公开(公告)号：EP0196232A2

公开(公告)日：1986-10-01

申请号：EP86302269.5

申请日：1986-03-26

申请人： MCGEAN-ROHCO, INC.

发明人： Opaskar, Vincent C ,  Canaris, Valerie M. ,  Willis, William J.

IPC分类号： C25D3/32 ,  C25D3/60 ,  C25D3/34 ,  C25D3/56

CPC分类号： C25D3/60 ,  C25D3/32 ,  C25D3/36 ,  H05K3/3473

摘要： A tin and/or lead electroplating bath is free from fluoride or fluoborate ions and comprises

(A) a bath-soluble metal salt which is a stannous salt, a lead salt, or a mixture of stannous and lead salts;
(B) an alkane sulphonic acid or alkanol sulphonic acid;
(C) a nonionic, cationic or amphoteric surfactant;
(D) a primary brightening agent which is an aromatic aldehyde, an acetophenone or a carbonyl compound of the formula:
in which Ar is a substituted or unsubstituted phenyl, naphthyl, pyridyl, thiophenyl or furyl group; and
(E) a secondary brightening agent which is a lower aliphatic aldehyde or a substituted olefin of the formula:
in which R, is a carboxy, carboxamide, alkali metal car boxylate, ammonium carboxylate, amine carboxylate or allyl carboxylate group; and R 2 , R 3 and R 4 are each independently hydrogen or lower alkyl groups.

摘要翻译： 锡和/或铅电镀浴不含氟化物或氟硼酸根离子，包括：（A）金属盐，铅盐或亚锡和铅盐的混合物的浴溶性金属盐;（B） 烷基磺酸或链烷醇磺酸;（C）非离子，阳离子或两性表面活性剂;（D）作为芳族醛的主增亮剂，下式的苯乙酮或羰基化合物：Ar-CH = CH-CO-CH 3（III）其中Ar是取代或未取代的苯基，萘基，吡啶基，噻吩基或呋喃基; 和（E）二级增白剂，其为低级脂族醛或下式的取代烯烃：其中R 1为羧基，羧酰胺，碱金属羧酸盐，羧酸铵，胺羧酸盐或烯丙基羧酸盐基团 ; 并且R 2，R 3和R 4各自独立地为氢或低级烷基。

公开(公告)号：EP0196232A3

公开(公告)日：1987-04-01

申请号：EP86302269

申请日：1986-03-26

申请人： MCGEAN-ROHCO, INC.

发明人： Opaskar, Vincent C ,  Canaris, Valerie M. ,  Willis, William J.

IPC分类号： C25D03/32 ,  C25D03/60 ,  C25D03/34 ,  C25D03/56

CPC分类号： C25D3/60 ,  C25D3/32 ,  C25D3/36 ,  H05K3/3473

摘要： A tin and/or lead electroplating bath is free from fluoride or fluoborate ions and comprises
(A) a bath-soluble metal salt which is a stannous salt, a lead salt, or a mixture of stannous and lead salts; (B) an alkane sulphonic acid or alkanol sulphonic acid; (C) a nonionic, cationic or amphoteric surfactant; (D) a primary brightening agent which is an aromatic aldehyde, an acetophenone or a carbonyl compound of the formula:
in which Ar is a substituted or unsubstituted phenyl, naphthyl, pyridyl, thiophenyl or furyl group; and (E) a secondary brightening agent which is a lower aliphatic aldehyde or a substituted olefin of the formula:
in which R, is a carboxy, carboxamide, alkali metal car boxylate, ammonium carboxylate, amine carboxylate or allyl carboxylate group; and R 2 , R 3 and R 4 are each independently hydrogen or lower alkyl groups.

公开(公告)号：EP0196232B1

公开(公告)日：1991-11-21

申请号：EP86302269.5

申请日：1986-03-26

申请人： MCGEAN-ROHCO, INC.

发明人： Opaskar, Vincent C ,  Canaris, Valerie M. ,  Willis, William J.

IPC分类号： C25D3/32 ,  C25D3/60 ,  C25D3/34 ,  C25D3/56

CPC分类号： C25D3/60 ,  C25D3/32 ,  C25D3/36 ,  H05K3/3473