4-二氮杂双环的存在下反应产生的[2.2.2]辛烷（3）或4 -pyrrolidinopyridine（4）。 异硫氰酸酯（1）由盐（2）与卤素化合物的反应制备。
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2.发明授权SALT OF DITHIOCARBAMIC ACID, PRODUCTION THEREOF, AND PRODUCTION OF ISOTHIOCYANATE FROM SAID SALT 失效二硫代氨基甲酸盐类，生产过程和过程产生这些盐的异硫氰酸酯
公开(公告)号：EP0523244B1
公开(公告)日：1996-04-10
申请号：EP92904239.8
申请日：1992-01-29
发明人： YAMAGUCHI, Mikio, Ihara Chemical Ind. Co., Ltd. , OHI, Hideo, Ihara Chemical Ind. Co. Ltd. Kenkyusho
IPC分类号： C07C333/16 , C07C331/28 , C07D401/04 , C07D487/08
CPC分类号： C07D213/74 , C07C331/28 , C07C333/16 , C07D487/08
摘要： Salts of dithiocarbamic acid which can be converted into isothiocyanates, which are suitable intermediates for producing thiazabicyclononane derivatives and monothiourazole derivatives, in a remarkably high yield; a process for producing the salts in a high yield without the necessity for using thiophosgene which is problematic in toxicity; and a process for producing isothiocyanates from the salts. The salt is a compound represented by general formula (2) and produced by the reaction of an aniline represented by general formula (5) with carbon disulfide in the presence of 1,4-diazabicyclo[2.2.2]octane (3) or 4-pyrrolidinopyridine (4). The isothiocyanate (1) is produced by the reaction of the salt (2) with a halogen compound.
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