公开(公告)号：EP2154187A2

公开(公告)日：2010-02-17

申请号：EP09290117.2

申请日：2009-02-18

Applicant: Korea Advanced Institute of Science and Technology

Inventor： Hong, Soon Hyung ,  Mo, Chan Bin ,  Ryu, Seong Woo

IPC: C08K3/10 ,  C08K9/04 ,  C08J5/00 ,  C08J3/215

CPC classification number: C08J5/005 ,  B82Y30/00 ,  C08J3/2053 ,  C08J2363/00

Abstract: Disclosed is a method for fabricating carbon nanotube-metal-polymer nanocomposites, in particular, to a method for fabricating a carbon nanotube-metal-polymer nanocomposite wherein the carbon nanotubes decorated with metal portion in a necklace form are homogeneously dispersed in a polymer base. The method for fabricating a carbon nanotube-metal-polymer nanocomposite comprises: preparing carbon nanotube-metal nanocomposite powder by introducing a polyol reducing agent as well as metal precursor in a carbon nanotube colloidal solution and heating the same; dispersing the carbon nanotube-metal nanocomposite powder in a polymer base; and curing the polymer base to form the carbon nanotube-metal-polymer nanocomposite. According to the present invention, as the carbon nanotubes decorated with metal particles in a necklace form are homogeneously dispersed in the polymer base, microwave absorbing and shielding properties of the final product are improved.

Abstract translation: 公开了一种制造碳纳米管 - 金属 - 聚合物纳米复合材料的方法，特别是制造碳纳米管 - 金属 - 聚合物纳米复合材料的方法，其中以项链形式的金属部分装饰的碳纳米管均匀地分散在聚合物基体中。 制造碳纳米管 - 金属 - 聚合物纳米复合材料的方法包括：通过在碳纳米管胶体溶液中引入多元醇还原剂和金属前体并加热碳纳米管 - 金属 - 纳米复合材料，制备碳纳米管 - 金属纳米复合材料粉末; 将碳纳米管 - 金属纳米复合粉末分散在聚合物基体中; 并固化聚合物基体以形成碳纳米管 - 金属 - 聚合物纳米复合材料。 根据本发明，由于以项链形式的金属颗粒装饰的碳纳米管均匀地分散在聚合物基体中，因此提高了最终产品的微波吸收和屏蔽性能。

公开(公告)号：EP2241658B1

公开(公告)日：2012-06-20

申请号：EP09157962.3

申请日：2009-04-15

Applicant: Korea Advanced Institute of Science and Technology

Inventor： Hong, Soon Hyung ,  Jeong, Yong Jin ,  Lee, Kyong Ho ,  Mo, Chan Bin

IPC: D01D5/247 ,  D01D10/02 ,  D01F1/10 ,  D01F9/12 ,  D01F9/14 ,  D01D5/00 ,  H01M4/88 ,  H01M8/10

CPC classification number: D01D5/247 ,  D01D10/02 ,  D01F1/10 ,  D01F9/14 ,  H01G9/058 ,  H01G11/34 ,  H01G11/36 ,  H01M4/8807 ,  H01M4/926 ,  Y02E60/13

公开(公告)号：EP2154187A3

公开(公告)日：2011-09-07

申请号：EP09290117.2

申请日：2009-02-18

Applicant: Korea Advanced Institute of Science and Technology

Inventor： Hong, Soon Hyung ,  Mo, Chan Bin ,  Ryu, Seong Woo

IPC: C08K3/10 ,  C08K9/04 ,  C08J5/00 ,  C08J3/215

CPC classification number: C08J5/005 ,  B82Y30/00 ,  C08J3/2053 ,  C08J2363/00

Abstract: Disclosed is a method for fabricating carbon nanotube-metal-polymer nanocomposites, in particular, to a method for fabricating a carbon nanotube-metal-polymer nanocomposite wherein the carbon nanotubes decorated with metal portion in a necklace form are homogeneously dispersed in a polymer base. The method for fabricating a carbon nanotube-metal-polymer nanocomposite comprises: preparing carbon nanotube-metal nanocomposite powder by introducing a polyol reducing agent as well as metal precursor in a carbon nanotube colloidal solution and heating the same; dispersing the carbon nanotube-metal nanocomposite powder in a polymer base; and curing the polymer base to form the carbon nanotube-metal-polymer nanocomposite. According to the present invention, as the carbon nanotubes decorated with metal particles in a necklace form are homogeneously dispersed in the polymer base, microwave absorbing and shielding properties of the final product are improved.

公开(公告)号：EP2241658A1

公开(公告)日：2010-10-20

申请号：EP09157962.3

申请日：2009-04-15

Applicant: Korea Advanced Institute of Science and Technology

Inventor： Hong, Soon Hyung ,  Jeong, Yong Jin ,  Lee, Kyong Ho ,  Mo, Chan Bin

IPC: D01F9/12 ,  D01F9/14 ,  D01D5/00 ,  H01M4/88 ,  H01M8/10

CPC classification number: D01D5/247 ,  D01D10/02 ,  D01F1/10 ,  D01F9/14 ,  H01G9/058 ,  H01G11/34 ,  H01G11/36 ,  H01M4/8807 ,  H01M4/926 ,  Y02E60/13

Abstract: Disclosed is a method for fabrication of porous carbon fibers. More particularly, the method for fabrication of porous carbon fibers comprises the steps of: processing starch to prepare a gelled starch solution; adding organic acid to the gelled starch solution to prepare a starch solution; dissolving carbon nanotubes in a solvent and adding fiber formable polymer thereto to prepare a carbon nanotube/fiber formable polymer solution; mixing the starch solution with the carbon nanotube/fiber formable polymer solution obtained from the above steps, in order to prepare a carbon nanotube/starch/fiber formable polymer solution; electro-spinning or wet-state spinning the prepared carbon nanotube/starch/fiber formable polymer solution to produce starch composite fibers; oxidation heating the starch composite fibers, then, executing carbonization and vacuum heat treatment of the heated fibers, so as to fabricate the porous carbon fibers. The fabricated porous carbon fiber has high specific surface area and high capacitance, thereby being favorably applicable in manufacturing electrodes for a super capacitor, fuel cell, etc.

Abstract translation: 公开了一种多孔碳纤维的制造方法。 更具体地说，制造多孔碳纤维的方法包括以下步骤：加工淀粉以制备胶凝淀粉溶液; 向凝胶状淀粉溶液中加入有机酸以制备淀粉溶液; 将碳纳米管溶解在溶剂中并加入可成纤的聚合物以制备碳纳米管/纤维可成形聚合物溶液; 将淀粉溶液与由上述步骤得到的碳纳米管/纤维可成型聚合物溶液混合，以制备碳纳米管/淀粉/纤维可成形聚合物溶液; 电纺或湿式纺丝制备的碳纳米管/淀粉/纤维成型聚合物溶液以生产淀粉复合纤维; 氧化加热淀粉复合纤维，然后进行加热纤维的碳化和真空热处理，以制造多孔碳纤维。 制造的多孔碳纤维具有高比表面积和高电容，因此有利地适用于制造用于超级电容器，燃料电池等的电极。