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公开(公告)号:EP0456838A1
公开(公告)日:1991-11-21
申请号:EP91900338.4
申请日:1990-12-05
IPC分类号: C07C229/08 , C07C227/12
CPC分类号: C07C227/26 , C07C227/12
摘要: A process for producing glycine by the reaction of glycolonitrile with carbon dioxide and ammonia in the presence of water, which comprises the steps of conducting a preliminary reaction of glycolonitrile, with carbon dioxide, ammonia and water at 80 to 120 °C for 0.5 to 1 hr, conducting a main reaction at 150 to 200 °C, separating glycine thus formed from the reaction mixture, and recycling the remaining mother liquor to the reaction system comprising glycolonitrile, carbon dioxide, ammonia and water to conduct the preliminary and/or main reaction.
摘要翻译: 甘氨酸通过乙醇腈,二氧化碳和氨在水的存在下反应生成,在80-120℃下初始反应0.5-1.0小时,然后在150-200℃下主反应。形成的甘氨酸是 然后从反应混合物中分离,其中包含乙醇腈,乙内酰脲,甘氨酰甘氨酸,乙酰胺,2,5-二酮哌嗪,乙内酰脲和甘氨酸。 然后将母液再循环至随后的反应。
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公开(公告)号:EP0456838B1
公开(公告)日:1995-11-02
申请号:EP91900338.4
申请日:1990-12-05
IPC分类号: C07C229/08 , C07C227/12
CPC分类号: C07C227/26 , C07C227/12
摘要: A process for producing glycine by the reaction of glycolonitrile with carbon dioxide and ammonia in the presence of water, which comprises the steps of conducting a preliminary reaction of glycolonitrile, with carbon dioxide, ammonia and water at 80 to 120 °C for 0.5 to 1 hr, conducting a main reaction at 150 to 200 °C, separating glycine thus formed from the reaction mixture, and recycling the remaining mother liquor to the reaction system comprising glycolonitrile, carbon dioxide, ammonia and water to conduct the preliminary and/or main reaction.
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