摘要:
The present invention relates to a negative electrode active material for a lithium secondary battery, a preparation method thereof, and a lithium secondary battery containing the negative electrode active material. The negative electrode active material for the lithium secondary battery according to the present invention is formed by mixing: a carbon material coated with vapor growth carbon fiber (VGCF) and amorphous graphite; and one or more kinds of other carbon material selected from natural graphite, artificial graphite, amorphous-coated graphite, resin-coated graphite and amorphous carbon. According to the present invention, when the negative electrode active material is prepared, the carbon fiber is uniformly dispersed-throughout the carbon material, and the carbon material is coated with the amorphous graphite and then mixed with other carbon materials, and thus, a high electrode density can be achieved. Accordingly, even with high electrode density, the invention can provide the negative electrode active material with excellent electrochemical properties such as charge/discharge efficiency and cycle characteristics.
摘要:
A carbon negative electrode material for a lithium secondary battery includes: a core carbon material; and a coated layer covering the core carbon material and comprising a carbon coating material and carbon fiber.
摘要:
A negative active material for a secondary battery, an electrode for a secondary battery including the same, a secondary battery, and a manufacturing method thereof are disclosed. The negative active material for a secondary battery includes a core carbon material whose edge is partially or entirely coated with a carbide layer, wherein a particle size distribution (PSD) broad value ranges from 0.1 to 0.85 and, when the negative active material is pressed at a pressure of 2 tons, a pore volume rate before and after the compression is 0.2 or greater. A discharge capacity, efficiency, and capacity retention in a long-term cycle can be improved by optimizing the PSB broad value related to a particle distribution among physical properties of a carbon material-based negative active material for a secondary battery, and a pore volume rate of the negative active material before and after compression.
摘要:
A negative active material for a secondary battery according to the present invention includes a core carbon material and a carbide layer formed on at least a portion of an edge of the core carbon material, and has a difference (an amount of compression density change) of 0.5g/cc or more between a first compression density measured when a pressure of 63.704 MPa is applied for 2 seconds and a second compression density measured when a pressure of 6.3704 MPa is applied for 2 seconds. A secondary battery manufactured using the negative active material according to the present invention can prevent deterioration of characteristics caused by destruction of the carbide layer during a compression process in the manufacture of an electrode of a secondary battery. As a result, a cycle efficiency and a discharging capacity retention rate at a long cycle can be improved.
摘要:
A negative active material for a secondary battery includes a core carbon material, and a carbide layer formed on at least a portion of an edge of the core carbon material, and has a specific surface area ratio of 1.6 or less and a sphericity ratio of 0.6 or more when the negative active material is compressed with a pressure of 1.3 ton per 1 cm2 for 2 seconds. A secondary battery manufactured using the negative active material can prevent deterioration of characteristics caused by destruction of the carbide layer and deformation of core carbon material that may occur during a compression process performed to manufacture an electrode for the secondary battery. As a result, the secondary battery can be improved in aspect of a discharging capacity, a cycle efficiency and a discharging capacity retention rate at a long cycle.