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    METHOD FOR PRODUCING CATALYST FOR CYCLIC CARBONATE SYNTHESIS
    1.
    发明公开
    METHOD FOR PRODUCING CATALYST FOR CYCLIC CARBONATE SYNTHESIS 审中-公开
    VERFAHREN ZUR HERSTELLUNG EINES KATALYSATORSFÜRCYCLISCHE CARBONATSYNTHESE

    公开(公告)号：EP2990114A4

    公开(公告)日：2017-02-08

    申请号：EP14788234

    申请日：2014-04-22

    申请人： NAT INST ADVANCED IND SCIENCE & TECH ,  MARUZEN PETROCHEM CO LTD

    发明人： TAKAHASHI TOSHIKAZU ,  YASUDA HIROYUKI ,  SAKAKURA TOSHIYASU ,  YAMAMOTO SHOUJI ,  NANIKI TAKASHI ,  FURUKAWA TAKURO

    IPC分类号： B01J31/26 ,  B01J31/06 ,  B01J37/02 ,  C07B61/00 ,  C07D317/36 ,  C07D317/38

    CPC分类号： C07D317/38 ,  B01J21/08 ,  B01J27/08 ,  B01J27/182 ,  B01J31/0231 ,  B01J31/0267 ,  B01J31/0268 ,  B01J31/0269 ,  B01J31/0271 ,  B01J31/069 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1061 ,  B01J2231/341 ,  C07D317/36

    摘要： Provided are: a method for easily producing a heterogeneous catalyst having excellent catalytic activity at a low cost, said heterogeneous catalyst being used for the purpose of synthesizing a cyclic carbonate by subjecting to a reaction an epoxide and carbon dioxide; a catalyst which is obtained by this production method; and a method for synthesizing a cyclic carbonate with use of this catalyst. A method for producing a catalyst that is used for the purpose of synthesizing a cyclic carbonate by subjecting to a reaction an epoxide with carbon dioxide, said method comprising the following steps (a) and (b): (a) a step of obtaining a catalyst precursor having a haloalkyl group or a haloaryl group, by subjecting to a reaction a silane compound having a haloalkyl group or a haloaryl group and a silica gel having an average pore diameter of from 3.5 to 50 nm, and (b) a step of obtaining a catalyst for cyclic carbonate synthesis, by subjecting to a reaction the catalyst precursor obtained in step (a) and a tertiary phosphine, in which the molar ratio of the halogen content to the phosphorus content, namely [halogen]/[phosphorus] is from 0.8 to 1.6.

    摘要翻译： 本发明提供一种易于制造低成本催化活性优异的非均相催化剂的方法，所述多相催化剂用于通过环氧化物和二氧化碳的反应合成环状碳酸酯; 通过该制造方法得到的催化剂; 以及使用该催化剂合成环状碳酸酯的方法。 一种制备用于通过使环氧化物与二氧化碳进行反应合成环状碳酸酯的目的的催化剂的方法，所述方法包括以下步骤（a）和（b）：（a）获得 具有卤代烷基或卤代芳基的催化剂前体通过使具有卤代烷基或卤代芳基的硅烷化合物和平均孔径为3.5至50nm的硅胶进行反应，和（b）步骤 通过使步骤（a）中得到的催化剂前体与卤素含量与磷含量的摩尔比即[卤素] / [磷]的叔膦反应，得到环状碳酸酯合成催化剂 从0.8到1.6。

    METHOD FOR CONTINUOUSLY PRODUCING CYCLIC CARBONATE
    3.
    发明公开
    METHOD FOR CONTINUOUSLY PRODUCING CYCLIC CARBONATE 有权
    VERFAHREN ZUR KONTINUIERLICHEN HERSTELLUNG VON CYCLISCHEN CARBONATEN

    公开(公告)号：EP3023419A4

    公开(公告)日：2017-05-03

    申请号：EP14825786

    申请日：2014-07-18

    申请人： MARUZEN PETROCHEM CO LTD ,  NAT INST ADVANCED IND SCIENCE & TECH

    发明人： NANIKI TAKASHI ,  HAYASHI YASUNORI ,  SAWADA GORO ,  FURUKAWA TAKURO ,  HARUNA TAKESHI ,  TAKAHASHI TOSHIKAZU ,  YASUDA HIROYUKI ,  YAMAMOTO SHOUJI

    IPC分类号： C07D317/38 ,  B01J27/08 ,  B01J31/02

    CPC分类号： C07D317/38 ,  B01J27/08 ,  B01J31/0231 ,  B01J31/0239 ,  B01J31/0254 ,  B01J31/0268 ,  B01J31/0269 ,  B01J31/0271 ,  B01J2231/341 ,  B01J2531/90

    摘要： Provided is a method for continuously producing a cyclic carbonate, by which generation of a glycol in a reaction for synthesizing a cyclic carbonate is suppressed, and a cyclic carbonate having a high purity can be efficiently obtained even by simple purification. A method for continuously producing a cyclic carbonate, including filling a catalyst in a fixed-bed tube reactor, and continuously feeding carbon dioxide and an epoxide to the fixed-bed tube reactor to thereby bringing the carbon dioxide and the epoxide into contact with the catalyst, while continuously withdrawing the reaction liquid in the fixed-bed tube reactor, wherein the method includes a pre-treatment step in which a pre-treatment liquid containing a cyclic carbonate is brought into contact with the catalyst before feeding the carbon dioxide and the epoxide to the fixed-bed tube reactor, and the generated glycol is removed out of the system.

    摘要翻译： 本发明提供一种连续制造环状碳酸酯的方法，通过该方法抑制环状碳酸酯合成反应中的二醇的生成，即使通过简单的精制也可以有效地得到高纯度的环状碳酸酯。 一种连续制备环状碳酸酯的方法，包括在固定床管式反应器中填充催化剂，并将二氧化碳和环氧化物连续加入到固定床管式反应器中，由此使二氧化碳和环氧化物与催化剂接触 ，同时在固定床管式反应器中连续排出反应液体，其中该方法包括预处理步骤，其中使含有环状碳酸酯的预处理液与催化剂接触，然后将二氧化碳和环氧化物 到固定床管式反应器，并将生成的乙二醇从系统中移出。