公开(公告)号：EP2157071A2

公开(公告)日：2010-02-24

申请号：EP09014595.4

申请日：2003-03-07

申请人： Lummus Technology Inc.

发明人： Gartside, Robert, J. ,  Greene, Marvin, I. ,  Jones, Quincy, J.

IPC分类号： C07C6/04

CPC分类号： C07C11/107 ,  C07C5/2512 ,  C07C6/04 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/16 ,  C07C2523/24 ,  C07C2523/30 ,  C07C2523/32 ,  C07C2529/06

摘要： A C 3 to C 6 hydrogen cut from a cracking unit is processed for the conversion of olefins to propylene and hexene via autometathesis. The autometathesis (16) of a mixed normal butenes feed (10) in the presence of a metathesis catalyst operates without any ethylene in the feed mix to the metathesis reactor. Some fraction of the 2-butene feed may be isomerized to 1-butene and the 1-butene formed plus the 1-butene in the feed react rapidly with the 2-butene to form propylene and 2-pentene. The feed to the reactor also includes the recycle of the 2-pentene (14) formed in the reactor with unreacted butenes to simultaneously form additional propylene and hexene. Some or all (34) of the 3-hexene (26) formed in the reaction is isomerized to 1-hexene (46). In one embodiment, some portion (72) of the 3-hexene (26) produced in the main metathesis reaction is reacted with ethylene to produce 1-butene (96) without the need for superfractionation.

摘要翻译： 处理从裂化装置切割的C 3至C 6氢气，以通过自动化将烯烃转化为丙烯和己烯。 在复分解催化剂存在下，混合的正丁烯进料（10）的自动化（16）在进料混合物中没有任何乙烯运行到复分解反应器。 2-丁烯进料的一部分可以异构化为1-丁烯，并且进料中形成的1-丁烯加上1-丁烯与2-丁烯快速反应形成丙烯和2-戊烯。 反应器的进料还包括在反应器中形成的2-戊烯（14）与未反应的丁烯循环，以同时形成另外的丙烯和己烯。 在反应中形成的3-己烯（26）中的一些或全部（34）异构化为1-己烯（46）。 在一个实施方案中，在主复分解反应中产生的3-己烯（26）的一部分（72）与乙烯反应以生产1-丁烯（96），而不需要超分级。

公开(公告)号：EP2157071A3

公开(公告)日：2010-03-31

申请号：EP09014595.4

申请日：2003-03-07

申请人： Lummus Technology Inc.

发明人： Gartside, Robert, J. ,  Greene, Marvin, I. ,  Jones, Quincy, J.

IPC分类号： C07C6/04

CPC分类号： C07C11/107 ,  C07C5/2512 ,  C07C6/04 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/16 ,  C07C2523/24 ,  C07C2523/30 ,  C07C2523/32 ,  C07C2529/06

摘要： A C 3 to C 6 hydrogen cut from a cracking unit is processed for the conversion of olefins to propylene and hexene via autometathesis. The autometathesis (16) of a mixed normal butenes feed (10) in the presence of a metathesis catalyst operates without any ethylene in the feed mix to the metathesis reactor. Some fraction of the 2-butene feed may be isomerized to 1-butene and the 1-butene formed plus the 1-butene in the feed react rapidly with the 2-butene to form propylene and 2-pentene. The feed to the reactor also includes the recycle of the 2-pentene (14) formed in the reactor with unreacted butenes to simultaneously form additional propylene and hexene. Some or all (34) of the 3-hexene (26) formed in the reaction is isomerized to 1-hexene (46). In one embodiment, some portion (72) of the 3-hexene (26) produced in the main metathesis reaction is reacted with ethylene to produce 1-butene (96) without the need for superfractionation.