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1.发明公开PROCESS FOR PRODUCING AN AQUEOUS SOLUTION OF PHOSPHORYLCHOLINE GROUP BEARING POLYMER AND AQUEOUS SOLUTION OF PHOSPHORYLCHOLINE GROUP BEARING POLYMER 失效用于生产水溶液磷酸胆碱基法的含氟聚合物溶液和水溶液磷酸胆碱基含氯聚合物
公开(公告)号：EP0767212A1
公开(公告)日：1997-04-09
申请号：EP96907752.8
申请日：1996-04-02
摘要： A method for producing an aqueous solution of a polymer having a phosphorylcholine group in which a polymerizable composition containing a polymerizable monomer having the phosphorylcholine group represented by the formula (1) is polymerized in the presence of a non-metal polymerization initiator soluble in a water-containing medium, to obtain a crude polymer aqueous solution, and the crude polymer aqueous solution is purified with a separation membrane, and an aqueous solution of the polymer having the phosphorylcholine group obtained by the method and having not more than 2000ppm of impurities.
(X: a divalent organic residue, Y: an alkyleneoxy group having C1 to 6, Z: H, R 5 -O-CO-(R 5 : an alkyl group of C1 to 10), R 1 :H, CH 3 , R 2 , R 3 , R 4 : H, a hydrocarbon group or a hydroxy substituted hydrocarbon group of C1 to 6, m; 0 or 1)摘要翻译： 一种用于在聚合物的wässrige溶液制备具有在其中磷酰胆碱基团的聚合性组合物含有具有由下式表示的磷酰胆碱基的聚合性单体的方法（1）聚合在非金属聚合的存在引发剂可溶于水 含介质，得到粗聚合物wässrige溶液，将粗聚合物wässrige溶液与分离膜纯化，并在具有通过该方法获得的磷酸胆碱基团和具有不大于杂质的2000ppm的更多的聚合物的溶液wässrige。
（X：二价有机残基，Y：具有C1〜6的亚烷氧基，Z为H，R <5> -O-CO-（R <5>：烷基C1〜10）中，R <1>：H，CH 3，R <2>，R <3>，R <4>：H，烃基或羟基取代的烃基C1至6，M为0或1） -
2.发明授权PROCESS FOR PRODUCING AN AQUEOUS SOLUTION OF PHOSPHORYLCHOLINE GROUP BEARING POLYMER AND AQUEOUS SOLUTION OF PHOSPHORYLCHOLINE GROUP BEARING POLYMER 失效一种用于制备含有磷酰胆碱基的聚合物的水溶液处理，并含有磷酰胆碱基的聚合物的水溶液
公开(公告)号：EP0767212B1
公开(公告)日：2001-07-18
申请号：EP96907752.8
申请日：1996-04-02
申请人： NOF CORPORATION , Japan Science and Technology Corporation , Nakabayashi, Nobuo , Ishihara, Kazuhiko
摘要： A process for producing an aqueous solution of a phosphorylcholine group bearing polymer, comprising polymerizing a polymerizable composition containing a phosphorylcholine group bearing monomer of general formula (1) in the presence of a nonmetallic polymerization initiator soluble in a water-containing medium to obtain a crude aqueous solution of a polymer and purifying the solution by the use of a separation membrane; and an aqueous solution of a phosphorycholine group bearing polymer produced by this process and having an impurity content of 2000 ppm. or below (X: a divalent organic residue; Y: C1-C6 alkyleneoxy; Z: H or R -O-CO- (R : C1-C10 alkyl or C1-C10 hydroxyalkyl); R : H or CH3; R , R and R : H, C1-C6 hydrocarbyl or hydroxylated hydrocarbyl; and m: 0 or 1).
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