摘要:
A method for preparing a metal complex of a porphyrin which has a structure obtained by inserting a transition metal into a porphyrin ring, wherein a porphyrin and a transition metal salt are dissolved separately in a solvent, and then the resulting solutions each containing a porphyrin or a transition metal salt are mixed and reacted in the presence of a basic compound, and wherein a metal complex of a porphyrin having a structure obtained by inserting a transition metal into a porphyrin ring can be synthesized in high selectivity, not only with a simple and easy means but also under a mild condition.
摘要:
A process for producing a metalloporphyrin containing a transition metal inserted into the porphyrin ring which comprises dissolving a porphyrin compound and a transition metal salt each in an independent solvent, combining the solutions, and carrying out the reaction in the presence of a basic substance. By this process, a metalloporphyrin containing a transition metal inserted into the porphyrin ring can be synthesized easily under mild conditions and with high selectivity.