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公开(公告)号:EP0566071B1
公开(公告)日:1997-07-02
申请号:EP93106027.1
申请日:1993-04-14
发明人: Kobayashi, Tetsuro, Nagakute-ryo 610 , Kawahara, Kazuo , Abe, Katsushi , Yamazaki, Kiyoshi, Nagakute-ryo 609 , Iijima, Tomoko , Yokota, Koji , Doi, Haruo , Iwahara, Hiroyasu
CPC分类号: B01D53/9413 , B01D53/326 , B01D53/9431 , B01D2255/1021 , B01D2255/2042 , B01D2255/2063 , B01D2255/2065 , B01D2255/207 , B01D2255/806 , F01N3/0892 , F01N3/20
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公开(公告)号:EP0566071A1
公开(公告)日:1993-10-20
申请号:EP93106027.1
申请日:1993-04-14
发明人: Kobayashi, Tetsuro, Nagakute-ryo 610 , Kawahara, Kazuo , Abe, Katsushi , Yamazaki, Kiyoshi, Nagakute-ryo 609 , Iijima, Tomoko , Yokota, Koji , Doi, Haruo , Iwahara, Hiroyasu
CPC分类号: B01D53/9413 , B01D53/326 , B01D53/9431 , B01D2255/1021 , B01D2255/2042 , B01D2255/2063 , B01D2255/2065 , B01D2255/207 , B01D2255/806 , F01N3/0892 , F01N3/20
摘要: A direct current voltage is applied between an anodic portion containing an oxidizing catalyst provided on one surface of a proton conductive solid electrolyte which separates the flow path of the gas to be treated into two parts, and a cathodic portion containing a reducing catalyst provided on the other surface of the solid electrolyte, the reducing catalyst comprising at least one selected from oxides of elements of Group 5A, Group 6A, and Group 7A of the periodic table, palladium, palladium alloys, transition elements carried on alumina, cerium oxide, and La 1-x Sr x Co 1-y Fe y O₃ (where, 0≦x≦1, 0≦y≦1), while bringing a gas containing water vapor into contact with the anodic portion and bringing a gas containing nitrogen oxides into contact with the cathodic portion. As a result, the water vapor is electrolytically oxidized into protons and oxygen on the anodic portion, so that the protons having been transported to the cathodic portion can be utilized to reduce nitrogen oxides by the reducing power of hydrogen. The method efficiently reduces nitrogen oxides in a gas even under an oxidizing atmosphere.
摘要翻译: 在将质子传导性固体电解质的一个表面上提供的氧化性催化剂的阳极部分施加直流电压,将待处理气体的流路分离成两部分,以及含有还原催化剂的阴极部分, 固体电解质的其它表面,还原催化剂包含选自周期表第5A组,第6A组和第7A组元素的氧化物中的至少一种,钯,钯合金,氧化铝上载有的过渡元素,氧化铈和La1 -xSrxCo1-yFeyO3(其中0≤x≤1,0
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