公开(公告)号：EP1537049B1

公开(公告)日：2006-08-16

申请号：EP03769604.4

申请日：2003-09-10

申请人： MSSA

发明人： Harabasz, Arnaud ,  LE MOUELLIC, Christian ,  Pointu, Lionel ,  FLACHER, Pierre

IPC分类号： C01G31/00

CPC分类号： H01M4/485 ,  C01G31/00 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2006/40 ,  H01M10/052

公开(公告)号：EP1537049A1

公开(公告)日：2005-06-08

申请号：EP03769604.4

申请日：2003-09-10

申请人： MSSA

发明人： Harabasz, Arnaud ,  LE MOUELLIC, Christian ,  Pointu, Lionel ,  FLACHER, Pierre

IPC分类号： C01G31/00

CPC分类号： H01M4/485 ,  C01G31/00 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2006/40 ,  H01M10/052

摘要： The invention relates to a method of producing a crystalline lithium/vanadium mixed oxide powder having formula Li1+xV3O8, wherein x is between 0 and 0.2. The inventive method comprises the following steps: formation of an aqueous suspension from a NH4VO3 paste and lithium hydroxide monohydrate powder; continuous dehydration of the aforementioned suspension in a stream of hot gas at a temperature of between 200 and 600 °C in order to form a dry powder of a precursor, having a particle size of between 10 and 100 µm; and calcination of said precursor at a temperature of between 380 and 580 °C into a crystalline powder Li1+xV3O8. The product thus obtained is intended, in particular, for the production of lithium rechargeable batteries and battery electrodes.

摘要翻译： 混合结晶锂和钒氧化物粉末的制备包括：（a）由NH4VO3和锂二锂一水合粉末形成水悬浮液; （b）悬浮液在200-600℃的温度下在热气流中连续脱水，形成粒度在10-100μm之间的干前体粉末; （c）在380-580℃的温度下煅烧前体以形成锂和氧化钒的结晶粉末。