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    Process for producing N-alkyl-N-methylamine or N-alkenyl-N-methylamine
    2.
    发明公开
    Process for producing N-alkyl-N-methylamine or N-alkenyl-N-methylamine 失效
    Verfahren zur Herstellung von N-烷基-N-甲基胺和N-烯基-N-甲基胺。

    公开(公告)号：EP0510493A2

    公开(公告)日：1992-10-28

    申请号：EP92106429.1

    申请日：1992-04-14

    申请人： KAO CORPORATION

    发明人： Abe, Hiroshi ,  Taniguchi, Hideki ,  Nishimoto, Yoshifumi ,  Sotoya, Kohshiro

    IPC分类号： C07C209/16 ,  B01J23/80 ,  B01J23/76 ,  B01J23/84 ,  B01J23/89 ,  C07C211/08

    CPC分类号： B01J29/068 ,  C07C209/16

    摘要： A process for producing an N-alkyl-N-methylamine or an N-alkenyl-N-methylamine in a high yield from a higher alcohol and methylamine comprising the step of reacting a higher alcohol with methylamine in the presence of a catalyst comprising copper and another fourth period transition metal of the Periodic Table, except chromium, or a catalyst comprising copper, another fourth period transition metal of the Periodic Table, except chromium, and an element of the platinum group, at a pressure ranging from atmospheric pressure to 100 atm, at a reaction temperature ranging from 100 to 250°C, with hydrogen gas being introduced into the reaction system while water produced in the reaction is removed from the reaction system and the amount of methylamine in the gaseous mixture which contains no water formed through the reaction and is exhausted from the reaction system is regulated to be from 5 to 50% by volume.

    摘要翻译： 从高级醇和甲胺生产高产率的N-烷基-N-甲胺或N-链烯基-N-甲胺的方法，包括使高级醇与甲胺在含铜和 除了铬以外的元素周期表的第四周期过渡金属或除了铬以外的包含铜的催化剂，周期表的另外的第四周期的过渡金属和铂的元素以及铂族的元素在大气压至100atm的压力下 在100-250℃的反应温度下，将氢气引入反应体系中，同时从反应体系中除去反应产生的水，而不含水的气态混合物中甲胺的含量 从反应体系中排出的反应调节为5〜50体积％。