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公开(公告)号：EP0057797B1
公开(公告)日：1986-06-25
申请号：EP81306103.3
申请日：1981-12-23
IPC分类号： C22B3/00 , C07D213/79 , C07D213/80 , C07D213/81 , C07D213/82
CPC分类号： C07D213/79 , C07D213/80 , C07D213/81 , C07D213/82 , C22B3/0036 , Y02P10/234 , Y10S423/14
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2.发明授权Composition and use of the composition for the extraction of metals from aqueous solutions 失效用于从水溶液中萃取金属的组合物的组成和用途
公开(公告)号：EP0202833B1
公开(公告)日：1991-01-23
申请号：EP86303559.8
申请日：1986-05-09
CPC分类号： C22B3/0032 , C01G3/003 , C22B3/0017 , Y02P10/234 , Y10S210/912 , Y10S423/14
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公开(公告)号：EP0332314B1
公开(公告)日：1992-12-23
申请号：EP89301652.7
申请日：1989-02-21
CPC分类号： C01G55/001 , C22B3/0036 , Y02P10/234
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公开(公告)号：EP0057797A3
公开(公告)日：1982-09-08
申请号：EP81306103
申请日：1981-12-23
IPC分类号： C22B03/00 , C07D213/79 , C07D213/80 , C07D213/81 , C07D213/82
CPC分类号： C07D213/79 , C07D213/80 , C07D213/81 , C07D213/82 , C22B3/0036 , Y02P10/234 , Y10S423/14
摘要： Metal values are extracted from aqueous solutions of metal salts containing halide or pseudo halide ions by pyridine derivatives containing the substituent -(COX) A where X is the group-OR, or -NR 2 R 3 and n is 1,2 or 3. R, is a hydrocarbyl group containing from 5 to 36 carbon atoms and R 2 and R 3 are hydrogen or a hydrocarbyl group wherein R 2 and R 3 together contain from 5 to 36 carbon atoms. The process is especially useful for the recovery of metals from leach solutions derived from sulphur-containing ores such as chalcopyrite.
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公开(公告)号：EP0332314A2
公开(公告)日：1989-09-13
申请号：EP89301652.7
申请日：1989-02-21
CPC分类号： C01G55/001 , C22B3/0036 , Y02P10/234
摘要： An aqueous solution containing palladium is contacted with a solution of heterocyclic ring compound having at least one ring substituent of the type -COX, which is, or contains, a hydrocarbyl group having at least 5 carbon atoms. The hererocyclic ring compound may be a pyridine mono-, di- or tri-carboxylic acid ester, for example the bis-isodecyl ester of pyridine- 3,5-dicarboxylic acid. Other hererocyclic ring compounds include those having a pyrimidine, pyrazine, pyridazine, 1,2,4-triazole or imidazole ring. Palladium is extracted into the water-immiscible solution whilst other metals, particularly platinum group metals, remain in the aqueous solution. The palladium can be stripped from the water-immiscible solution for example using a dilute aqueous solution of ammonia.
摘要翻译： 将含有钯的水溶液与具有-COX的至少一个环取代基的杂环化合物溶液接触，所述环取代基为或含有具有至少5个碳原子的烃基。 本环状环化合物可以是吡啶单 - ，二 - 或三 - 羧酸酯，例如吡啶-3,5-二羧酸的双异癸基酯。 其它本环化合物包括具有嘧啶，吡嗪，哒嗪，1,2,4-三唑或咪唑环的化合物。 将钯提取到与水不混溶的溶液中，而其它金属，特别是铂族金属则保留在水溶液中。 钯可以从不与水混溶的溶液中汽提，例如使用稀的氨水溶液。
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6.发明公开Process for the extraction of metal values and novel metal extractants 失效一种用于金属的值和Metallextrahierungsmittel提取过程。
公开(公告)号：EP0057797A2
公开(公告)日：1982-08-18
申请号：EP81306103.3
申请日：1981-12-23
IPC分类号： C22B3/00 , C07D213/79 , C07D213/80 , C07D213/81 , C07D213/82
CPC分类号： C07D213/79 , C07D213/80 , C07D213/81 , C07D213/82 , C22B3/0036 , Y02P10/234 , Y10S423/14
摘要： Metal values are extracted from aqueous solutions of metal salts containing halide or pseudo halide ions by pyridine derivatives containing the substituent -(COX) A where X is the group-OR, or -NR 2 R 3 and n is 1,2 or 3. R, is a hydrocarbyl group containing from 5 to 36 carbon atoms and R 2 and R 3 are hydrogen or a hydrocarbyl group wherein R 2 and R 3 together contain from 5 to 36 carbon atoms. The process is especially useful for the recovery of metals from leach solutions derived from sulphur-containing ores such as chalcopyrite.
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公开(公告)号：EP0332314A3
公开(公告)日：1990-02-07
申请号：EP89301652.7
申请日：1989-02-21
CPC分类号： C01G55/001 , C22B3/0036 , Y02P10/234
摘要： An aqueous solution containing palladium is contacted with a solution of heterocyclic ring compound having at least one ring substituent of the type -COX, which is, or contains, a hydrocarbyl group having at least 5 carbon atoms. The hererocyclic ring compound may be a pyridine mono-, di- or tri-carboxylic acid ester, for example the bis-isodecyl ester of pyridine- 3,5-dicarboxylic acid. Other hererocyclic ring compounds include those having a pyrimidine, pyrazine, pyridazine, 1,2,4-triazole or imidazole ring. Palladium is extracted into the water-immiscible solution whilst other metals, particularly platinum group metals, remain in the aqueous solution. The palladium can be stripped from the water-immiscible solution for example using a dilute aqueous solution of ammonia.
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8.发明公开Composition and use of the composition for the extraction of metals from aqueous solutions 失效组合物和用于从水溶液中萃取金属的组合物
公开(公告)号：EP0202833A3
公开(公告)日：1989-03-15
申请号：EP86303559.8
申请日：1986-05-09
CPC分类号： C22B3/0032 , C01G3/003 , C22B3/0017 , Y02P10/234 , Y10S210/912 , Y10S423/14
摘要： The invention relates to compositions for the extraction of metal values, particularly copper, from aqueous solution by solvent extraction. The composition comprises a strong 2-hydroxy-5-alkylbenzaldoxime extractant and a modifier which is a C10-C30 highly branched aliphatic ester or alcohol. The new modifiers overcome the disadvantages with entrainment and "crud" formation.
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9.发明公开
公开(公告)号：EP0202833A2
公开(公告)日：1986-11-26
申请号：EP86303559.8
申请日：1986-05-09
CPC分类号： C22B3/0032 , C01G3/003 , C22B3/0017 , Y02P10/234 , Y10S210/912 , Y10S423/14
摘要： The invention relates to compositions for the extraction of metal values, particularly copper, from aqueous solution by solvent extraction. The composition comprises a strong 2-hydroxy-5-alkylbenzaldoxime extractant and a modifier which is a C10-C30 highly branched aliphatic ester or alcohol. The new modifiers overcome the disadvantages with entrainment and "crud" formation.
摘要翻译： 本发明涉及一种组合物用于金属值通过溶剂萃取萃取，特别是铜，从wässrige溶液。 所述组合物包含强2-羟基-5- alkylbenzaldoximes萃取剂和改性剂的所有其为C10-C30的高度支化脂族酯或醇。 新的改性剂克服夹带和“污物”形成的缺点。
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