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    Conversion of light hydrocarbons to ether rich gasolines
    2.
    发明公开
    Conversion of light hydrocarbons to ether rich gasolines 失效
    在Ether enthaltende Benzine的Umwandlung von lichten Kohlenwasserstoffen。

    公开(公告)号：EP0509162A1

    公开(公告)日：1992-10-21

    申请号：EP91303339.5

    申请日：1991-04-16

    申请人： MOBIL OIL CORPORATION (a New York corporation)

    发明人： Bell, Weldon Kay ,  Haag, Werner Otto ,  Harandi, Mohsen Nadimi ,  Owen, Hartley

    IPC分类号： C10L1/02

    CPC分类号： C10L1/023 ,  Y02P30/20

    摘要： A process is disclosed for converting a light hydrocarbon feedstock that contains a mixture of linear and branched olefins to ether-rich high octane gasoline streams that include tertiary alkyl and isoalkyl ethers such as MTBE, TAME, methyl isopropyl ether (MIPE), and methyl sec-butylether (MSBE). The process involves initially etherifying the tertiary olefins with a lower alcohol in the presence of an ion exchange resin catalyst, and then etherifying the linear olefins in the presence of a zeolite catalyst, such as zeolite beta. The unreacted olefins from the etherification reactions are converted to gasoline boiling range hydrocarbons by oligomerization with a zeolite catalyst, such as ZSM-5.

    摘要翻译： 公开了一种将包含直链和支链烯烃混合物的轻质烃原料转化成富含高级辛烷值汽油的方法，其中包括叔烷基和异烷基醚如MTBE，TAME，甲基异丙醚（MIPE）和甲基sec 丁基醚（MSBE）。 该方法首先在离子交换树脂催化剂的存在下用低级醇醚化叔烯烃，然后在沸石催化剂如沸石β存在下醚化直链烯烃。 来自醚化反应的未反应烯烃通过用沸石催化剂如ZSM-5低聚转化成汽油沸程烃。