摘要:
The present invention provides a process for preparation of a solid titanium catalyst component for use as pro-catalyst for a Ziegler-Natta catalyst system. The solid titanium catalyst component comprises a combination of 15 to 20 wt% of a magnesium moiety, 1.0 to 6.0 wt% of a titanium moiety and 5.0 to 20 wt% of an internal donor, said solid titanium catalyst component has an average particle size in the range of 1 to 100 µm, characterized by a three point particle size distribution of D10 in the range of 1 to 10 µm; D50 in the range of to 25 µm and D90 in the range of 15 to 50 µm. The present invention also provides a 15 Ziegler-Natta catalyst system comprising the solid titanium catalyst component and the method of polymerizing and/or copolymerizing olefins by using the Ziegler-Natta catalyst system.
摘要:
A catalyst composition for use as precursor for Ziegler-Natta catalyst system, said catalyst composition comprising a combination of magnesium moiety, titanium moiety and an internal donor containing at least one 1,2-phenylenedioate compound of structure (A). Also, the present invention provides a process for preparing the aforesaid catalyst composition. Further, the present invention provides a Ziegler-Natta catalyst system incorporating the aforesaid catalyst composition and a method for polymerizing and/or copolymerizing olefins using the Ziegler-Natta catalyst system.
摘要:
The present invention provides a solid organomagnesium precursor having formula {Mg(OR′)X}.a{MgX2}.b{Mg(OR′)2}.c{R′OH}, wherein R′ is selected from a hydrocarbon group, X is selected from a halide group, and a:b:c is in range of 0.01-0.5:0.01-0.5:0.01-5 and process for preparing the same, said process comprising contacting a magnesium source with a solvating agent, an organohalide and an alcohol to obtain the solid organomagnesium precursor. The present invention also provides a process for preparing a catalyst system using the organomagnesium precursor and its use thereof for polymerization of olefins. The organomagnesium precursor is prepared as follows: At 0° C., magnesium in diethyl ether is reacted with the organohalide. After all magnesium has reacted, the calculated amount of alcohol was added and after the completion of addition, the ether was evaporated and a solid compound obtained.
摘要:
The present invention provides a liquid organomagnesium precursor having formula {Mg(OR')X}.a{MgX}.b{Mg(OR')}.c{R'OH}, wherein R' is selected from a hydrocarbon group, X is selected from a halide group, and a:b:c is in range of 0.1-99.8 : 0.1-99.8 : 0.1-99.8, and a process for preparing the same. The said process comprises contacting a magnesium source with an organohalide and alcohol in a solvent to form the liquid organomagnesium precursor. The present invention also provides a catalyst system using the organomagnesium precursor and its use thereof for polymerization of olefins.